Electronic Structures of REBaCuO Systems and Its Relation withSuperconductivities

Abstract

Abstract: The electronic structures of RECu₈O₈(RE=La, Pr, Nd, Sm, Gd, Dy, Ho, Er) were calculated by means of SCF-Xα-SW methods. The result shows that: There
is an inner-orbit coupling for these oxide superconductor systems. The inner-orbit coupling is due to interaction of two saturated electronic orbits of RE5p and O2s
since they have a nearly similar energy state level and relatively larger orbital electronic clouds. Compared with experiments, the overlaps in space between two
orbits has a close relation with T_c and the number of enrolling electrons has a similar relation with J_c, therefore the influence of inner-orbit
coupling on superconductivity can not be overlooked.

Key words: structure and properties, electronic structure, oxides, superconductors

CLC Number:

TM26

CHEN Ning,ZHANG Bao-Dong,QING Jia,MA Li,LI Fu-Xing. Electronic Structures of REBaCuO Systems and Its Relation withSuperconductivities[J]. Journal of Inorganic Materials.

[1]	WEN Zhiqin, HUANG Binrong, LU Taoyi, ZOU Zhengguang. Pressure on the Structure and Thermal Properties of PbTiO₃: First-principle Study [J]. Journal of Inorganic Materials, 2022, 37(7): 787-794.
[2]	ZHANG Xian, ZHANG Ce, JIANG Wenjun, FENG Deqiang, YAO Wei. Synthesis, Electronic Structure and Visible Light Photocatalytic Performance of Quaternary BiMnVO₅ [J]. Journal of Inorganic Materials, 2022, 37(1): 58-64.
[3]	XIANG Hui, QUAN Hui, HU Yiyuan, ZHAO Weiqian, XU Bo, YIN Jiang. Piezoelectricity of Graphene-like Monolayer ZnO and GaN [J]. Journal of Inorganic Materials, 2021, 36(5): 492-496.
[4]	ZHAO Linyan, LIU Yangsi, XI Xiaoli, MA Liwen, NIE Zuoren. First-principles Study on Nanoscale Tungsten Oxide: a Review [J]. Journal of Inorganic Materials, 2021, 36(11): 1125-1136.
[5]	ZHAO Yupeng,HE Yong,ZHANG Min,SHI Junjie. First-principles Study on the Photocatalytic Hydrogen Production of a Novel Two-dimensional Zr₂CO₂/InS Heterostructure [J]. Journal of Inorganic Materials, 2020, 35(9): 993-998.
[6]	LI Jing,LIU Xiaoyue,QIU Qianfeng,LI Ling,CAO Xiaoyan. Phosphorus Sorption Characteristics on Aluminum Oxides with Different Structures [J]. Journal of Inorganic Materials, 2020, 35(9): 1005-1010.
[7]	HU Li-Fang,LIU Liu,HE Jie,SUN Zhi-Peng,CHEN Xiao-Ping. Aspirin on Ni-Ti-LDHs Nanosheets: Load and Sustained-release [J]. Journal of Inorganic Materials, 2020, 35(2): 165-172.
[8]	ZHENG Shiyou, DONG Fei, PANG Yuepeng, HAN Pan, YANG Junhe. Research Progress on Nanostructured Metal Oxides as Anode Materials for Li-ion Battery [J]. Journal of Inorganic Materials, 2020, 35(12): 1295-1306.
[9]	WANG Zhong, ZHA Xian-Hu, WU Ze, HUANG Qing, DU Shi-Yu. First-principles Study on Electronic and Magnetic Properties of Mn-doped Strontium Ferrite SrFe₁₂O₁₉ [J]. Journal of Inorganic Materials, 2019, 34(10): 1047-1054.
[10]	WANG Song-Can, TANG Feng-Qiu, WANG Lian-Zhou. Visible Light Responsive Metal Oxide Photoanodes for Photoelectrochemical Water Splitting: a Comprehensive Review on Rational Materials Design [J]. Journal of Inorganic Materials, 2018, 33(2): 173-197.
[11]	ZHAO Han, ZHOU Xiao-Xia, PAN Lin-Yu, CHEN Hang-Rong. Birdnest-like CuCeZr Mixed Oxides: Synthesis and Excellent Catalysts for Diesel Exhaust Oxidatio [J]. Journal of Inorganic Materials, 2017, 32(9): 923-930.
[12]	YAN Hong-Hao, ZHAO Tie-Jun, LI Xiao-Jie, WU Lin-Song. Preparation and Immobilization of Ti-based Oxides by Detonation Method [J]. Journal of Inorganic Materials, 2017, 32(6): 667-672.
[13]	TIAN Xiao-Dong, LI Xiao, YANG Tao, SONG Yan, LIU Zhan-Jun, GUO Quan-Gui. Recent Advances on Synthesis and Supercapacitor Application of Binary Metal Oxide [J]. Journal of Inorganic Materials, 2017, 32(5): 459-468.
[14]	QI Xing-Yao, ZHOU Qing-Feng, CUI Mang-Wei, YANG Yong-Zhen, JIANG Hai-Wei, LIANG Wei, KANG Li-Tao. Capacitive Performance of Zn-Ni Hydroxide Nano-sheet Arrays on Nickel Foams via a Mild Chemical-bath Deposition Process [J]. Journal of Inorganic Materials, 2017, 32(4): 372-378.
[15]	WANG Wei-Qi, ZHENG Hui-Feng, LU Guan-Hong, LIU Yang-Qiao, SUN Jing, GAO Lian. Recent Progress on Applications of Nano Metal Oxides in Perovskite Solar Cells [J]. Journal of Inorganic Materials, 2016, 31(9): 897-907.

Electronic Structures of REBaCuO Systems and Its Relation withSuperconductivities

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments