固相反应法制备MgAl2O4纳米粉体及其烧结行为研究

doi:10.3724/SP.J.1077.2012.11725

无机材料学报 ›› 2012, Vol. 27 ›› Issue (9): 991-996.DOI: 10.3724/SP.J.1077.2012.11725 CSTR: 32189.14.SP.J.1077.2012.11725

固相反应法制备MgAl₂O₄纳米粉体及其烧结行为研究

苏兴华¹, 李建功², 周振君¹

(1. 长安大学材料科学与工程学院, 西安 710061; 2. 兰州大学材料科学与工程研究所, 兰州 730000)

收稿日期:2011-11-18 修回日期:2012-01-04 出版日期:2012-09-20 网络出版日期:2012-08-28
基金资助:
国家自然科学基金(51102022); 高等学校博士学科点专项科研基金(20110205120001); 中国博士后科学基金(2011M501426); 中央高校基本科研业务费专项基金(CHD2012ZD015, CHD2011JC134); 长安大学基础研究支持计划专项基金

Solid-state Reaction Preparation and Sintering Behavior of MgAl₂O₄ Nanopowders

SU Xing-Hua¹, LI Jian-Gong², ZHOU Zhen-Jun¹

(1. School of Materials Science and Engineering, Chang’an University, Xi’an 710061, China; 2. Institute of Materials Science and Engineering, Lanzhou University, Lanzhou 730000, China)

Received:2011-11-18 Revised:2012-01-04 Published:2012-09-20 Online:2012-08-28
Supported by:
National Natural Science Foundation of China (51102022); Specialized Research Fund for the Doctoral Program of Higher Education (20110205120001); China Postdoctoral Science Foundation (2011M501426); Special Fund for Basic Scienti?c Research of Central Colleges, Chang’an University (CHD2012ZD015, CHD2011JC134); Special Fund for Basic Research Support Programs of Chang’an University

摘要/Abstract

摘要： 在800℃下煅烧Al(OH)₃和MgSO₄混合粉末, 冷却后经过水洗得到了结晶良好的MgAl₂O₄纳米粉体. 采用DSC/TG、XRD、TEM和SEM等分析手段研究了混合粉末中Mg/Al原子比对颗粒尺寸及团聚状况的影响, 以及MgAl₂O₄纳米粉体的烧结性能. 所制备的MgAl₂O₄纳米粉体平均颗粒尺寸为12 nm, 尺寸分布窄, 团聚少. MgAl₂O₄的生成归因于γ-Al₂O₃和MgSO₄的固相反应. MgAl₂O₄纳米粉体显示了良好的烧结活性, 在1450℃烧结1 h即能获得相对密度为95%的MgAl₂O₄陶瓷.

关键词: MgAl₂O₄, 纳米粉体, 固相反应, 煅烧, 烧结

Abstract: Well-crystallized MgAl₂O₄ nanopowders were prepared by calcining a powder mixture of Al(OH)₃ and MgSO₄ at 800℃, and then washing with water. The effect of Mg/Al atomic ratios on the particle sizes and agglomeration degrees, and sintering behavior of MgAl₂O₄ nanopowders were studied by differential thermal and thermogravimetric analysis (DSC/TG), X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). The obtained MgAl₂O₄ nanopowders have an average particle size of 12 nm, a narrow size distribution, and weak agglomeration. The formation of MgAl₂O₄ can be attributed to a solid-state reaction between γ-Al₂O₃ and MgSO₄. Besides, these MgAl₂O₄ nanopowders own an excellent sinterability, e.g., a relative density of 95% can be achieved after sintered at 1450℃ for 1 h.

Key words: MgAl₂O₄, nanopowders, solid-state reaction, calcination, sintering

中图分类号:

TQ174

苏兴华, 李建功, 周振君. 固相反应法制备MgAl₂O₄纳米粉体及其烧结行为研究[J]. 无机材料学报, 2012, 27(9): 991-996.

SU Xing-Hua, LI Jian-Gong, ZHOU Zhen-Jun. Solid-state Reaction Preparation and Sintering Behavior of MgAl₂O₄ Nanopowders[J]. Journal of Inorganic Materials, 2012, 27(9): 991-996.

参考文献

[1] Huang Cun-Xin, Peng Zai-Xue, Wang Yan-Peng, et al. Study on transparent mechanism of polycrystalline MgAl2O4. Journal of Synthetic Crystals, 1995, 24(3): 198-202.

[2] Liu Wei, Wu Deng-Hui. Preparation of ultrafine magnesium aluminate spinel powders by alkoxide hydrolysis process. Shandong Ceramics, 2009, 32(1): 33-35.

[3] Yuan Ying, Zhang Shu-Ren, You Wen-Nan. Aluminium semi-alkoxide Sol-Gel synthesis and sintering behavior of MgAl2O4 spinel powder. Journal of Inorganic Materials, 2004, 19(4): 755-760.

[4] Zhang Xian, Zeng Qing-Feng, Hao Fu-Suo. Synthesis of MgAl2O4 spinel nanopowder by Sol-Gel process. Bulletin of the Chinese Ceramic Society, 2009, 28(S1): 130-133.

[5] Li J G, Ikegami T, Lee J H, et al. A wet-chemical process yielding reactive magnesium aluminate spinel (MgAl2O4) powder. Ceram. Int., 2001, 27(4): 481-489.

[6] Shiono T, Shiono K, Miyamoto K, et al. Synthesis and characterization of (MgAl2O4) spinel precursor from a heterogeneous alkoxide solution containing fine MgO powder. J. Am. Ceram. Soc., 2000, 83(1): 235-237.

[7] Ye G, Oprea G, Troczynski T. Synthesis of MgAl2O4 spinel powder by combination of Sol-Gel and precipitation processes. J. Am. Ceram. Soc., 2005, 88(11): 3241-3244.

[8] Saberi A, Golestani-Fard F, Willert-Porada M, et al. A novel approach to synthesis of nanosize MgAl2O4 spinel powder through Sol-Gel citrate technique and subsequent heat treatment. Ceram. Int., 2009, 35(3): 933-937.

[9] Li G, Sun Z, Chen C, et al. Synthesis of nanocrystalline MgAl2O4 spinel powders by a novel chemical method. Mater. Lett., 2007, 61(17): 3585-3588.

[10] Lee P Y, Suematsu H, Yano T, et al. Synthesis and characterization of nanocrystalline MgAl2O4 spinel by polymerized complex method. J. Nanopart. Res., 2006, 8(6): 911-917.

[11] Alinejad B, Sarpoolaky H, Beitollahi A, et al. Synthesis and characterization of nanocrystalline MgAl2O4 spinel via sucrose process. Mater. Res. Bull., 2008, 43(5): 1188-1194.

[12] Iano- R, Laz-u R. Combustion synthesis, characterization and sintering behavior of magnesium aluminate (MgAl2O4) powders. Mater. Chem. Phys., 2009, 115(2/3): 645-648.

[13] Domanski D, Urretavizcaya G, Castro F J, et al. Mechanochemical synthesis of magnesium aluminate spinel powder at room temperature. J. Am. Ceram. Soc., 2004, 87(11): 2020-2024.

[14] Ple-ingerová B, -tevulová N, Luxová M, et al. Mechanochemical synthesis of magnesium aluminate spinel in oxide-hydroxide systems. J. Mater. Synth. Process, 2000, 8(5/6): 287-293.

[15] Levin I, Brandon D. Metastable alumina polymorphs: crystal structures and transition sequences. J. Am. Ceram. Soc., 1998, 81(8): 1995-2012.

[16] Perry D L, Phillips S L. Handbook of Inorganic Compounds: Version 2.0. CRC press, Florida, 1995: 245.

[17] Klug H P, Alexander L E. X-ray Diffraction Procedure for Polycrystalline and Amorphous Materials: 2nd ed. Wiley, New York, 1974: 634.

[18] Ryskhewitch E. Oxide Ceramics. Academic Press, New York, 1960: 271.

固相反应法制备MgAl₂O₄纳米粉体及其烧结行为研究

Solid-state Reaction Preparation and Sintering Behavior of MgAl₂O₄ Nanopowders

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王康龙, 殷杰, 陈晓, 王力, 刘学建, 黄政仁. 颗粒级配对选区激光烧结打印结合常压固相烧结制备碳化硅陶瓷性能的影响[J]. 无机材料学报, 2024, 39(7): 754-760.
[2]	刘焱, 覃显鹏, 甘霖, 周国红, 章天金, 王士维, 陈鹤拓. 亚微米球形Y₂O₃粉体及其透明陶瓷的制备[J]. 无机材料学报, 2024, 39(6): 691-696.
[3]	王伟明, 王为得, 粟毅, 马青松, 姚冬旭, 曾宇平. 以非氧化物为烧结助剂制备高导热氮化硅陶瓷的研究进展[J]. 无机材料学报, 2024, 39(6): 634-646.
[4]	郑斌, 康凯, 张青, 叶昉, 解静, 贾研, 孙国栋, 成来飞. 前驱体转化陶瓷法制备Ti₃SiC₂陶瓷及其热稳定性研究[J]. 无机材料学报, 2024, 39(6): 733-740.
[5]	郑雅雯, 张翠萍, 张瑞杰, 夏乾, 茹红强. 硼酸碳热还原-渗硅反应烧结制备碳化硼陶瓷复合材料[J]. 无机材料学报, 2024, 39(6): 707-714.
[6]	何宗倍, 陈放, 刘佃光, 李统业, 曾强. 模拟核芯FCM燃料的振荡烧结行为研究[J]. 无机材料学报, 2024, 39(5): 501-508.
[7]	吕朝阳, 徐勇, 杨久延, 涂广升, 涂兵田, 王皓. MgF₂助剂对MgAl_1.9Ga_0.1O₄透明陶瓷的制备与光学性能的影响[J]. 无机材料学报, 2024, 39(5): 531-538.
[8]	张婷婷, 王方园, 刘长友, 张国荣, 吕佳辉, 宋宇晨, 介万奇. 水热-烧结法制备Cr²⁺:ZnSe/ZnSe核壳结构纳米孪晶[J]. 无机材料学报, 2024, 39(4): 409-415.
[9]	江强, 施立志, 陈政燃, 周志勇, 梁瑞虹. 高于居里温度极化的硬性PZT压电陶瓷的制备及叠层驱动器性能研究[J]. 无机材料学报, 2024, 39(10): 1091-1099.
[10]	彭萍, 谭礼涛. CuO掺杂(Ba,Ca)(Ti,Sn)O₃陶瓷的结构与压电性能[J]. 无机材料学报, 2024, 39(10): 1100-1106.
[11]	王博, 蔡德龙, 朱启帅, 李达鑫, 杨治华, 段小明, 李雅楠, 王轩, 贾德昌, 周玉. SrAl₂Si₂O₈增强BN陶瓷的力学性能及抗热震性能[J]. 无机材料学报, 2024, 39(10): 1182-1188.
[12]	柯鑫, 谢炳卿, 王忠, 张敬国, 王建伟, 李占荣, 贺会军, 汪礼敏. 第三代半导体互连材料与低温烧结纳米铜材的研究进展[J]. 无机材料学报, 2024, 39(1): 17-31.
[13]	李俊生, 曾良, 刘荣军, 王衍飞, 万帆, 李端. 锶钽氧氮化物功能陶瓷的高效合成、致密化及介电性能研究[J]. 无机材料学报, 2023, 38(8): 885-892.
[14]	吴俊林, 丁继扬, 黄新友, 朱丹阳, 黄东, 代正发, 杨文钦, 蒋兴奋, 周健荣, 孙志嘉, 李江. Gd₂O₂S:Tb闪烁陶瓷的制备与结构: 水浴合成中H₂SO₄/Gd₂O₃摩尔比的影响[J]. 无机材料学报, 2023, 38(4): 452-460.
[15]	冯静静, 章游然, 马名生, 陆毅青, 刘志甫. 冷烧结技术的研究现状及发展趋势[J]. 无机材料学报, 2023, 38(2): 125-136.