Journal of Inorganic Materials ›› 2016, Vol. 31 ›› Issue (7): 699-704.DOI: 10.15541/jim20150563
• Orginal Article • Previous Articles Next Articles
LU Xiao-Yu1, JIA Nan1, FANG Bi-Jun1, YANG Zhao-Rong2, ZHANG Yu-Heng2
Received:
2015-11-13
Revised:
2016-03-02
Published:
2016-07-20
Online:
2016-06-22
About author:
LU Xiao-Yu. E-mail: 1483326817@qq.com
Supported by:
CLC Number:
LU Xiao-Yu, JIA Nan, FANG Bi-Jun, YANG Zhao-Rong, ZHANG Yu-Heng. Transport Behavior and Magnetism of Colossal Magnetoresistance Materials A0.05Co0.95Cr2S4 (A=Zn, Ni, Cd, Fe)[J]. Journal of Inorganic Materials, 2016, 31(7): 699-704.
Doping element | Fe | Zn | Ni | Cd |
---|---|---|---|---|
Ionic radius/nm | 0.063 | 0.060 | 0.055 | 0.078 |
Cell parameter, a/nm | 0.99325 | 0.99317 | 0.99253 | 0.99402 |
Table 1 Ionic radius of doping elements and unit cell parameter of A0.05Co0.95Cr2S4 (A=Zn、Fe、Ni、Cd)
Doping element | Fe | Zn | Ni | Cd |
---|---|---|---|---|
Ionic radius/nm | 0.063 | 0.060 | 0.055 | 0.078 |
Cell parameter, a/nm | 0.99325 | 0.99317 | 0.99253 | 0.99402 |
Fig. 2 Temperature dependence of resistivity and magnetoresistance measured at zero field and 4.5 T and the relationships of lnρ-1000/T under zero field (insets)(a) Fe0.05Co0.95Cr2S4; (b) Zn0.05Co0.95Cr2S4; (c) Ni0.05Co0.95Cr2S4
Doping element | Fe | Zn | Ni | Cd |
---|---|---|---|---|
MR4.5T | 0.0290 | 0.1800 | 0.0035 | — |
EH/meV | 37 | 126 | 308 | — |
EL/meV | 18 | 45 | 119 | — |
TC/K | 218 | 215 | 218 | 213 |
HC/T | 0.01972 | 0.03712 | 0.01546 | 0.01998 |
Table 2 The magnetoresistance parameters of A0.05Co0.95Cr2S4(A=Zn、Fe、Ni、Cd)
Doping element | Fe | Zn | Ni | Cd |
---|---|---|---|---|
MR4.5T | 0.0290 | 0.1800 | 0.0035 | — |
EH/meV | 37 | 126 | 308 | — |
EL/meV | 18 | 45 | 119 | — |
TC/K | 218 | 215 | 218 | 213 |
HC/T | 0.01972 | 0.03712 | 0.01546 | 0.01998 |
Fig. 4 The relationships of ZFC and FC magnetization versus temperature measured at H=0.01 T of A0.05Co0.95Cr2S4 (A=Fe、Zn、Ni、Cd)(a) Cd0.05Co0.95Cr2S4 and Fe0.05Co0.95Cr2S4; (b) Zn0.05Co0.95Cr2S4 and Ni0.05Co0.95Cr2S4
Fig. 5 Magnetic hysteresis loops of A0.05Co0.95Cr2S4 (A=Fe、Zn、Ni、Cd) measured at 5 K(a) Fe0.05Co0.95Cr2S4; (b) Zn0.05Co0.95Cr2S4; (c) Ni0.05Co0.95Cr2S4; (d) Cd0.05Co0.95Cr2S4
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