Nafion改性多级孔径石墨烯气凝胶制备与性能研究

doi:10.15541/jim20170165

无机材料学报 ›› 2018, Vol. 33 ›› Issue (4): 469-474.DOI: 10.15541/jim20170165 CSTR: 32189.14.10.15541/jim20170165

所属专题：乘风破浪的新能源材料

• • 上一篇

Nafion改性多级孔径石墨烯气凝胶制备与性能研究

王勇^1,2, 于云¹, 冯爱虎^1,2, 江峰^1,2, 胡学兵³, 宋力昕¹

1. 中国科学院上海硅酸盐研究所无机涂层重点实验室, 上海 200050;
2. 中国科学院大学, 北京 100049;
3. 景德镇陶瓷大学江西省高等学校无机膜重点实验室, 景德镇 333001

收稿日期:2017-04-10 出版日期:2018-04-30 网络出版日期:2018-03-27
作者简介:王勇. E-mail: ouyuu@foxmail.com

Nafion Modified Graphene Aerogel with Hierarchical Porous Structures

WANG Yong^1,2, YU Yun¹, FENG Ai-Hu^1,2, JIANG Feng^1,2, HU Xue-Bing³, SONG Li-Xin¹

1. Chinese Academy of Sciences Key Laboratory of Inorganic Coating Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China;
3. Key Laboratory of Inorganic Membrane, Jindezhen Ceramic Institute, Jingdezhen 333001, China

Received:2017-04-10 Published:2018-04-30 Online:2018-03-27
About author:WANG Yong (1984-), male, candidate of PhD. E-mail: ouyuu@foxmail.com
Supported by:
National Natural Science Foundation of China (51662019)

摘要/Abstract

摘要：

通过溶胶-凝胶法制备了孔径小于1 μm的多级孔径新型石墨烯气凝胶。制备过程中, 首先通过Nafion对氧化石墨烯(GO)表面进行化学修饰, 并利用乙二胺还原制备石墨烯水凝胶, 最终通过冷冻干燥形成石墨烯气凝胶。实验发现Nafion可以有效减少制备过程中氧化石墨烯的团聚, 使石墨烯气凝胶形成多级孔径形貌。所得石墨烯气凝胶的孔径可控制在1 μm以内, 远小于传统石墨烯气凝胶材料的孔径(20~100 μm)。这种具有独特结构的石墨烯气凝胶表现出优异的性能, 例如高比表面积, 高孔隙率, 其电化学电容性能相对传统气凝胶提高了约40%。

关键词: 三维石墨烯, 石墨烯气凝胶, 石墨烯, 氧化石墨烯, Nafion

Abstract:

A novel graphene aerogel with pore size less than 1 µm was synthesized by Sol-Gel method, in which Nafion was skillfully introduced as modifiers connecting graphene oxides (GO). Ethylenediamine was used to produce a chemically linked graphene hydrogel during reducing process, which can then be freeze-dried to remove the absorbed water to form graphene aerogel. Nafion in GO solution prohibits the re-stacking of individual graphene sheets during reduction and freeze-drying process. By the above method, the pore size of as-prepared graphene aerogel could be effectively controlled within 1 µm, much less than that of the traditional graphene aerogel (20- 100 µm). The new graphene aerogel with unique structure exhibited excellent properties, such as high specific surface area, high porosity, and better electrochemical properties. All data suggest that this graphene aerogel may have promising application prospect in the field of energy.

Key words: three-dimensional graphene, graphene aerogel, graphene, graphene oxide, Nafion

中图分类号:

O613

王勇, 于云, 冯爱虎, 江峰, 胡学兵, 宋力昕. Nafion改性多级孔径石墨烯气凝胶制备与性能研究[J]. 无机材料学报, 2018, 33(4): 469-474.

WANG Yong, YU Yun, FENG Ai-Hu, JIANG Feng, HU Xue-Bing, SONG Li-Xin. Nafion Modified Graphene Aerogel with Hierarchical Porous Structures[J]. Journal of Inorganic Materials, 2018, 33(4): 469-474.

图/表 8

Fig. 1 AFM height image of GO (a), GO modified with Nafion (b) and the height profiles of GO (c) and GO modified with Nafion (d)

Fig. 2 XRD patterns of GO, rGO, graphite, GA and GA-Nafion

Fig. 3 Raman spectra of GO, rGO, GA and GA-Nafion

Fig. 4 FT-IR spectra of GO, rGO, GA and GA-Nafion

Fig. 5 SEM morphologies of GA (a), GO nano sheets modified with Nafion (b), GA-Nafion (c) and its high resolution morphology (d)

Fig. 6 Chemical structure of Nafion

Fig. 7 Specific surface area of GO, rGO, GO-EDA, and GA-Nafion

Fig. 8 Cyclic voltammogram of activated carbon (AC), GA and GA-Nafion

参考文献 18

[1]	ALLEN M J, TUNG V C, KANER R B.Honeycomb carbon: a review of graphene.Chemical Reviews, 2010, 110(1): 132-145.
[2]	NAIR R R, BLAKE P, GRIGORENKO A N, et al. Science. Science, 2008, 320(5881): 1308-1308.
[3]	CHEN H, GAO H, XIAO H W, et al. Electrochimica Acta. Electrochimica Acta, 2016, 206: 10-16.
[4]	OH J, YOO H, CHOI J, et al. Nano Energy. Nano Energy, 2017, 35: 26-35.
[5]	BALANDIN A A, GHOSH S, BAO W, et al. Nano Letters. Nano Letters, 2008, 8(3): 902-907.
[6]	JO Y K, KIM I Y, KIM S J, et al. RSC Advances. RSC Advances, 2015, 5(20): 19259-19263.
[7]	PALERMO V, KINLOCH I A, LIGI S, et al. Advanced Materials. Advanced Materials, 2016, 28(29): 6232-6238.
[8]	DU J, CHENG H M.The fabrication, properties, and uses of graphene/polymer composites.Macromolecular Chemistry and Physics, 2012, 213(10/11): 1060-1077.
[9]	ZHU C, LIU T, QIAN F, et al. Nano Letters. Nano Letters, 2016, 16(6): 3448-3456.
[10]	WANG J, CHEN B, XING B.Wrinkles and folds of activated graphene nanosheets as fast and efficient adsorptive sites for hydrophobic organic contaminants.Environmental Science & Technology, 2016, 50(7): 3798-3808.
[11]	AHN W, SEO M H, JUN Y S, et al. ACS Applied Materials & Interfaces. ACS Applied Materials & Interfaces, 2016, 8(3): 1984-1991.
[12]	SHI J L, TANG C, PENG H J, et al. Small. Small, 2015, 11(39): 5243-5252.
[13]	KOTAL M, KIM J, OH J, et al. Frontiers in Materials. Frontiers in Materials, 2016, 3: 29.
[14]	DREYER D R, PARK S, BIELAWSKI C W, et al. Chemical Society Reviews. Chemical Society Reviews, 2010, 39(1): 228-240.
[15]	ZHANG X, SUI Z, BIN X, et al. Journal of Materials Chemistry. Journal of Materials Chemistry, 2011, 21(18): 6494-6497.
[16]	XIE X, ZHOU Y, BI H, et al. Scientific Reports. Scientific Reports, 2013, 3: 2117.
[17]	KRISHNAMOORTHY K, VEERAPANDIAN M, MOHAN R, et al. Applied Physics A: Materials Science & Processing. Applied Physics A: Materials Science & Processing, 2012, 106(3): 501-506.
[18]	SHI W, BAKER L A.Imaging heterogeneity and transport of degraded Nafion membranes.RSC Advances, 2015, 5(120): 99284-99290.

Nafion改性多级孔径石墨烯气凝胶制备与性能研究

Nafion Modified Graphene Aerogel with Hierarchical Porous Structures

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 18

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李红兰, 张俊苗, 宋二红, 杨兴林. Mo/S共掺杂的石墨烯用于合成氨: 密度泛函理论研究[J]. 无机材料学报, 2024, 39(5): 561-568.
[2]	孙川, 何鹏飞, 胡振峰, 王荣, 邢悦, 张志彬, 李竞龙, 万春磊, 梁秀兵. 含有石墨烯阵列的SiC基陶瓷材料的制备与力学性能[J]. 无机材料学报, 2024, 39(3): 267-273.
[3]	王艳莉, 钱心怡, 沈春银, 詹亮. 石墨烯基介孔锰铈氧化物催化剂: 制备和低温催化还原NO[J]. 无机材料学报, 2024, 39(1): 81-89.
[4]	杨平军, 李铁虎, 李昊, 党阿磊. 石墨烯对环氧树脂泡沫炭石墨化、电导率和力学性能的影响[J]. 无机材料学报, 2024, 39(1): 107-112.
[5]	董怡曼, 谭占鳌. 宽带隙钙钛矿基二端叠层太阳电池复合层的研究进展[J]. 无机材料学报, 2023, 38(9): 1031-1043.
[6]	陈赛赛, 庞雅莉, 王娇娜, 龚䶮, 王锐, 栾筱婉, 李昕. 绿-黄可逆电热致变色织物的制备及其性能[J]. 无机材料学报, 2022, 37(9): 954-960.
[7]	孙铭, 邵溥真, 孙凯, 黄建华, 张强, 修子扬, 肖海英, 武高辉. RGO/Al复合材料界面性质第一性原理研究[J]. 无机材料学报, 2022, 37(6): 651-659.
[8]	安琳, 吴淏, 韩鑫, 李耀刚, 王宏志, 张青红. 非贵金属Co_5.47N/N-rGO助催化剂增强TiO₂光催化制氢性能[J]. 无机材料学报, 2022, 37(5): 534-540.
[9]	王虹力, 王男, 王丽莹, 宋二红, 赵占奎. 功能化石墨烯担载型AuPd纳米催化剂增强甲酸制氢反应[J]. 无机材料学报, 2022, 37(5): 547-553.
[10]	董淑蕊, 赵笛, 赵静, 金万勤. 离子化氨基酸对氧化石墨烯膜渗透汽化过程中水选择性渗透的影响[J]. 无机材料学报, 2022, 37(4): 387-394.
[11]	蒋丽丽, 徐帅帅, 夏宝凯, 陈胜, 朱俊武. 缺陷调控石墨烯复合催化剂在氧还原反应中的作用[J]. 无机材料学报, 2022, 37(2): 215-222.
[12]	吴静, 余立兵, 刘帅帅, 黄秋艳, 姜姗姗, ANTON Matveev, 王连莉, 宋二红, 肖蓓蓓. NiN₄/Cr修饰的石墨烯电化学固氮电极[J]. 无机材料学报, 2022, 37(10): 1141-1148.
[13]	李铁, 李玥, 王颖异, 张珽. 石墨烯-铁酸铋纳米晶复合材料的制备及其催化性能研究[J]. 无机材料学报, 2021, 36(7): 725-732.
[14]	向晖, 全慧, 胡艺媛, 赵炜骞, 徐波, 殷江. 类石墨烯单层结构ZnO和GaN的压电特性对比研究[J]. 无机材料学报, 2021, 36(5): 492-496.
[15]	李豪, 唐志红, 卓尚军, 钱荣. 基于ZIF8/rGO的高性能NO₂室温传感器[J]. 无机材料学报, 2021, 36(12): 1277-1282.