无机材料学报

• 研究论文 • 上一篇    下一篇

螺旋形碳纳米管的制备表征及其生长机理的探讨

吴明在1; 姚连增1; 姜国伟1; 刘伟丰1; 蔡维理1; 李晓光1; 姚震2   

  1. 1. 中国科学技术大学材料科学与工程系, 合肥 230026; 2. 德克萨斯大学物理系, 奥斯汀, 美国
  • 收稿日期:2001-12-30 修回日期:2002-02-27 出版日期:2003-01-20 网络出版日期:2003-01-20

Fabrication, Characterization and Its Growth Mechanism of Helical Carbon Nanotubes

WU Ming-Zai1; YAO Lian-Zeng1; JIANG Quo-Wei1; LIU Wei-Feng1; CAI Wei-Li1; LI Xiao-Guang1; YAO Zhen2   

  1. 1.Department of Materials Science and Engineering; University of Science and Technology of China; Hefei 230026; China; 2.Department of Physics; The University of Texas at Austin; Austin; TX 78712-1081 USA
  • Received:2001-12-30 Revised:2002-02-27 Published:2003-01-20 Online:2003-01-20

摘要: 采用气凝胶与干凝胶两种催化剂载体通过化学气相淀积方法制备出螺旋状的碳纳米管.研究结果表明:气凝胶催化剂载体所制备出的螺旋碳纳米管和干凝胶载体所制备出的螺旋碳管相比较具有以下几个特点:(1)较好的石墨化程度,(2)较小的直径,(3)较好的螺旋形态,即较好的螺距一致性.分析结果认为气凝胶独特的介孔性质是导致气凝胶样品所制备的碳管具有以上特点的根本原因.另外,还提出催化剂颗粒周边上催化活性的各向异性将导致螺旋碳管的生长.

关键词: 化学气相淀积, 螺旋碳管, 气凝胶

Abstract: Helical carbon nanotubes were synthesized by a chemical vapour deposition method from both silica aerogels and silica xerogels containing catalysts.
The research result shows that the helical carbon nanotubes prepared from the silica aerogels have the following pecularities compared with those from
silica xerogels: (1) more degree of graphitization; (2) smaller diameter; (3) better helical shape, namely, the more identical pitch. The peculiar
mesoscopic properties of aerogels are responsible for those above pecularties of helical carbon nanotubes prepared from silica aerogels when compared
with those from xerogels. What’s more, the anisotropy of catalytic activity of the catalyst particles leads to the growth of helical carbon nanotubes.

Key words: chemical vapour deposition, helical carbon nantotube, aerogel

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