Journal of Inorganic Materials ›› 2011, Vol. 26 ›› Issue (3): 311-316.DOI: 10.3724/SP.J.1077.2011.00311

• Research Paper • Previous Articles     Next Articles

Selective Catalytic Reduction of NO with Propylene over Pd-ZrO2/Al2O3catalysts Catalysts

WANG Yu-dong1,2,ZHANG Hao-Jie2, HE Dan-nong1,2   

  1. 1. School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China; 2.Ntional Engineering Research Center for Nanotechnology, Shanghai 200241, China
  • Received:2010-05-31 Revised:2010-08-18 Published:2011-03-20 Online:2011-02-18
  • Supported by:

    National Key Technology R&D Program (2007BAJ03B00)

Abstract: An alumina supported Pd-ZrO2 catalyst with high surface area was synthesized by impregnation method and characterized byBET, XRD and TEM techniques. The catalytic activity of the catalyst onselective catalytic reduction (SCR) of NO with C3H6 as reducer was studied, and the influence of the reaction temperature, catalyst component, calcination temperature, reactant ratio and space velocity on the catalytic activity were investigated, respectively. The results indicated that the Pd nano-particles had been dispersed evenly on the Al2O3support, and a dding withfter appropriate amount of ZrO2 addition, the obtained compound catalyst 1 wt%Pd-2 wt%ZrO2/Al2O3showed high catalytic activity on NO selective catalytic reduction reaction,and the NO conversion could reached 50 wt %-70 wt% in the temperature range of 240-250℃. The improvement of NO conversion is ascribed to the ZrO2 loaded on the catalysts, which can The ZrO2loaded on the catalysts could promote the adsorption of NO and C3H6on the catalyst surface, a synergetic catalytic effect between Pd and ZrO2has been proposed. .

Key words: selectivecatalyst reduction (SCR), C3H6, NO conversion, ZrO2

CLC Number: