Filling TiO2Nanotubes with Biological Apatite by Alternative Loop Immersion Method

doi:10.3724/SP.J.1077.2011.00078

Abstract

Abstract: A vertically aligned TiO₂ nanotube array was fabricated on the surfaceof titanium substrate in fluoride-containing electrolyes by anodization. Alternative Loop Immersion Method(ALIM) was investigated to fill TiO₂ nanotubes with the biologicalapatite in the saturated solution of Ca(OH)₂ and 0.02 mol/L (NH₄)₂HPO₄.In this way, the structure of the apatite-coating on the Ti substrate waschanged for solving the problem of coating shedding well. And the amount ofsynthetic apatite formed by ALIM was quantified according to key tubeproperties such as the tube diameter, the layer thickness, the crystalstructure (amorphous or anatase), <>etc. The effect of filling biologicalapatite of TiO₂ nanotubes fabricated in glycerol-based electrolyteat 60V is the best. And the rate of inducing biological apatite on amorphous TiO₂nanotubes with the treatment of ALIM is better than that of anatase TiO₂nanotubes. Mineralization <>in vitro experiments indicates that TiO₂nanotubes after ALIM treatment promote natural apatite formation significantlyin a simulated body fluid (SBF). Such TiO₂ nanotube arrays with ALIMtreatment, are useful as a well-adhered bioactive surface layer on Ti implantmetals for orthopaedic and dental implants.

Key words: TiO₂nanotubes, ALIM, fill, biological apatite

CLC Number:

O646
O614

YU Jia,XIAO Xiu-Feng, LIANG Jian-He,LIU Rong-Fang, WANG Chun-Yan,MAO Dan. Filling TiO₂Nanotubes with Biological Apatite by Alternative Loop Immersion Method[J]. Journal of Inorganic Materials, 2011, 26(1): 78-84.

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Filling TiO₂Nanotubes with Biological Apatite by Alternative Loop Immersion Method

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