Study on Miniamount Redox in Melting V2O5

Abstract

Abstract: The V₂O₅ melting prepared under 750, 800 and 1100℃ separately were made into V₂O₅ sol by quenching, and then V₂O₅ gel thin films were obtained by dipping non-crystal glass substrates into V₂O₅ sol. The tetravalence vanadium was found in V₂O₅ gel thin films by measuring the electrical resistance change of V₂O₅ gel thin films with temperature, ESCA and X-ray diffraction analysis. in this paper, from miniamount redox in melting V₂O₅ and crystal structure, the influencing mechanism of miniamount redox on changing valence of vanadium was analyzed and discussed in detail.

Key words: sol-gel, thin films, V₂O₅

CLC Number:

O645

WEI Jing-Song,ZHAO Kang,GU Chen-Qing. Study on Miniamount Redox in Melting V₂O₅[J]. Journal of Inorganic Materials.

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Study on Miniamount Redox in Melting V₂O₅

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