单源热蒸发制备有机无机杂化CH3NH3PbI3薄膜及其性能表征

doi:10.15541/jim20150098

无机材料学报 ›› 2015, Vol. 30 ›› Issue (10): 1105-1109.DOI: 10.15541/jim20150098

单源热蒸发制备有机无机杂化CH₃NH₃PbI₃薄膜及其性能表征

范平^1,2, 古迪¹, 梁广兴^1,2, 罗景庭^1,2, 张东平^1,2, 陈聚龙¹

(1. 深圳大学物理科学与技术学院, 薄膜物理与应用研究所, 深圳518060; 2. 深圳市传感器技术重点实验室, 深圳518060)

收稿日期:2015-02-12 修回日期:2015-05-18 出版日期:2015-10-20 网络出版日期:2015-09-30
基金资助:
国家自然科学青年基金(61404086);中央财政支持地方高校发展专项基金(000022070150);深圳市传感器技术重点实验室开放基金(SST201401)

Growth and Characterization of Hybrid Organolead Halide CH₃NH₃PbI₃ Thin Films Prepared by Single Source Thermal Evaporation

FAN Ping^1,2, GU Di¹, LIANG Guang-Xing^1,2, LUO Jing-Ting^1,2, ZHANG Dong-Ping^1,2, CHEN Ju-Long¹

(1. Institute of Thin Film Physics and Applications, College of Physics Science and Technology, Shenzhen University, Shenzhen 518060, China; 2. Shenzhen Key Laboratory of Sensor Technology, Shenzhen University, Shenzhen 518060, China)

Received:2015-02-12 Revised:2015-05-18 Published:2015-10-20 Online:2015-09-30
Supported by:
National Natural Science Foundation of China (61404086);Central Finance for the Development of Local Universities (000022070150);Shenzhen Key Laboratory of Sensor Technology Open Project (SST201401)

摘要/Abstract

摘要：

采用全真空单源热蒸发沉积技术直接制备钙钛矿太阳电池用有机无机杂化CH₃NH₃PbI₃薄膜。利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、能量色散谱仪(EDS)和分光光度计对制备的CH₃NH₃PbI₃薄膜微结构、表面形貌、化学成分和光学性能进行表征分析, 并与非真空旋涂法制备的CH₃NH₃PbI₃薄膜性能进行比较。结果表明: 单源热蒸发法制备的CH₃NH₃PbI₃薄膜呈现单一的钙钛矿四方晶体结构, 且与蒸发源材料的晶体结构同源性高, 没有出现杂质相偏析; 对比旋涂法制备的CH₃NH₃PbI₃薄膜表面均匀致密平整, 且薄膜结晶度更高; 单源热蒸发法制备的CH₃NH₃PbI₃薄膜禁带宽度为1.57 eV, 符合钙钛矿太阳电池吸收层光学性能要求。

关键词: 单源热蒸发法, CH3NH3PbI3薄膜, 钙钛矿太阳电池, 微结构

Abstract:

Hybrid organolead halide CH₃NH₃PbI₃ thin films were prepared by thermal evaporation with single source. The microstructure, composition, surface morphology and optical properties of the thin films were characterized by X-ray diffractometry (XRD), X-ray dispersive spectroscope (EDS), scanning electron microscope (SEM) and spectrophotometer technique, respectively. The comparison on properties for the films prepared by different methods (thermal evaporation and spin coating) was illustrated. Compared to the film prepared by spin coating, uniform, the nonporous and complete surface coverage perovskite thin film with high level of phase purity and good crystallization is formed by single source thermal evaporation. A direct bandgap of 1.57 eV for CH₃NH₃PbI₃ thin films is obtained which makes this material to be a good light absorber.

Key words: thermal evaporation, CH3NH3PbI3 thin films, perovskite solar cell, microstructure

中图分类号:

O649

范平, 古迪, 梁广兴, 罗景庭, 张东平, 陈聚龙. 单源热蒸发制备有机无机杂化CH₃NH₃PbI₃薄膜及其性能表征[J]. 无机材料学报, 2015, 30(10): 1105-1109.

FAN Ping, GU Di, LIANG Guang-Xing, LUO Jing-Ting, ZHANG Dong-Ping, CHEN Ju-Long. Growth and Characterization of Hybrid Organolead Halide CH₃NH₃PbI₃ Thin Films Prepared by Single Source Thermal Evaporation[J]. Journal of Inorganic Materials, 2015, 30(10): 1105-1109.

图/表 6

图1 不同方法制备的CH3NH3PbI3薄膜的XRD图谱

Fig. 1 XRD patterns of CH3NH3PbI3 thin films prepared by different methods. (a) Spin coating; (b) CH3NH3PbI3 powder; (c) Single source thermal evaporation

表1 不同方法制备的CH3NH3PbI3薄膜(110)峰的晶粒尺寸和半高宽

Table 1 FWHM and grain size of CH3NH3PbI3 (110) diffraction peak prepared by different methods

Methods	FWHM/(°)	Grain size/nm
Powder	0.373	22.3
Single source thermal evaporation	0.391	21.2
Spin coating	0.489	16.7

表 2 不同方法制备的CH3NH3PbI3薄膜的成分

Table 2 Elemental composition of CH3NH3PbI3 prepared by different methods

Methods	Elemental composition /at%		Pb/I
Methods	Pb	I	Pb/I
Powder	25.24	74.76	0.34
Single source thermal evaporation	25.05	74.95	0.33
Spin coating	25.24	74.76	0.34

图2 不同方法制备的CH3NH3PbI3薄膜的成分分布图

Fig. 2 Distribution of elemental composition of CH3NH3PbI3 prepared by different methods. (a,b,c) Spin coating; (d,e,f) Single source thermal evaporation

图3 不同方法制备的CH3NH3PbI3薄膜的表面形貌

Fig. 3 SEM images of surface morphology of CH3NH3PbI3 prepared by different methods. (a,b) Spin coating; (c,d) Single source thermal evaporation

图4 不同方法制备CH3NH3PbI3薄膜的透射率曲线

Fig. 4 Transmitted spectra of CH3NH3PbI3 prepared by different methods. (a) Single source thermal evaporation; (c) Spin coating

参考文献 14

[1]	MALINKIEWICZ O, YELLA A, LEE YH, et al.Perovskite solar cells employing organic charge-transport layers.Nature Photonics,2013, 8(2):128-132.
[2]	GONZALEZ-PEDRO V, JUAREZ-PEREZ EJ, ARSYAD WS, et al.General working principles of CH3NH3PbX3 perovskite solar cells.Nano Letters, 2014, 14(2):888-893.
[3]	STRANKS SD, EPERON GE, GRANCINI G,et al.Electron- hole diffusion lengths exceeding 1 nicrometerinan organometal trihalide perovskite absorber.Science, 2013, 342(6156): 341-344.
[4]	KOJIMA A, TESHIMA K, SHIRAI Y, et al.Organometal halide perovskitesas visible-light sensitizers for photovoltaic cells.Journal of the American Chemical Society, 2009, 131(17):6050-6051.
[5]	(updated on Dec. 18, 2014).
[6]	IM J H, LEE C R, LEE J W, et al. 6.5% efficient perovskite quantum-dot-sensitized solar cell. Nanoscale, 2011, 3(10):4088-4093.
[7]	LIU M, JOHNSTON M B, SNAITH H J.Efficient planar heterojunction perovskite solar cells by vapour deposition.Nature, 2013, 501(7467):395-398.
[8]	HE M, ZHENG D, WANG M, et al.High efficiency perovskite solar cells: from complex nanostructure to planar heterojunction.Journal of Materials Chemistry A, 2014, 2(17):5994.
[9]	ZHOU H, CHEN Q, LI G, et al.Interface engineering of highly efficient perovskite solar cells. Science, 2014, 345(6196): 542-546.
[10]	LEE M M, TEUSCHER J, MIYASAKA T, et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites.Science, 2012, 338(6107): 643-647.
[11]	BURSCHKA J, PELLET N, MOON S J, et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells.Nature, 2013, 499(7458):316-319.
[12]	CHEN Q, ZHOU H, HONG Z, et al.Planar heterojunction perovskite solar cells prepared by vapor-assisted solution process solution process.Journal of the American Chemical Society, 2014, 136(2):622-626.
[13]	SHI J, DONG J, LV S, et al.Hole-conductor-free perovskite organic lead iodide heterojunction thin-film solar cells: high efficiency and junction property.Applied Physics Letters, 2014, 104(6): 063901.
[14]	BAIKIE T, FANG Y, KADRO J M, et al.Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitized solar cell applications.Journal of Materials Chemistry A, 2013, 1(18):5628-5641.

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单源热蒸发制备有机无机杂化CH₃NH₃PbI₃薄膜及其性能表征

Growth and Characterization of Hybrid Organolead Halide CH₃NH₃PbI₃ Thin Films Prepared by Single Source Thermal Evaporation

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