钛表面激光熔覆原位制备Ti5Si3涂层结构及摩擦学性能

doi:10.3724/SP.J.1077.2012.11661

无机材料学报 ›› 2012, Vol. 27 ›› Issue (9): 970-976.DOI: 10.3724/SP.J.1077.2012.11661 CSTR: 32189.14.SP.J.1077.2012.11661

钛表面激光熔覆原位制备Ti₅Si₃涂层结构及摩擦学性能

郭纯^1,2, 周健松¹, 陈建敏¹

(1. 中国科学院兰州化学物理研究所, 兰州 730000; 2. 中国科学院研究生院, 北京100039)

收稿日期:2011-10-24 修回日期:2012-03-02 出版日期:2012-09-20 网络出版日期:2012-08-28
作者简介:郭纯(1984-), 男, 博士研究生. E-mail: guochun@licp.cas.cn
基金资助:
国家自然科学基金重点项目(51045004); 中科院知识创新工程重要方向项目(YYYJ-0913)

Microstructure and Tribological Properties of Ti₅Si₃ Coating In-situ Synthesized on Titanium Substrate by Laser Cladding

GUO Chun^1,2, ZHOU Jian-Song¹, CHEN Jian-Min¹

(1. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China; 2. Graduate University of the Chinese Academy of Sciences, Beijing 100039, China)

Received:2011-10-24 Revised:2012-03-02 Published:2012-09-20 Online:2012-08-28
About author:GUO Chun. E-mail: guochun@licp.cas.cn
Supported by:
National Natural Science Foundation of China (51045004); Knowledge Innovation Project in Chinese Academy of Science (YYYJ-0913)

摘要/Abstract

摘要： 利用激光熔覆技术在钛表面预置硅粉原位制备了Ti₅Si₃涂层. 用XRD、SEM和TEM分析了涂层的组成和组织结构. 在UMT摩擦磨损试验机上对Ti₅Si₃涂层在不同载荷和不同滑动速度下的摩擦磨损性能进行了测试. 实验结果表明: 涂层的物相主要是Ti₅Si₃相和基材Ti相, 涂层的显微结构为球状和块状晶, Ti₅Si₃涂层具有较高的显微硬度, 涂层截面的平均显微硬度约为840 HV_0.2, 是钛基材的4.4倍; Ti₅Si₃涂层可显著提高钛基材的耐磨性能; Ti₅Si₃涂层的磨损机理为磨粒磨损和粘着磨损.

关键词: 钛, 激光熔覆, 涂层, Ti₅Si₃, 摩擦性能

Abstract: Using silicon powder as the precursor to improve the wear resistance of Ti₅Si₃ coating was in situ successfully synthesized on Ti substrate by laser cladding. Friction and wear behavior of Ti₅Si₃ coatings under different normal loads and sliding speeds wear test conditions were evaluated using a UMT-2MT friction and wear tester. It is found that the prepared coating is mainly composed of Ti₅Si₃ and Ti phases. The high resolution transmission electron microscopy results confirm further the existence of Ti₅Si₃ compound in the prepared coating. Ti₅Si₃ coating has spherical and block-like microstructure. The Ti₅Si₃ coating shows a high average hardness of approximately 840 HV_0.2, which is about 4.4 times as that of Ti substrate. Tribological properties of the prepared Ti₅Si₃ coating were systematically evaluated. It is found that the Ti₅Si₃coating can improve the wear resistance of Ti. The wear mechanism of Ti₅Si₃ coating is abrasive and adhesive wear when sliding against GCr15 steel ball under all wear conditions.

Key words: titanium, laser cladding, coating, Ti₅Si₃, tribological property

中图分类号:

TG115

郭纯, 周健松, 陈建敏. 钛表面激光熔覆原位制备Ti₅Si₃涂层结构及摩擦学性能[J]. 无机材料学报, 2012, 27(9): 970-976.

GUO Chun, ZHOU Jian-Song, CHEN Jian-Min. Microstructure and Tribological Properties of Ti₅Si₃ Coating In-situ Synthesized on Titanium Substrate by Laser Cladding[J]. Journal of Inorganic Materials, 2012, 27(9): 970-976.

参考文献

[1] Bruni S, Martinesi M, Stio M, et al. Effects of surface treatment of Ti-6Al-4V titanium alloy on biocompatibility in cultured human umbilical vein endothelial cells. Acta Biomater., 2005, 1(2): 223-234.

[2] DAS M, BALLA V K, BASU D, et al. Laser processing of SiC-particle-reinforced coating on titanium. Scr. Mater., 2010, 63(4): 438-441.

[3] LI X M, LI Y S, HAN Y. Preparation of alumina coatings on titanium by cathodic micro-arc electrodeposition. Journal of Inorganic Materials, 2005, 20(6): 1493-1499.

[4] GUO L T, LIU X C, GAO J Q, et al. Effect of titaniumsurface oxidation on the bonding strength of Ti-porcelain. Journal of Inorganic Materials, 2009, 24(5): 915-918.

[5] GUO C, ZHOU J, ZHAO J, et al. Effect of ZrB2 on the microstructure and wear resistance of Ni-based composite coating produced on pure Ti by laser cladding. Tribol. Trans., 2011, 54(1): 80-86.

[6] BAKER T N, SELAMAT M S. Surface engineering of Ti-6Al-4V by nitridingand powder alloying using CW CO2 laser. Mater. Sci. Technol., 2008, 24(4): 189-200.

[7] YILDIZ F, YETIM A, ALSARAN A, et al. Plasma nitriding behavior of Ti6Al4V orthopedic alloy. Surf. Coat. Technol., 2008, 202(11): 2471-2476.

[8] JIANG P, HE X L, LI X X, et al. Wear resistance of a laser surface alloyed Ti-6Al-4V alloy. Surf. Coat. Technol., 2000, 130: 24-28.

[9] NOLAN D, HUANG S, LESKOVSEK V, et al. Sliding wear of titanium nitride thin films deposited on Ti-6Al-4V alloy by PVD and plasma nitriding processes. Surf. Coat. Technol., 2006, 200(20/21): 5698-5705.

[10] LI Q J, WU H H, WANG J B, et al. Effects of pulse frequencies on properties of MAO coatings on pure titanium. Journal of Inorganic Materials, 2006, 21(2): 488-492.

[11] GONG Y S, TU R, GOTO T. High-speed deposition of oriented TiNx films by laser metal-organic chemical vapor deposition. Journal of Inorganic Materials, 2010, 25(4): 391-395.

[12] ZHANG S, ZHANG C H, WU W T, et al. An in situ formed TiC particle reinforcement composite coating induced by laser melting on surface of alloy Ti6Al4V and its wearing performance. Acta Metall. Sinica, 2001, 37(3): 315-320.

[13] GUO C, ZHOU J, ZHAO J, et al. Microstructure and friction and wear behavior of laser boronizing composite coatings on titanium substrate. Appl. Surf. Sci., 2011, 257(9): 4398-4405.

[14] GUO B, ZHOU J, ZHANG S, et al. Phase composition and tribological properties of Ti–Al coatings produced on pure Ti by laser cladding. Appl. Surf. Sci., 2007, 253(24): 9301-9310.

[15] GUO C, ZHOU J, ZHAO J, et al. Improvement of the oxidation and wear resistance of pure Ti by laser-cladding Ti3Al coating at elevated temperature. Tribol. Lett., 2011, 42(2): 151-159.

[16] GU D D, SHEN Y F. Microstructure of in situ TiN-Ti5Si3 composites prepared by selective laser melting. Acta Metall Sinica, 2010, 46(6): 761-768.

[17] Counihan P J, Crawford A, Thadhani N N. Influence of dynamic densification on nanostructure formation in Ti5Si3 intermetallic alloy and its bulk properties. Mater. Sci. Eng. A , 1999, 267: 26-35.

[18] GU D D, HAGEDORN Y C, MEINERS W, et al. Selective laser melting of in-situ TiC/Ti5Si3 composites with novel reinforcement architecture and elevated performance. Surf. Coat. Technol., 2011, 205(10): 3285-3292.

[19] WANG H M, LIU Y F. Microstructure and wear resistance of laser clad Ti5Si3/NiTi2 intermetallic composite coating on titanium alloy. Mater. Sci. Eng. A , 2002, 338:126-132.

[20] LIU X, WANG H. Microstructure, wear and high-temperature oxidation resistance of laser clad Ti5Si3/γ/TiSi composite coatings on γ-TiAl intermetallic alloy. Surf. Coat. Technol., 2006, 200(14/15): 4462-4470.

[21] RAO K, ZHOU J. Characterization and mechanical properties of in situ synthesized Ti5Si3/TiAl composites. Mater. Sci. Eng. A, 2003, 356(1/2): 208-218.

[22] GUO C, ZHOU J, ZHAO J, et al. Microstructure and tribological properties of ZrB2-containing composite coating produced on pure Ti Substrate by laser surface alloying. J. Tribol., 2011, 133(1): 011301-1-7.

[23] Selvan J S, Subramanian K, Nath A K, et al. Laser boronising of Ti-6Al-4V as a result of laser alloying with pre-placed BN. Mater. Sci. Eng. A , 1999, 260(1/2): 178--87.

[24] Eskin S, Zahavi J, Berner A. CO2-Laser nitriding as a result of Ti coating modification in a nitrogen atmosphere. 1. Features of nitriding process. Laser Eng., 1995, 4(2): 85-96.

[25] YAN M, LIU B, LI J. 中国航空材料手册, 第四卷. 北京: 中国标准出版社, 2001: 8-21.

[26] PEI Y T, OUYANG J H, LEI T Q. Developments of laer clad composite coatings. Journal of Harbin Institute of Technology, 1994, 26(1): 73-80.

[27] BLAU P J. Metals Handbook, 10th Edition. USA:The Materials Information Society, 1990: 414-418.

[28] LA P, XUE Q, LIU W. Effects of boron doping on tribological properties of Ni3Al-Cr7C3 coatings under dry sliding. Wear, 2001, 249(1/2): 94-100.

[29] ARCHARD J F. Contact and rubbing of flat surfaces. J .Appl. Phys., 1953, 24(8): 981-988.

[30] CHU C L, WU S K. A study on the dry uni-directional sliding behaviour of tiatnium aluminides. Scripta Matall Mater., 1999, 33(1): 139-143.

[31] BHUSHAN B. Introduction to Tribology. New York:John Wiley & Sons, 2002: 210-212.

钛表面激光熔覆原位制备Ti₅Si₃涂层结构及摩擦学性能

Microstructure and Tribological Properties of Ti₅Si₃ Coating In-situ Synthesized on Titanium Substrate by Laser Cladding

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