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无机材料学报

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钛酸纳米管的制备及 TEM表征

黄琮1,4, 张开坚2,3, 党志1, 李新军4   

  1. 1. 华南理工大学环境科学与工程学院, 广州 510640;
    2. 重庆大学经济与工商管理学院, 重庆 400044;
    3. 攀钢集团攀枝花钢铁研究院, 攀枝花 617000;
    4. 中科院广州能源研究所, 广州 510640
  • 收稿日期:2005-05-23 修回日期:2005-07-11 出版日期:2006-05-20 网络出版日期:2006-05-20

Preparation of Trititanate Nanotube and TEM Observation

HUANG Cong1,4, ZHANG Kai-Jian2,3, DANG Zhi1, Li Xin-Jun4   

  1. 1. College of Environmental Science and Engineering, South China University
    of Technology, Guangzhou 510640, China;
    2. Economy, Industry and Business Management College, Chongqing University, Chongqing 400044, China;
    3. Panzhihua Iron & Steel Research Institute, Panzhihua I & S Ltd. Co, Panzhihua 617000, China;
    4. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
  • Received:2005-05-23 Revised:2005-07-11 Published:2006-05-20 Online:2006-05-20

PDF (PC)

1893

被引次数

6

摘要： 采用水热合成法以金红石型纳米TiO2粉为原料制备钛酸纳米管, 考察了搅拌、酸洗及焙烧温度对纳米管的形成和结构的影响, 并通过TEM观察了产物的形貌、结构. 结果显示: 持续搅拌能促进原料粉末的定向生长, 有利于形成钛酸纳米片;酸洗是纳米管的形成阶段; 300℃是纳米管转变为长棒状晶柱的临界温度. 实验表明以优化的水热合成法制得的纳米管形貌均一, 长度超过1μm, 钛酸纳米管长径比为125:1.

关键词: 钛酸纳米管, 制备, TEM表征

Abstract:

Trititanate nanotubes were synthesized from rutile TiO2 via hydrothermal process. The influences of process parameters such as stirring, acid leaching and calcination temperature on formation and structure of nanotubes were observed by TEM. The results show that continuous stirring could improve the directional growth of TiO2 particles and formation of trititanate nanoflakes, and nanotubes are formed in the acid leaching process. It also reveals that 300℃ is the critical transformation temperature between nanotubes and long-stick crystalline column. The nanotubes synthesized under optimal condition are uniform and longer than 1μm, and the ratio of length to diameter is 125:1.

Key words: trititanate nanotube, preparation, TEM

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