Photocatalytic Properties of Magnetic Activated Carbon Supported F-doped TiO2

doi:10.3724/SP.J.1077.2013.12671

Abstract

Abstract: Fluorine-doped TiO₂ (F-TiO₂) prepared by Sol-Gel method was coated on magnetic activated carbon, and the magnetically separable composite photocatalyst (F-TMAC) was synthesized. The prepared samples were characterized by XRD, SEM, UV-Vis, XPS and vibrating sample magnetometer (VSM). The photocatalytic activity was determined by degradation of 100 mg/L reactive brilliant red (X-3B) in a 200 mL aqueous solution with 0.2 g catalyst. The results showed that the photocatalytic activity of such type catalyst was better than that of Degussa P25. The degradation ratio of X-3B was 99.8% under 18 W UV lamp irradiation and 83.1% under 250 W visible lamp irradiation, respectively. Furthermore, the photocatalyst can be separated easily by an external magnetic field with good reuse performance. The degradation ratio of X-3B was decreased by 6% after 5 cycles.

Key words: magnetic activated carbon, magnetical separation, fluorine-doped TiO₂, photocatalysis

CLC Number:

O643

LIN Xiao-Xia, JI Xiang, FU De-Gang, HAO Ling-Yun. Photocatalytic Properties of Magnetic Activated Carbon Supported F-doped TiO₂[J]. Journal of Inorganic Materials, 2013, 28(9): 997-1002.

References

[1] Zhang Q H. Progress on TiO2-based nanomaterials and its utilization in the clean energy technology. Journal of Inorganic Materials, 2012, 27(1): 1-10.

[2] Kowalska E, Mahaney O O P, Abe R, et al. Visible-light-induced photocatalysis through surface plasmon excitation of gold on titania surfaces. Phys. Chem. Chem. Phys., 2010, 12(10): 2344-2355.

[3] Su L C, Chu C L, Dong Y S, et al. N-doped TiO2 immobilized on Nickel foam and its photocatalytic performance for formaldehyde degradation under visible light. Journal of Inorganic Materials, 2010, 25(7): 753-757.

[4] Lin X X, Rong F, Ji X, et al. Carbon-doped mesoporous TiO2 film and its photocatalytic activity. Microporous Mesoporous Mater., 2011, 142: 276-281.

[5] Xiong Z G, Zhao X S. Nitrogen-doped titanate-anatase core-shell nanobelts exposed ﹛101﹜anatase facets and enhanced visible light photocatalytic activity. J. Am. Chem. Soc., 2012, 134(13): 5754-5757.

[6] Yang G D, Yan Z F, Xiao T C. Low-temperature solvothermal synthesis of visible-light-responsive S-doped TiO2 nanocrystal. Appl. Surf. Sci., 2012, 258(8): 4016-4022.

[7] Han X P, Shao G S. Electronic properties of rutile TiO2 with nonmetal dopants from first principles. J. Phys. Chem. C, 2011, 115: 8274-8282.

[8] Li D, Haneda H, Hishita S. Fluorine-doped TiO2 powders prepared by spray pyrolysis and their improved photocatalytic activity for decomposition of gas-phase acetaldehyde. J. Fluorine Chem., 2005, 126(1): 69-77.

[9] Li D, Haneda H, Hishita S. Visible-light-driven N-F-codoped TiO2 photocatalysts. 1. synthesis by spray pyrolysis and surface characterization. Chem. Mater., 2005, 17(10): 2588-2595.

[10] Xu J J, Ao Y H, Fu D G, et al. Low-temperature preparation of F-doped TiO2 film and its photocatalytic activity under solar light. Appl. Surf. Sci., 2008, 254(10): 3033-3038.

[11] Yu J C, Yu J G, Ho W K, et al. Effects of F- doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem. Mater., 2002, 14(9): 3808-3816.

[12] Li Y J, Zhou X M, Chen W, et al. Photodecolorization of Rhodamine B on tungsten-doped TiO2/activated carbon under visible-light irradiation. J. Hazard. Mater., 2012, 227-228: 25-33.

[13] He Z, Yang S G, Ju Y M, et al. Microwave photocatalytic degradation of Rhodamine B using TiO2 supported on activated carbon: mechanism implication. J. Environ. Sci., 2009, 21: 268-272.

[14] Wang X J, Hu Z H, Chen Y J. A novel approach towards high-performance composite photocatalyst of TiO2 deposited on activated carbon. Appl. Surf. Sci., 2009, 255: 3953-3958.

[15] Huang H, Jiang Z P, Yang H W, et al. Synthesis of a kind of photocatalyst carried by magnetic particle by Sol-Gel method. Techniques and Equipment for Environmental Pollution Control, 2004, 5(1): 65-68.

[16] Ao Y H, Xu J J, Fu D G, et al. A novel magnetically separable composite photocatalyst: titania-coated magnetic activated carbon. Sep. Purif. Technol., 2008, 61: 436-441.

[17] Xu C K, Killmeyer R, Gray M L, et al. Enhanced carbon doping of n-TiO2 thin films for photoelectrochemical water splitting. Electrochem. Commun., 2006, 8(10): 1650-1654.

[18] He Y, Bai F F, He P, et al. Research on preparation and electric properties of F-doped tin oxide nanopowder. Electronic Components and Materials, 2007, 26(4): 1-3.

[19] Asahi R, Morikawa T, Ohwaki T. Visible-light photocatalysis in nitrogen-doped titanium oxides. Science, 2001, 293(5528): 269-271.

[20] Ho W, Yu J C, Lee S. Synthesis of hierarchical nanoporous F-doped TiO2 spheres with visible light photocatalytic activity. Chem. Commun., 2006, 10: 1115-1117.

[21] Pan J H, Zhang X, Du A J, et al. Self-etching reconstruction of hierachically mesoporous F-TiO2 hollow microspherical photocatalyst for concurrent membrane water purifications. J. Am. Chem. Soc., 2008, 130(34): 11256.

[22] Lin X X, Rong F, Ji X, et al. Fabrication and enhanced visible light photocatalytic activity of fluorine doped TiO2 by loaded with Ag. J. Nanosci. Nanotechnol., 2011, 11: 1-6.

[23] Li D, Haneda H, Labhsetwar N K, et al. Visible-light-driven photocatalysis on fluorine-doped TiO2 powders by the creation of surface oxygen vacancies. Chem. Phys. Lett., 2005, 401: 579-584.

Photocatalytic Properties of Magnetic Activated Carbon Supported F-doped TiO₂

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