表面活性剂对羟基磷灰石纤维形貌的影响

doi:10.15541/jim20150487

无机材料学报 ›› 2016, Vol. 31 ›› Issue (7): 726-730.DOI: 10.15541/jim20150487 CSTR: 32189.14.10.15541/jim20150487

表面活性剂对羟基磷灰石纤维形貌的影响

齐美丽^1,2,3, 亓佳^1,2, 肖桂勇^1,2,3, 吕宇鹏^1,2,3

(1. 山东大学材料液固结构演变与加工教育部重点实验室, 济南 250061; 2. 山东大学材料科学与工程学院, 济南250061; 3. 山东大学苏州研究院, 苏州 215123)

收稿日期:2015-10-10 修回日期:2015-12-29 出版日期:2016-07-20 网络出版日期:2016-06-22
作者简介:齐美丽(1988–), 女, 博士研究生. E-mail: beauty0507@163.com
基金资助:
山东大学基本科研业务费专项基金(2015JC018);江苏省青年科学基金(BK20140412);山东省优秀中青年科学家科研奖励基金(BS2013CL030)

Effect of Surfactants on the Morphology of Hydroxyapatite Fibers

QI Mei-Li^{1, 2, 3}, QI Jia^{1, 2}, XIAO Gui-Yong^{1, 2, 3}, LU Yu-Peng^{1, 2, 3}

(1. Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Ji’nan, 250061, China; 2. School of Materials Science and Engineering, Shandong University, Ji’nan, 250061, China; 3. Shandong University Suzhou Institute, Suzhou, 215123)

Received:2015-10-10 Revised:2015-12-29 Published:2016-07-20 Online:2016-06-22
About author:QI Mei-Li. E-mail: beauty0507@163.com
Supported by:
Special Fund of Shandong University Basic Research (2015JC018);Jiangsu Province Science Foundation for Youths (BK20140412);Shangdong Province Young and Middle-Aged Scientists Research Awards Fund (BS2013CL030)

摘要/Abstract

摘要：

以Ca(NO₃)₂·4H₂O和(NH₄)₂HPO₄水溶液为前驱体, 采用水热均相沉淀法制备了结晶度较高的羟基磷灰石纤维, 研究了表面活性剂十六烷基三甲基溴化胺(CTAB)、十二烷基硫酸钠(SDS)和聚乙二醇(PEG)及其含量对产物形貌和相组成的影响。结果表明, 采用这三种表面活性剂制备的产物都是羟基磷灰石, 部分样品含有少量碳酸钙杂质。加入CTAB和SDS均会对纤维的生长起到抑制作用, 得到纤维与球形团聚体并存的产物, 而PEG的加入在一定程度上促进了纤维的生长。

关键词: 羟基磷灰石纤维, 表面活性剂, 水热均相沉淀, 形貌

Abstract:

Hydroxyapatite fiber with high crystallinity was successfully fabricated by hydrothermal homogeneous precipitation synthesis with Ca(NO₃)₂·4H₂O and (NH₄)₂HPO₄ as precursors. Effects of the surfactants include cetyltrimethylammonium bromide (CTAB), sodium dodecyl sulfate (SDS) and polyethylene glycol (PEG), and different amounts of them on the morphology and phase composition of the obtained products were investigated. Results show that the products obtained by using the three surfactants are all hydroxyapatite with minor CaCO₃in some samples. The addition of both CTAB and SDS inhibits the growth of the fibers, leading to the coexistence of fibers and spherical aggregates. However, the addition of PEG can promote the growth of fibers to some extent.

Key words: hydroxyapatite fibers, surfactants, hydrothermal homogeneous precipitation, morphology

中图分类号:

TB321

齐美丽, 亓佳, 肖桂勇, 吕宇鹏. 表面活性剂对羟基磷灰石纤维形貌的影响[J]. 无机材料学报, 2016, 31(7): 726-730.

QI Mei-Li, QI Jia, XIAO Gui-Yong, LV Yu-Peng. Effect of Surfactants on the Morphology of Hydroxyapatite Fibers[J]. Journal of Inorganic Materials, 2016, 31(7): 726-730.

图/表 4

图1 未添加及分别添加不同量的表面活性剂后制备产物的XRD图谱

Fig. 1 XRD patterns of the products synthesized without (a) and with the addition of different amounts of surfactants (b-d)

图2 未添加及分别添加不同量的CTAB后制备的产物SEM照片

Fig. 2 SEM images of the products with addition of different amounts of CTAB (a) 0 mmol/L; (b) 1.84 mmol/L; (c) 3.9 mmol/L; (d) 9.2 mmol/L

图3 添加不同量的SDS后制备的产物SEM照片

Fig. 3 SEM images of the products with addition of different amounts of SDS (a) 0.435 mmol/L; (b) 0.87 mmol/L; (c) 4.35 mmol/L

图4 添加不同量的PEG后制备的产物SEM照片

Fig. 4 SEM images of the products with addition of different amounts of PEG (a) n(Ca2+):n(PO43-):n(PEG)=10.8:6:1; (b) n(Ca2+):n(PO43-):n(PEG)=10.8:6:2; (c) n(Ca2+):n(PO43-):n(PEG)=10.8:6:10

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表面活性剂对羟基磷灰石纤维形貌的影响

Effect of Surfactants on the Morphology of Hydroxyapatite Fibers

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