Journal of Inorganic Materials ›› 2021, Vol. 36 ›› Issue (11): 1163-1170.DOI: 10.15541/jim20210109
• RESEARCH ARTICLE • Previous Articles Next Articles
GUO Yu(), JIANG Xiaoqing, WU Hongmei, XIAO Yu, WU Dafu, LIU Xin
Received:
2021-02-23
Revised:
2021-04-26
Published:
2021-11-20
Online:
2021-04-30
About author:
GUO Yu(1981-), male, professor. E-mail: guoyu@lnut.edu.cn
Supported by:
CLC Number:
GUO Yu, JIANG Xiaoqing, WU Hongmei, XIAO Yu, WU Dafu, LIU Xin. Preparation of 2-hydroxy-1-naphthalene Functionalized SBA-15 Adsorbent for the Adsorption of Chromium(III) Ions from Aqueous Solution[J]. Journal of Inorganic Materials, 2021, 36(11): 1163-1170.
Sample | SBET/(cm2·g-1) | Pore size/nm |
---|---|---|
SBA-15 | 757 | 9.6 |
Q-SBA-15 | 283 | 6.7 |
Table 1 Textural properties of the synthesized samples
Sample | SBET/(cm2·g-1) | Pore size/nm |
---|---|---|
SBA-15 | 757 | 9.6 |
Q-SBA-15 | 283 | 6.7 |
Temperature /℃ | Langmuir | Freundlich | |||||
---|---|---|---|---|---|---|---|
qm/(g·mg-1) | KL | R2 | KF | n | R2 | ||
30 | 106.84 | 0.09 | 0.988 | 24.59 | 3.12 | 0.836 | |
40 | 108.23 | 0.25 | 0.997 | 48.39 | 5.47 | 0.913 | |
50 | 112.74 | 0.41 | 0.997 | 42.72 | 4.27 | 0.697 |
Table 2 Different model parameters for adsorption of Cr(III) by Q-SBA-15 at different temperatures
Temperature /℃ | Langmuir | Freundlich | |||||
---|---|---|---|---|---|---|---|
qm/(g·mg-1) | KL | R2 | KF | n | R2 | ||
30 | 106.84 | 0.09 | 0.988 | 24.59 | 3.12 | 0.836 | |
40 | 108.23 | 0.25 | 0.997 | 48.39 | 5.47 | 0.913 | |
50 | 112.74 | 0.41 | 0.997 | 42.72 | 4.27 | 0.697 |
Fig. 8 XPS spectra of Q-SBA-15 (a) Overview spectra of Q-SBA-15 before and after Cr(III) adsorption; (b) Cr2p spectrum of Q-SBA-15 after Cr(III) adsorption; C1s spectra of (c) Q-SBA-15 (before adsorption) and (d) Q-SBA-15 (after adsorption); N1s spectra of (e) Q-SBA-15 (before adsorption) and (f) Q-SBA-15 (after adsorption)
Sample | qe,exp/(mg·g-1) | Pseudo first-order model | Pseudo second-order model | ||||
---|---|---|---|---|---|---|---|
K1/ min-1 | qe,cal/(mg·g-1) | R2 | K2/(g·mg-1·min-1) | qe,cal/(mg·g-1) | R2 | ||
Q-SBA-15 | 102.3 | 0.0647 | 61.75 | 0.857 | 4.26×10-4 | 119.19 | 0.979 |
Table S1 Kinetic parameters for Cr(III) adsorption onto Q-SBA-15
Sample | qe,exp/(mg·g-1) | Pseudo first-order model | Pseudo second-order model | ||||
---|---|---|---|---|---|---|---|
K1/ min-1 | qe,cal/(mg·g-1) | R2 | K2/(g·mg-1·min-1) | qe,cal/(mg·g-1) | R2 | ||
Q-SBA-15 | 102.3 | 0.0647 | 61.75 | 0.857 | 4.26×10-4 | 119.19 | 0.979 |
Adsorbent | qm/(mg·g-1) | References |
---|---|---|
Biomass-based hydrogel | 41.7 | [1] |
m-MCM-41-NH2 | 36.92 | [2] |
Graphene oxide | 13.3 | [3] |
Thiol-functionalized MCM-41 | 15.34 | [4] |
TS-SBA-15 | 95.68 | [5] |
NH2-SBA-15 | 24.88 | [6] |
Q-SBA-15 | 102.3 | This work |
Table S2 Comparison of Cr(III) adsorption performance with different materials selected from literature
Adsorbent | qm/(mg·g-1) | References |
---|---|---|
Biomass-based hydrogel | 41.7 | [1] |
m-MCM-41-NH2 | 36.92 | [2] |
Graphene oxide | 13.3 | [3] |
Thiol-functionalized MCM-41 | 15.34 | [4] |
TS-SBA-15 | 95.68 | [5] |
NH2-SBA-15 | 24.88 | [6] |
Q-SBA-15 | 102.3 | This work |
Sample | Tempera- ture/K | Kc | ΔG/ (kJ·mol-1) | ΔS/ (kJ·mol·K-1) | ΔH/ (kJ·mol-1) |
---|---|---|---|---|---|
Q-SBA-15 | 293 | 1.846 | -4.386 | 0.128 | 33.118 |
303 | 2.095 | -5.666 | |||
313 | 2.650 | -6.946 | |||
318 | 2.780 | -7.586 | |||
323 | 3.088 | -8.226 |
Table S3 Thermodynamic parameters of Cr(III) adsorption on Q-SBA-15
Sample | Tempera- ture/K | Kc | ΔG/ (kJ·mol-1) | ΔS/ (kJ·mol·K-1) | ΔH/ (kJ·mol-1) |
---|---|---|---|---|---|
Q-SBA-15 | 293 | 1.846 | -4.386 | 0.128 | 33.118 |
303 | 2.095 | -5.666 | |||
313 | 2.650 | -6.946 | |||
318 | 2.780 | -7.586 | |||
323 | 3.088 | -8.226 |
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