负载ZnS的介孔炭复合硫正极材料的制备及性能研究

doi:10.3724/SP.J.1077.2013.13017

无机材料学报 ›› 2013, Vol. 28 ›› Issue (10): 1127-1131.DOI: 10.3724/SP.J.1077.2013.13017 CSTR: 32189.14.SP.J.1077.2013.13017

负载ZnS的介孔炭复合硫正极材料的制备及性能研究

陈龙, 刘景东, 张诗群

(福州大学化学化工学院, 福州 350108)

收稿日期:2013-01-08 修回日期:2013-03-18 出版日期:2013-10-20 网络出版日期:2013-09-18
作者简介:陈龙(1988–), 男, 硕士研究生. E-mail: 574278287@qq.com
基金资助:
国家基础科学人才培养基金(J1103303)

Preparation of Mesoporous Carbon/Sulfur Composite Loaded with ZnS and Its Property for Lithium-sulfur Batteries

CHEN Long, LIU Jing-Dong, ZHANG Shi-Qun

(College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China)

Received:2013-01-08 Revised:2013-03-18 Published:2013-10-20 Online:2013-09-18
About author:CHEN Long. E-mail: 574278287@qq.com
Supported by:
National Science Foundation for Fostering Talents in Basic Research of China (J1103303)

摘要/Abstract

摘要： 为了获得高性能的锂硫电池正极材料, 采用先超声分散再进行热处理的方法制备了负载ZnS的介孔炭复合材料(ZnS/MC), 进而用热复合法获得负载有ZnS的介孔炭复合硫正极材料(ZnS/MC/S)。XRD、SEM、EDS和N2吸附脱附等温线表明, 当ZnS含量低于17wt%时, 通过超声波分散, ZnS可以均匀负载到介孔炭中; 但热处理或提高ZnS含量时ZnS会发生聚集, 形成闪锌矿型ZnS晶相。循环伏安测试表明, ZnS对多硫离子的氧化起促进作用; 充放电测试表明, ZnS/MC/S电极的初始放电比容量为1354.6 mAh/g, 首次充放电库仑效率为98.7%; 50次循环后容量仍有650 mAh/g。

关键词: 锂硫电池, ZnS, 介孔炭, 超声波分散, 循环性能

Abstract: With the aim to obtain high performance cathode materials for lithium-sulfur batteries, composite of mesoporous carbon (MC) loaded with ZnS (ZnS/MC) was prepared through ultrasonic dispersion and heat treatment. The as-prepared composite was blended with elemental sulfur by heating, then cathode materials (ZnS/MC/S) was obtained. The ZnS/MC composite was characterized by XRD, SEM, EDS and N₂ adsorption-desorption isotherms. The results showed that ZnS particle was uniformly loaded to the surface of MC through ultrasonic dispersion when content of ZnS was less than 17wt%. ZnS nanoparticles aggregated to form sphalerite ZnS by heat treatment or increasing content of ZnS. Cyclic voltammetry test showed that ZnS accelerated the oxidation process of polysulfides. Charge/ discharge tests indicated that the initial discharge specific capacity was 1354.6 mAh/g, while the coulombic efficiency of the first charge and discharge was 98.7%. The capacity still remained 650 mAh/g after 50 cycles.

Key words: lithium sulfur battery, ZnS, mesoporous carbon, ultrasonic dispersion, cyclic performance

中图分类号:

TM912

陈龙, 刘景东, 张诗群. 负载ZnS的介孔炭复合硫正极材料的制备及性能研究[J]. 无机材料学报, 2013, 28(10): 1127-1131.

CHEN Long, LIU Jing-Dong, ZHANG Shi-Qun. Preparation of Mesoporous Carbon/Sulfur Composite Loaded with ZnS and Its Property for Lithium-sulfur Batteries[J]. Journal of Inorganic Materials, 2013, 28(10): 1127-1131.

参考文献

[1] LIANG Xiao, Wen Zhao-Yin, LIU Yu. Research progress of high performance lithium sulfur battery materials. Chemical Progress, 2011, 23(2/3): 520–526.

[2] JI Xiu-Lei, Nazar Linda F. Advances in Li-S batteries. Journal of Material Chemistry, 2010, 20(44): 9821–9826.

[3] Mikhaylik Yury V, Akridge James R. Polysulfide shuttle study in the Li/S battery system. Journal of The Electrochemical Society, 2004, 151(11): A1969–A1976.

[4] Cheon Sang-Eun, Ko Ki-Seok, Cho Ji-Hoon, et al. Rechargeable lithium sulfur battery I. Structural change of sulfur cathode during discharge and charge. Journal of The Electrochemical Society, 2003, 150(6): A796–A799.

[5] Cheon Sang-Eun, Ko Ki-Seok, Cho Ji-Hoon, et al. Rechargeable lithium sulfur battery II. Rate capability and cycle characteristics. Journal of The Electrochemical Society, 2003, 150(6): A800–A805.

[6] Wang J, Chen J, Konstartirov K, et a1. Sulphur-polypyrrole composite positive electrode materials for rechargeable lithium batteries. J. Electrochimica Acta, 2006, 51(22): 4634–4638．

[7] SUN Ming-Ming, ZHANG Shi-Chao, JING Tao, et al. Nano-wire networks of sulfur-polypyrrole composite cathode materials for rechargeable lithium batteries. Electrochem. Commun., 2008, 10(12): 1819–1822.

[8] DUAN Li, LU Jia-Chun, LIU Wen-Yuan, et al. Fabrication of conductive polymer-coated sulfur composite cathode materials based on layer-by-layer assembly for rechargeable lithium-sulfur batteries. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2012, 414(23): 98–103.

[9] GUO Ju-Chen, XU Yun-Hua, WANG Chun-Sheng. Sulfur- impregnated disordered carbon nanotubes cathode for lithium- sulfur batteries. Nano Letter, 2011, 11(10): 4288–4294.

[10] ZHENG Guang-Yuan, YANG Yuan, Cha Judy J, et al. Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries. Nano Letter, 2011, 11(7): 4462–4467.

[11] Jayaprakash N, Shen J, Moganty Surya S, et al. Porous hollow Carbon@Sulfur composites for high-power lithium-sulfur batteries. Angewandte Chemie-International Edition, 2011, 50(26): 5904–5908.

[12] Dimos K, Koutselas I B, Karakassides M A. Synthesis and characterization of ZnS nanosized semiconductor particles within mesoporous solids. Journal of Physical Chemistry B, 2006, 110(45): 22339–22345.

[13] JI Xiu-Lei, Lee Kyu Tae, Nazar Linda F. A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries. Nature Materials, 2009, 8(6): 500–506.

[14] LIU Hui, YUE Xin, LIU Jing-Dong. Effect of montmorillonite on the performance of mesoporous carbon/sulfur composite electrode. Battery, 2012, 42(4): 186–188.

[15] Yamin H, Penciner J, Gorenshtein A, et al. The electrochemical behavior of polysulfides in tetrahydrofuran. Journal of Power Sources, 1985, 14(2): 129–134.

[16] Yamin H, Gorenshtein A, Penciner J, et al. Lithium sulfur battery oxidation/reduction mechanisms of polysulfides in THF Solutions. Journal of the Electrochemical Society, 1988, 135(5): 1045–1048.

负载ZnS的介孔炭复合硫正极材料的制备及性能研究

Preparation of Mesoporous Carbon/Sulfur Composite Loaded with ZnS and Its Property for Lithium-sulfur Batteries

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张婷婷, 王方园, 刘长友, 张国荣, 吕佳辉, 宋宇晨, 介万奇. 水热-烧结法制备Cr²⁺:ZnSe/ZnSe核壳结构纳米孪晶[J]. 无机材料学报, 2024, 39(4): 409-415.
[2]	王新玲, 周娜, 田亚文, 周明冉, 韩静茹, 申远升, 胡执一, 李昱. SnS₂/ZIF-8衍生二维多孔氮掺杂碳纳米片复合材料的锂硫电池性能研究[J]. 无机材料学报, 2023, 38(8): 938-946.
[3]	李高然, 李红阳, 曾海波. 硼基材料在锂硫电池中的研究进展[J]. 无机材料学报, 2022, 37(2): 152-162.
[4]	李婷婷, 张阳, 陈加航, 闵宇霖, 王久林. 锂硫电池S@pPAN正极用柔性黏结剂研究[J]. 无机材料学报, 2022, 37(2): 182-188.
[5]	付宇坤, 曾敏, 饶先发, 钟盛文, 张慧娟, 姚文俐. 锂离子电池高镍LiNi_0.8Mn_0.2O₂正极材料的微波合成及其Co、Al共改性[J]. 无机材料学报, 2021, 36(7): 718-724.
[6]	金高尧, 何海传, 吴杰, 张梦源, 李亚娟, 刘又年. 锂硫电池正极用钴掺杂空心多孔碳载体材料[J]. 无机材料学报, 2021, 36(2): 203-209.
[7]	汤嘉伟, 王永邦, 马成, 杨海潇, 王际童, 乔文明, 凌立成. 甲基萘沥青基有序中孔炭的制备及电化学性能[J]. 无机材料学报, 2021, 36(10): 1031-1038.
[8]	蒋浩,吴淏,侯成义,李耀刚,肖茹,张青红,王宏志. 切割方向对桦木衍生的取向微通道生物质炭锂硫电池隔膜性能的影响[J]. 无机材料学报, 2020, 35(6): 717-723.
[9]	王佳宁, 靳俊, 温兆银. α-MoC_1-_x纳米晶富集碳球修饰隔膜对锂硫电池性能的影响[J]. 无机材料学报, 2020, 35(5): 532-540.
[10]	孙顶, 丁彦妍, 孔令炜, 张玉红, 郭秀娟, 魏立明, 张力, 张立新. Mg掺杂Cu₂ZnSnS₄的第一性原理研究[J]. 无机材料学报, 2020, 35(11): 1290-1294.
[11]	李亚东, 李伟平, 王琴, 郑道光, 王建新. 碳纤维支撑柔性碳硫复合电极的制备、物性及电池性能研究[J]. 无机材料学报, 2019, 34(4): 373-378.
[12]	周蓓莹, 陈东, 刘佳乐, 江莞, 罗维, 王连军. CuInS₂/ZnS核壳结构量子点的水相制备与性能研究[J]. 无机材料学报, 2018, 33(3): 279-283.
[13]	李永生, 陈玲. 可控制备磁性四氧化三铁-金纳米复合颗粒及其催化性能研究[J]. 无机材料学报, 2018, 33(2): 221-228.
[14]	王琦, 彭大春, 马倩, 何月德, 刘洪波. 炭包覆LiFePO₄纳米片的制备及电化学性能研究[J]. 无机材料学报, 2018, 33(12): 1349-1354.
[15]	王宇晖, 靳俊, 郭战胜, 温兆银. 锂硫电池循环过程中变形演化的直接观测[J]. 无机材料学报, 2017, 32(3): 247-251.