石墨烯装载不同含量钴锌铁氧体及其电磁行为对比

doi:10.15541/jim20180280

Journal of Inorganic Materials ›› 2019, Vol. 34 ›› Issue (4): 407-416.doi: 10.15541/jim20180280

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Comparison of Electromagnetism Behavior of Different Content Cobalt-zinc Ferrite Loaded with Graphene

Zhi-Jun MA,Chang-Ye MANG,Hai-Tao ZHAO,Zhi-Hao GUAN,Liang CHENG

College of Mining, Liaoning Technical University, Fuxin 123000, China

Received:2018-06-22 Revised:2018-10-22 Online:2019-04-20 Published:2019-04-15
Supported by:
National Natural Science Foundation of China(51372108)

Abstract

Abstract:

A kind of graphene composite (rGO/Co_0.5Zn_0.5Fe₂O₄) was synthesized with the graphene oxide (GO) prepared from natural flake graphite and cobalt-zinc ferrite (Co_0.5Zn_0.5Fe₂O₄) manufactured by the hydrothermal method. The structure of composites was characterized by X-ray diffraction (XRD), Raman spectrometer (Raman) and the Fourier-transform infrared spectroscopy (FT-IR). Morphology, electromagnetic loss properties, Debye relaxation, and microwave absorbing properties of rGO/Co_0.5Zn_0.5Fe₂O₄ were investigated by transmission electron microscope (TEM) and vector network analyser (VNA). Sharp peak of graphene oxide was changed from 2θ=9.74° to 24.15° in the XRD patterns and the oxygen functional group disappeared after the composite reaction, which demonstrated that GO was successfully reduced to rGO. The graphene was embedded with cobalt-zinc ferrite, observed by transmission electron microscope, with its dispersion worse with the loaded Co_0.5Zn_0.5Fe₂O₄ increasing. Absorbing property of rGO/Co_0.5Zn_0.5Fe₂O₄ composite prepared with w(Co_0.5Zn_0.5Fe₂O₄) : w(GO)= 2 : 1 is the best with the minimum reflectivity of -36.89 dB at 15.11 GHz and the effective absorption frequency bandwidth of 3.74.

Key words: graphene, composite materials, cobalt-zinc ferrite, electromagnetic behavior, graphene oxide

CLC Number:

TM277

Zhi-Jun MA, Chang-Ye MANG, Hai-Tao ZHAO, Zhi-Hao GUAN, Liang CHENG. Comparison of Electromagnetism Behavior of Different Content Cobalt-zinc Ferrite Loaded with Graphene[J]. Journal of Inorganic Materials, 2019, 34(4): 407-416.

Figures/Tables 9

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References 50

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Structural formula	2θ/(°)	a/nm	(311) Priority crystallization diffraction peak
Structural formula	2θ/(°)	a/nm	FWHM/rad	Intensity/(a.u.)	Size/nm
Co_0.5Zn_0.5Fe₂O₄	35.597	0.8391	0.618	86	13.8
rGO/Co_0.5Zn_0.5Fe₂O₄	35.595	0.8358	0.466	94	17.7

Comparison of Electromagnetism Behavior of Different Content Cobalt-zinc Ferrite Loaded with Graphene

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