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TiO2和α-Al2O3晶体的生长习性

李汶军; 郑燕青; 施尔畏; 陈之战; 殷之文   

  1. 中国科学院上海硅酸盐研究所, 上海 200050
  • 收稿日期:1999-12-01 修回日期:2000-02-29 出版日期:2000-12-20 网络出版日期:2000-12-20

Growth Habit of TiO2 and а-Al2O3 Crystals

LI Wen-JUn; ZHENG Yan-Qing; SHI Er-Wei; CHEN Zhi-Zhan; YIN Zhi-Wen   

  1. Shanghai Institute of Ceramics; Chinese Academy of Science; Shanghai 201800; China
  • Received:1999-12-01 Revised:2000-02-29 Published:2000-12-20 Online:2000-12-20

摘要: 通过水热法制备粉体的实验观察到金红石、锐钛矿和а-Al晶体的生长习性.采用配位多面体生长习性法则合理地解释了TiO和а-Al的生长习性.其主要结果为а-Al晶体的生长习性为平板{0001},其各晶面的生长速度为:{0001}{1123}{0112}{1120}{0110}。金红石的生长习性为柱状,其各晶面的生长速度为:<110><100><101><001><111>;锐钛矿的生长习性为四面体,其各晶面的生长速度为<010><001><010><111>.而PBC理论很难合理地解释α-Al晶体的生长习性.

关键词: TiO2, α-Al2O3, 生长习性, 水热法

Abstract: The observed growth habit of TiO2, α-Al2O3 crystals observed under hydrothermal conditions were successfully explained by the coordination polyhedron rule concerning
growth habit. It is concluded that the habit of α-Al2O3 crystal is the hexagonal platy {0001}, and the relationship of growth rate of various faces is:
V{0001}<V{1123}<V{0112}<V{1120}<V{1010}; the growth habit of rutile (TiO2) crystal is elongated prismatic form, and the relationship
of growth rate of various faces is: V<110><V<100><V<101><V<001><V<111>; the growth habit of anatase (TiO2) crystal is
a tetrahedron, and the relationship of growth rate of various faces is: V<010>=V<001>>V<010>>V<111>. These results were compared with previous studies based on PBC theory.

Key words: TiO2, α-Al2O3, growth habit, hydrothermal method

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