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无机材料学报

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燃烧合成Ti3AlC2粉体的机理研究

葛振斌1; 陈克新1; 郭俊明1,2; 周和平1; 宁晓山1   

  1. 1. 清华大学材料科学与工程系新型陶瓷与精细工艺国家重点实验室 北京 100084; 2. 蒙自师范高等专科学校化学系; 云南 蒙自 661100
  • 收稿日期:2002-02-01 修回日期:2002-03-19 出版日期:2003-03-20 网络出版日期:2003-03-20

Formation Mechanism of Ternary Carbide Ti3AlC2 by Combustion Synthesis

GE Zhen-Bin1; CHEN Ke-Xin1; GUO Jun-Ming1,2; ZHOU He-Ping1; NING Xiao-Shan1   

  1. 1.Department of Material Science & Engineering; The State Key Lab of New Ceramics & Fine Processing; Tsinghua University; Beijing 100084; China; 2.Department of Chemistry; Mengzi Teachers College; Yunnan Mengzi 661100; China
  • Received:2002-02-01 Revised:2002-03-19 Published:2003-03-20 Online:2003-03-20

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摘要： 利用淬火实验并结合XRD、SEM研究了燃烧合成Ti3AlC2粉体的机理.实验结果表明,燃烧合成Ti3AlC2粉体的机理是溶解再析出机制.即先生成的TiC晶核重新溶解到Ti-Al熔体中,同时三元碳化物开始析出并发育成层状结构.反应可以分为三个阶段:A.预热阶段;B.初始反应阶段;C.溶解析出阶段.

关键词: 燃烧合成, Ti3AlC2, 反应机理, 粉体

Abstract: The formation mechanism of Ti3AlC2 powders by the combustion synthesis was investigated by analyzing the microstructure and phase content of the quenched sample. The results show that the mechanism of the reaction is a solution- precipitation mechanism: at first previously formed TiC particles dissolve in the Ti-Al melt, followed by the precipitation of ternary phase Ti3AlC2 that will grow into a layered morphology. The model of combustion synthesis of Ti3AlC2 can be divided into four stages: unreacted stage, preheating and initial reacting stage, dissolution and precipitation stage, completely reacted stage.

Key words: Ti3AlC2, mechanism, combustion synthesis, powders

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