Phase Inversion Tape Casting and Electrochemical Performance of Solid Oxide Fuel Cell Anode

doi:10.15541/jim20150225

Abstract

Abstract:

For an anode-supported solid oxide fuel cell (SOFC), the anode consists of a thick support layer with large pores and a thin functional layer with small pores. In the present work, the anode of NiO and yttria-stabilized zirconia (YSZ) comprising a porous support layer of ~700 μm thick and a functional layer of ~60 μm thick were formed in a single step using the phase inversion tape casting method. For the as-prepared anode, the support layer contained large open pores which were aligned along the thickness direction. A thin dense YSZ electrolyte layer with a thickness of 15 μm was deposited onto the anode by dip-coating and co-sintering techniques. A composite cathode of YSZ-La_0.8Sr_0.2MnO_3-_δ (LSM) with a weight ratio of 50:50 was screen-printed on the surface of the YSZ electrolyte layer. The resulting fuel cell exhibited promising electrochemical performance. A maximum power density of 891 mW/cm² was obtained at 800 ℃ using H₂-3% H₂O as the fuel and ambient air as the oxidant. The cell did not show any sign of concentration polarization even at high current densities, which should be attributed to the open straight pore structure and resultant fast gas-phase transport in the anode support.

Key words: SOFC, anode support, phase inversion-tape casting, concentration polarization

CLC Number:

TQ174
TM911

ZHANG Yu-Yue, LIN Jie, MIAO Guo-Shuan, GAO Jian-Feng, CHEN Chu-Sheng, XIA Chang-Rong, ZHAN Zhong-Liang, WANG Shao-Rong. Phase Inversion Tape Casting and Electrochemical Performance of Solid Oxide Fuel Cell Anode[J]. Journal of Inorganic Materials, 2015, 30(12): 1291-1294.

Figures/Tables 6

Fig. 1 Schematic of phase-inversion tape casting

Fig. 2 Cross section of green NiO-YSZ anode support

Fig. 3 Porous structure images of reduced anode support. (a) Cross section; (b) Top view; (c) Bottom view

Fig. 4 SEM images of the anode-supported cell after electrochemical testing. (a) Cross section; (b) Enlarged cross section corresponding to the region marked by square in (a)

Fig. 5 Output performance of cell (I-V and I-P curves)

Fig. 6 Impedance spectra of cell under open circuit condition

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