无机材料学报

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一种新型的溶液型电致变色器件的研究

葛万银1,2, 李永祥1, 于晓峰1,2, 杨群保1   

  1. 1. 中国科学院 上海硅酸盐研究所 高性能陶瓷超微结构国家重点实验室, 上海200050;
    2. 中国科学院 研究生院, 北京 100049
  • 收稿日期:2005-03-22 修回日期:2005-05-12 出版日期:2006-03-20 网络出版日期:2006-03-20

A Novel Solution-Based Electrochromic Device

GE Wan-Yin1,2, LI Yong-Xiang1,YU Xiao-Feng1,2, YANG Qun-Bao1   

  1. 1. State Key Laboratory of High Performance Ceramics and Superfine
    Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;
    2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2005-03-22 Revised:2005-05-12 Published:2006-03-20 Online:2006-03-20

摘要: 通过在紫罗精溶液中加入钛离子, 得到了一种新型互补型的电致变色溶液. 利用这种电致变色溶液设计成电致变色器件, 通过紫外-可见分光光度计表征, 这种溶液型电致变色器件透过率变化在600nm附近可由80%降低到20%; 通过电致变色器件和透射光强变化的关系, 测得其退色时间<2s, 并且具有自擦除效果.

关键词: 电致变色, 互补溶液, 紫罗精, 退色时间

Abstract: A new coupling electrochromic solution was investigated by introducing titanium ion into viologen solution. The solution-based electrochromic device was assembled by using this coupling solution. The transmittance of this electrochromic device decreased from 80% to 20% in the wavelength of 600nm, which was characterized by UV-Vis spectra. The bleaching time of this electrochromic device was less than 2s and this electrochromic device had a character of self-erasing process.

Key words: electrochromic devices, coupling solution system, viologen, bleaching time

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