Eu3+掺杂Bi4Si3O12材料的制备和发光特性

doi:10.3724/SP.J.1077.2011.11200

无机材料学报 ›› 2011, Vol. 26 ›› Issue (12): 1341-1344.DOI: 10.3724/SP.J.1077.2011.11200 CSTR: 32189.14.SP.J.1077.2011.11200

• 研究快报 • 上一篇

Eu³⁺掺杂Bi₄Si₃O₁₂材料的制备和发光特性

张彦, 徐家跃, 张婷婷

(上海应用技术学院材料科学与工程学院, 上海200235)

收稿日期:2011-04-01 修回日期:2011-06-03 出版日期:2011-12-20 网络出版日期:2011-11-11
作者简介:ZHANG Yan(1977-), male, PhD, lecturer. E-mail: yanzhang@sit.edu.cn
基金资助:
National Natural Science Foundation of China (50972093); National Key Basic Research Program (2011CB612310); Shanghai Municipal Education Commission (J51504, 09ZZ196, 10XD1403800, yyy09005); SIT Research Project on Optical Functional Crystals (TDP 2009-03, 1020K116001 - YJ2009-01)

Synthesis and Luminescence Properties of Eu³⁺-doped Bi₄Si₃O₁₂

ZHANG Yan, XU Jia-Yue, Zhang Ting-Ting

(School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 200235, China)

Received:2011-04-01 Revised:2011-06-03 Published:2011-12-20 Online:2011-11-11
About author:ZHANG Yan(1977-), male, PhD, lecturer. E-mail: yanzhang@sit.edu.cn
Supported by:
National Natural Science Foundation of China (50972093); National Key Basic Research Program (2011CB612310); Shanghai Municipal Education Commission (J51504, 09ZZ196, 10XD1403800, yyy09005); SIT Research Project on Optical Functional Crystals (TDP 2009-03, 1020K116001 - YJ2009-01)

摘要/Abstract

摘要： 采用传统的固相合成法制备了Eu³⁺掺杂的Bi₄Si₃O₁₂发光材料. 使用X射线粉末衍射技术对制备的发光粉体进行了表征. Eu³⁺掺杂的Bi₄Si₃O₁₂材料的激发谱表明, 在265 nm处强而宽的谱带对应于Eu³⁺ → O^2-之间的电荷转移跃迁带. 在用紫外光激发的荧光光谱中, Eu³⁺掺杂的Bi₄Si₃O₁₂材料在614 nm处有强的红光发射. 材料的激发和发射光谱结果表明, Eu3+掺杂的Bi₄Si₃O₁₂有望做为红色固体发光的候选材料.

关键词: 硅酸铋, 荧光粉, 铕发光

Abstract: Eu³⁺-doped Bi₄Si₃O₁₂ phosphors were synthesized by the conventional solid state reaction. X-ray diffraction analysis confirmed the formation of Bi₄Si₃O₁₂: Eu3+. The excitation spectra of Eu3+-doped Bi₄Si₃O₁₂ show an intense broad band with maximum at 265 nm related to Eu³⁺→O^2- charge transfer transition. Photoluminescence spectra indicate that the phosphor emits strong red light centered at 614 nm under UV light excitation. Due to high emission intensity and a good excitation profile, the Eu³⁺-doped Bi₄Si₃O₁₂ phosphor may be a promising candidate in solid state lighting applications.

Key words: bismuth silicate, phosphor, europium luminescence

中图分类号:

TQ174

张彦, 徐家跃, 张婷婷. Eu³⁺掺杂Bi₄Si₃O₁₂材料的制备和发光特性[J]. 无机材料学报, 2011, 26(12): 1341-1344.

ZHANG Yan, XU Jia-Yue, Zhang Ting-Ting. Synthesis and Luminescence Properties of Eu³⁺-doped Bi₄Si₃O₁₂[J]. Journal of Inorganic Materials, 2011, 26(12): 1341-1344.

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Eu³⁺掺杂Bi₄Si₃O₁₂材料的制备和发光特性

Synthesis and Luminescence Properties of Eu³⁺-doped Bi₄Si₃O₁₂

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