液相包覆制备Ce-TZP陶瓷的力学性能与稳定行为

无机材料学报

液相包覆制备Ce-TZP陶瓷的力学性能与稳定行为

方平安¹, 顾辉¹, Vleugels Jef², Van der Biest Omer²

1. 中科院上海硅酸盐研究所高性能陶瓷与超微结构国家重点实验室, 上海 200050; 2. Department of Metallurgy and Materials
Engineering, Katholieke Universiteit Leuven, Kasteelpark Arenberg 44, B-3001 Leuven, Belgium

收稿日期:2003-08-08 修回日期:2003-10-08 出版日期:2004-09-20 网络出版日期:2004-09-20

Mechanical Properties and Stabilization Behavior of Ce-TZP Ceramics Prepared by Coating Process

FANG Ping-An¹, GU Hui¹, Vleugels Jef², Van der Biest Omer²

1. State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences,
Shanghai 200050, China; 2. Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, Kasteelpark Arenberg 44, B-3001 Leuven,
Belgium

Received:2003-08-08 Revised:2003-10-08 Published:2004-09-20 Online:2004-09-20

摘要/Abstract

摘要： 采用XRD、SEM、 TEM等分析手段对由液相包覆工艺制备的Ce-TZP陶瓷的微结构进行了研究, 并和共沉淀粉体制备的Ce-TZP陶瓷进行了对比分析. 力学性能表明, 同共沉淀粉体制备的Ce-TZP?陶瓷相比, 由液相包覆工艺制备的Ce-TZP陶瓷虽硬度下降, 但断裂韧性改善; 液相添加少量 Al₂O₃硬度随之增加、断裂韧性显著提高. 电镜分析表明, 液相包覆工艺制备的Ce-TZP陶瓷晶粒尺寸分布宽化, 一部分晶粒尺寸较大但CeO₂含量低、易发生马氏体相转变晶粒的存在是断裂韧性改善的主要原因. 陶瓷体中单斜相大晶粒与四方相之间的残余应力、添加少量 Al₂O₃在晶界上易形成薄的非晶包裹层, 是增加可相变四方相数量, 提高断裂韧性的其它机制.

关键词: Ce-TZP陶瓷, 包覆, 力学性能, 相变

Abstract: The microstructure of Ce-TZP ceramics processed by a coating technique, compared to co-precipitated
powder-based Ce-TZP, was analysed using a combination of XRD, SEM, TEM, etc. The results showed that CeO₂-coated powder-based zirconia ceramics
exhibited higher fracture toughness than co-precipitated powder-based zirconia ceramics in spite of a little decreasing hardness. Besides, a
small amount of alumina addition can significantly improve the fracture toughness of CeO₂-coated powder-based zirconia ceramics. In contrast
with homogeneous grain size and stabilizer content distribution of co-precipitated powder-based Ce-TZP ceramics, SEM and EPMA analysis
revealed that coating process resulted in wider grain size and stabilizer content distribution in this Ce-TZP ceramics. The superior fracture
toughness of CeO₂-coated Ce-TZP ceramics was mainly attributed to a fraction of highly transformable tetragonal ZrO₂ grains with low ceria
content. The residual stress existing between anisotropic monoclinic and tetragonal grains, and the thin glass films containing alumina and silica
at grain boundary observed by TEM, were believed to benefit the preservation more tetragonal grains during sintering, contributing to the stress-induced
martensitic phase transformation.

Key words: Ce-TZP ceramics, coating, mechanical properties, phase transformation

中图分类号:

TQ174

方平安,顾辉,Vleugels Jef,Van der Biest Omer. 液相包覆制备Ce-TZP陶瓷的力学性能与稳定行为[J]. 无机材料学报.

FANG Ping-An,GU Hui,Vleugels Jef,Van der Biest Omer. Mechanical Properties and Stabilization Behavior of Ce-TZP Ceramics Prepared by Coating Process[J]. Journal of Inorganic Materials.

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