无机材料学报

• 研究论文 • 上一篇    下一篇

PMN-PT弛豫铁电粉体的溶胶-凝胶法制备及其性质

王歆1; 庄志强1; 齐雪君2   

  1. 1. 华南理工大学材料学院, 广州 510640; 2. 中国科学院上海硅酸盐研究所, 上海 200050
  • 收稿日期:2001-03-02 修回日期:2001-03-19 出版日期:2002-03-20 网络出版日期:2002-03-20

Preparation and Characterization of PMN-PT Relax Ferroelectric Powders by Sol-Gel Method

WANG Xin1; ZHUANG Zhi-Qiang1; QI Xue-Jun2   

  1. 1. College of Materials Sci. & Eng.; South China University of Technology; Guangzhou 510640; China; 2. Shanghai Institute of Ceramics; Academy of Sciences of China; Shanghai 200050; China
  • Received:2001-03-02 Revised:2001-03-19 Published:2002-03-20 Online:2002-03-20

摘要: 以无机盐或氧化物Nb、MgO、TiCl和Pb(AC)、3HO为原材料,柠檬酸和EDTA为复合螫合剂,乙二醇为溶剂,分别制备Nb、Mg-Nb、Ti和Pb的有机化合物前驱液,采用溶胶-凝胶工艺制备PMN-PT弛豫铁电陶瓷粉体及其烧结体.讨论了制备工艺和螯合剂等对金属有机化合物溶液的性质、材料物相形成和介电性能的影响.

关键词: 溶胶-凝胶法, PMN-PT弛豫铁电体, 柠檬酸-EDTA复合螯合剂, 无机盐

Abstract: PMN-PT relax ferroelectric fine powders were prepared by a sol-gel routes with inorganic compounds, Nb2O5, TiCl4 and Pb(Ac)2·3H2O as raw materials, citric acid and EDTA as co-chelate and ethylene glycol as solvent. The effects of processing technology and complex/ chelate on the properties of organic compounds precursors, the powders synthesis, the phases formation and dielectric properties were discussed.

Key words: sol-gel method, PMN-PT relax ferroelectric, CA-EDTA co-chelate, inorganic salts

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