超重力熔铸Y2O3-Al2O3-SiO2玻璃的晶化行为研究

doi:10.3724/SP.J.1077.2013.12592

无机材料学报 ›› 2013, Vol. 28 ›› Issue (7): 780-784.DOI: 10.3724/SP.J.1077.2013.12592 CSTR: 32189.14.SP.J.1077.2013.12592

超重力熔铸Y₂O₃-Al₂O₃-SiO₂玻璃的晶化行为研究

杨增朝^1,2, 刘光华², 徐利华¹, 李江涛², 郭世斌²

(1. 北京科技大学材料科学与工程学院, 北京100083; 2. 中国科学院理化技术研究所, 北京100190)

收稿日期:2012-10-01 修回日期:2012-11-15 出版日期:2013-07-20 网络出版日期:2013-06-19
作者简介:杨增朝(1982–), 男, 博士研究生. E-mail: yangzengchao5@163.com
基金资助:
国家自然科学基金(50932006, 51002163); 北京市自然科学基金(2112043)

Investigation on Crystallization Behavior of Y₂O₃-Al₂O₃-SiO₂ Glass Prepared by High-gravity Combustion Synthesis

YANG Zeng-Chao^1,2, LIU Guang-Hua², XU Li-Hua¹, LI Jiang-Tao², GUO Shi-Bin²

(1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China; 2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China)

Received:2012-10-01 Revised:2012-11-15 Published:2013-07-20 Online:2013-06-19
About author:YANG Zeng-Chao. E-mail: yangzengchao5@163.com
Supported by:
National Natural Science Foundation of China (50932006, 51002163); Beijing Natural Science Foundation (2112043)

摘要/Abstract

摘要： 研究了以超重力熔铸方法制备的Y₂O₃-Al₂O₃-SiO₂玻璃的晶化行为, 并结合相图分析了热处理条件对晶化过程的影响规律。实验结果表明, Y₂O₃-Al₂O₃-SiO₂玻璃的晶化行为与热处理温度和SiO₂含量密切相关。当热处理温度为1050℃时, 晶化后样品的相组成沿超重力场方向呈现出梯度分布, 自上而下分别为Al₆Si₂O₁₃玻璃陶瓷、纯玻璃相、χ-Al₂O₃玻璃陶瓷。当退火温度为1100℃时, 析出晶相主要为Y₃Al₅O₁₂及Y₂Si₂O₇; 退火温度为1200℃时主要析出Y₃Al₅O₁₂。因此, 以超重力熔铸法制备YAS玻璃结合后续热处理的工艺, 提供了一种快速制备YAS基微晶玻璃的新方法。

关键词: 超重力熔铸, YAS玻璃, 退火, 晶化

Abstract: The crystallization behavior of Y₂O₃-Al₂O₃-SiO₂ glass prepared by high-gravity combustion synthesis was investigated by isothermal annealing experiments. The effect of annealing condition on the crystallization behavior of the glass was discussed according to the Y₂O₃-Al₂O₃-SiO₂ternary phase diagram. From experimental results, the crystallization behavior of the glass strongly depended on the annealing temperature and the content of SiO₂. After being annealed at 1050℃, the sample showed a graded phase distribution along the high-gravity direction, consisting of Al₆Si₂O₁₃ glass-ceramic, pure glass and χ-Al₂O₃ glass-ceramic. At annealing temperature of 1100℃, Y₃Al₅O₁₂ and Y₂Si₂O₇ were precipitated as the major crystalline phases. When the annealing temperature further increased to 1200℃, the predominant crystalline phase was Y₃Al₅O₁₂. The research provides a possible way to prepare Y₂O₃-Al₂O₃-SiO₂ glass-ceramics by integrating high-gravity combustion synthesis with post annealing treatment.

Key words: high-gravity combustion synthesis, Y₂O₃-Al₂O₃-SiO₂ glass, annealing, crystallization

中图分类号:

TB321

杨增朝, 刘光华, 徐利华, 李江涛, 郭世斌. 超重力熔铸Y₂O₃-Al₂O₃-SiO₂玻璃的晶化行为研究[J]. 无机材料学报, 2013, 28(7): 780-784.

YANG Zeng-Chao, LIU Guang-Hua, XU Li-Hua, LI Jiang-Tao, GUO Shi-Bin. Investigation on Crystallization Behavior of Y₂O₃-Al₂O₃-SiO₂ Glass Prepared by High-gravity Combustion Synthesis[J]. Journal of Inorganic Materials, 2013, 28(7): 780-784.

参考文献

[1] Zhang Yahong, Alexandra Navrotsky. Thermochemistry of glasses in the Y2O3-Al2O3-SiO2 system. Journal of the American Ceramic Society, 2003, 86(10): 1727–1732.

[2] Hyatt M J, Day D E. Glass properties in the yttria-alumina-silica system. Journal of the American Ceramic Society, 1987, 70(10): 283–287.

[3] Gomez E, Echeberria J, Iturriza I, et al. Liquid phase sintering of SiC with additions of Y2O3, Al2O3 and SiO2. Journal of the European Ceramic Society, 2004, 24: 2895–2903.

[4] Shimada Kazuya, Eiza Nobuhiko, Park Joon-Soo, et al. High-temperature mechanical property improvements of SiC ceramics by NITE process. Materials Transactions, 2006, 47(4): 1204–1208.

[5] Akio Makishima, Michiko Kobayashi, Takajiro Shimohira. Formation of aluminosilicate glasses containing rare-earth oxides. Communications of the American Ceramic Society, 1982, 12: 210.

[6] Masakazu Kawashita, Fumiaki Miyaji, Tadashi Kokubo, et al. Surface structure and chemical durability of P+-implanted Y2O3-Al2O3-SiO2 glass for radiotherapy of cancer. Journal of Non-Crystalline Solids, 1999, 255(2/3): 140–148.

[7] Shunsuke Fujita, Satoru Yoshihara, Akihiko Sakamoto, et al. YAG Glass-ceramic Phosphor for White LED (Ⅰ):Background and Development. Fifth International Conference on Solid State Lighting, Bellingham, 2005, 594111.

[8] Setsuhisa Tanabe, Shunsuke Fujita, Satoru Yoshihara, et al. YAG Glass-ceramic Phosphor for White LED (Ⅱ):Luminescence Characteristics. Fifth International Conference on Solid State Lighting, Bellingham, 2005, 594112.

[9] Fujita Y, Umayahara S. Tanabe. Influence of light scattering on luminous efficacy in Ce:YAG glass-ceramic phosphor. Journal of the Ceramic Society of Japan, 2010, 118(2): 128–131.

[10] Masakasu Kawashita, Ryo Shineha, Kim Hyun-Min, et al. Preparation of ceramic microspheres for in situ radiotherapy of deep-seated cancer. Biomaterials, 2003, 24(17): 2955–2963.

[11] Zhao Di, Huang Wenhai, Rahaman Mohamed, et al. Preparation and characterization of composite microspheres for brachytherapy and hyperthmia treatment of cancer. Materials Science and Engineering C, 2012, 32: 276–281.

[12] Mao Huahai, Malin Selleby, Olga Fabrichnaya. Thermodynamic reassessment of the Y2O3-Al2O3-SiO2 system and its subsystems. Computer Coupling of Phase Diagrams and Thermochemistry, 2008, 32: 399–412.

[13] Zhang Yuepin, Xia Haipin, Zhang Xinmin, et al. Preparation and spectroscopic properties of Yb:YAG glassc-ceramics. Journal of Inorganic Materials, 2006, 21(6): 1307–1311.

[14] Sainz M A, Osendi M I, Miranzo P. Protective Si-Al-O-Y glass coatings on stainless steel in situ prepared by combustion flame spraying. Surface & Coatings Technology, 2008, 202(9): 1712-1717.

[15] Arita Irene H, Wilkinson David S, Purdy Gary R. Crystallization of yttria-alumina-silica glasses. Journal of the American Ceramic Society, 1992, 75(12): 3315–3320.

[16] Yang Zengchao, Liu Guanghua, Li Jiangtao, et al. Preparation of transparent Y2O3-Al2O3-SiO2 glasses by high-gravity combustion synthesis with heating assistance. Journal of the American Ceramic Society, 2012, 95(6): 1799–1802.

[17] Li Xiuying, Lu Anxian. Preparation of Y-Al-Si-O-N glass-ceramics with Y3Al5O12 major phase. Journal of Central South University (Science and Technology), 2011, 42(3): 636–643.

[18] Najim Sadiki, Jean Pierre Coutures, Catherine Fillet, et al. Crystallization of lanthanum and yttrium aluminosilicate glasses. Journal of Nuclear Materials, 2006, 348:70–78.

超重力熔铸Y₂O₃-Al₂O₃-SiO₂玻璃的晶化行为研究

Investigation on Crystallization Behavior of Y₂O₃-Al₂O₃-SiO₂ Glass Prepared by High-gravity Combustion Synthesis

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