Journal of Inorganic Materials ›› 2023, Vol. 38 ›› Issue (11): 1281-1291.DOI: 10.15541/jim20230209
Special Issue: 【能源环境】污染物去除(202312)
• RESEARCH ARTICLE • Previous Articles Next Articles
TANG Ya1,2(), SUN Shengrui2, FAN Jia1,2, YANG Qingfeng3, DONG Manjiang2, KOU Jiahui1(
), LIU Yangqiao2(
)
Received:
2023-04-28
Revised:
2023-05-29
Published:
2023-06-01
Online:
2023-06-01
Contact:
LIU Yangqiao, professor. E-mail: yqliu@mail.sic.ac.cn;About author:
About author: TANG Ya (1998-), male, Master candidate. E-mail: tangya153@163.com
Supported by:
CLC Number:
TANG Ya, SUN Shengrui, FAN Jia, YANG Qingfeng, DONG Manjiang, KOU Jiahui, LIU Yangqiao. PEI Modified Hydrated Calcium Silicate Derived from Fly Ash and Its adsorption for Removal of Cu (II) and Catalytic Degradation of Organic Pollutants[J]. Journal of Inorganic Materials, 2023, 38(11): 1281-1291.
Fig. 3 Adsorption characteristics of samples (a) Variation of adsorption capacity of samples with time; (b) Effect of pH on the adsorption capacity of PCSH; (c) Adsorption isotherms of samples; (d) Variation of adsorption capacity of samples with initial concentration of Zn(II)-Pb(II)
Fig. 7 Degradation of RhB by PMS with CSH-Cu-c and PCSH-Cu-c (a) RhB residue percentage; (b) Photo of catalytic device; (c) Catalytic performance of PCSH-Cu-c-M
Catalyst | C1/(g·L-1) | CPMS/(g·L-1) | CRhB/(mg·L-1) | k/min-1 | Ref. |
---|---|---|---|---|---|
MPC | 1 | 0.616 | 20 | 0.013 | [ |
α-MnO2/Pal | 0.1 | 0.1 | 20 | 0.0204 | [ |
Vis/BiVO4 | 0.5 | 0.616 | 10 | 0.04 | [ |
rGO-CoPc | 0.3 | 0.616 | 10 | 0.288 | [ |
CSH-Cu-c | 0.8 | 0.12 | 20 | 0.036 | This work |
PCSH-Cu-c | 0.8 | 0.12 | 20 | 0.7135 | This work |
Table 1 Rate constants (k) for the degradation of RhB by PMS with different catalysts
Catalyst | C1/(g·L-1) | CPMS/(g·L-1) | CRhB/(mg·L-1) | k/min-1 | Ref. |
---|---|---|---|---|---|
MPC | 1 | 0.616 | 20 | 0.013 | [ |
α-MnO2/Pal | 0.1 | 0.1 | 20 | 0.0204 | [ |
Vis/BiVO4 | 0.5 | 0.616 | 10 | 0.04 | [ |
rGO-CoPc | 0.3 | 0.616 | 10 | 0.288 | [ |
CSH-Cu-c | 0.8 | 0.12 | 20 | 0.036 | This work |
PCSH-Cu-c | 0.8 | 0.12 | 20 | 0.7135 | This work |
Fig. 8 Suface elements and chemical status of samples (a) Cu2p and (b) O1s XPS spectra of PCSH-Cu-c before and after reaction; (c) Cu2p and (d) O1s XPS spectra of CSH-Cu-c and PCSH-Cu-c before reaction
Catalyst | C1/ (g·L-1) | CNaBH4/ (mmol·L-1) | C4-NP/ (mmol·L-1) | k/(×10-3, s-1) | Ref. |
---|---|---|---|---|---|
CuO NLs | 0.307 | 10 | 0.12 | 0.36 | [ |
Ag-NP/C | 0.333 | 6.667 | 4.7×10-2 | 1.69 | [ |
Cu2−xSe/ rGO/PVP | 2.5 | 62.5 | 0.125 | 2.3 | [ |
Pd-FG | 0.5 | 10 | 0.1 | 2.35 | [ |
CSH-Cu-c | 0.167 | 5 | 0.1 | 0.61 | This work |
PCSH-Cu-c | 0.167 | 5 | 0.1 | 11.47 | This work |
Table 2 Rate constants (k) for the degradation of 4-NP by NaBH4 with different catalysts
Catalyst | C1/ (g·L-1) | CNaBH4/ (mmol·L-1) | C4-NP/ (mmol·L-1) | k/(×10-3, s-1) | Ref. |
---|---|---|---|---|---|
CuO NLs | 0.307 | 10 | 0.12 | 0.36 | [ |
Ag-NP/C | 0.333 | 6.667 | 4.7×10-2 | 1.69 | [ |
Cu2−xSe/ rGO/PVP | 2.5 | 62.5 | 0.125 | 2.3 | [ |
Pd-FG | 0.5 | 10 | 0.1 | 2.35 | [ |
CSH-Cu-c | 0.167 | 5 | 0.1 | 0.61 | This work |
PCSH-Cu-c | 0.167 | 5 | 0.1 | 11.47 | This work |
Sample | Langmuir model | Freundlich model | ||||
---|---|---|---|---|---|---|
qm | KL | R2 | n | KF | R2 | |
CSH | 294.10 | 0.0200 | 0.9945 | 3.810 | 54.00 | 0.8670 |
PCSH | 588.23 | 0.0563 | 0.9982 | 5.848 | 198.86 | 0.9450 |
Table S1 Langmuir and Freundlich isotherm fitting parameters
Sample | Langmuir model | Freundlich model | ||||
---|---|---|---|---|---|---|
qm | KL | R2 | n | KF | R2 | |
CSH | 294.10 | 0.0200 | 0.9945 | 3.810 | 54.00 | 0.8670 |
PCSH | 588.23 | 0.0563 | 0.9982 | 5.848 | 198.86 | 0.9450 |
Sample | q / (mg·g-1) | SBET/ (m2·g-1) | Ref. |
---|---|---|---|
Activated carbon | 10 | 921 | [S1] |
Modified SBA-15 mesoporous silica | 46 | 317 | [S2] |
MCM-48 | 126 | 511 | [S3] |
Citrate-LDH | 137 | 8 | [S4] |
Mesoporous silica | 153 | 462 | [S5] |
Humulus scandens-derived biochars | 221 | 450 | [S6] |
Steel slag-derived CSH | 244 | 77 | [S7] |
Amorphous molybdenum sulphide | 259 | 28 | [S8] |
NPCS-PEI | 276 | 491 | [S9] |
CSH | 294 | 240 | This work |
PCSH | 588 | 371 | This work |
Table S2 Comparison of maximum adsorption capacities of various sorbents as reported in the literature for Cu(II)
Sample | q / (mg·g-1) | SBET/ (m2·g-1) | Ref. |
---|---|---|---|
Activated carbon | 10 | 921 | [S1] |
Modified SBA-15 mesoporous silica | 46 | 317 | [S2] |
MCM-48 | 126 | 511 | [S3] |
Citrate-LDH | 137 | 8 | [S4] |
Mesoporous silica | 153 | 462 | [S5] |
Humulus scandens-derived biochars | 221 | 450 | [S6] |
Steel slag-derived CSH | 244 | 77 | [S7] |
Amorphous molybdenum sulphide | 259 | 28 | [S8] |
NPCS-PEI | 276 | 491 | [S9] |
CSH | 294 | 240 | This work |
PCSH | 588 | 371 | This work |
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