Journal of Inorganic Materials ›› 2013, Vol. 28 ›› Issue (1): 45-50.DOI: 10.3724/SP.J.1077.2013.12066
• Orginal Article • Previous Articles Next Articles
ZHAO Xin, WANG De-Ping, QIU Wen-Qing, YE Song
Received:2012-02-02
Revised:2012-03-27
Published:2013-01-10
Online:2012-12-20
About author:ZHAO Xin. E-mail: zhaoxin_cynthia@163.com
Supported by:CLC Number:
ZHAO Xin, WANG De-Ping, QIU Wen-Qing, YE Song. Influence of Strontium on Hydroxyapatite Morphology and Luminescence Characteristics[J]. Journal of Inorganic Materials, 2013, 28(1): 45-50.
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| Sample | Sr(NO3)2 /mmol | Ca(NO3)2·4H2O/mmol | χSr=n(Sr)/ n(Ca+Sr) |
|---|---|---|---|
| S1 | 0 | 3 | 0 |
| S2 | 0.9 | 2.1 | 0.3 |
| S3 | 1.5 | 1.5 | 0.5 |
| S4 | 3 | 0 | 1 |
Table 1 Formula of strontium hydroxyapatite samples
| Sample | Sr(NO3)2 /mmol | Ca(NO3)2·4H2O/mmol | χSr=n(Sr)/ n(Ca+Sr) |
|---|---|---|---|
| S1 | 0 | 3 | 0 |
| S2 | 0.9 | 2.1 | 0.3 |
| S3 | 1.5 | 1.5 | 0.5 |
| S4 | 3 | 0 | 1 |
Fig. 1 XRD patterns of samples S1, S2, S3 and S4
| Sample | Product | 2θ(211) | (a=b)/nm | c/nm |
|---|---|---|---|---|
| S1 | Ca10(PO4)6(OH)2 | 31.54 | 0.94533 | 0.69063 |
| S2 | Ca7Sr3(PO4)6(OH)2 | 31.40 | 0.95299 | 0.70126 |
| S3 | Ca5Sr5(PO4)6(OH)2 | 31.22 | 0.95931 | 0.70945 |
| S4 | Sr10(PO4)6(OH)2 | 30.40 | 0.98235 | 0.72865 |
Table 2 Crystalline phase, peak position (211) and lattice parameters of different samples
| Sample | Product | 2θ(211) | (a=b)/nm | c/nm |
|---|---|---|---|---|
| S1 | Ca10(PO4)6(OH)2 | 31.54 | 0.94533 | 0.69063 |
| S2 | Ca7Sr3(PO4)6(OH)2 | 31.40 | 0.95299 | 0.70126 |
| S3 | Ca5Sr5(PO4)6(OH)2 | 31.22 | 0.95931 | 0.70945 |
| S4 | Sr10(PO4)6(OH)2 | 30.40 | 0.98235 | 0.72865 |
Fig. 2 FTIR spectra of samples S1, S2, S3 and S4
Fig. 3 SEM images of samples (a) S1, (b) S2, (c) S3 and (d) S4
Fig. 4 Excitation (a) and emission (b) spectra of samples S1, S2, S3 and S4
Fig. 5 XPS spectra of samples S1, S2 and S3
Fig. 6 XPS deconvulation for P2p3 peaks of samples S1, S2 and S3
| Sample | OKLL-Mg | O1s | Ca2s | Ca2p1/2 | Ca2p3/2 | C1s | C1s(Ⅲ) | P2s | P2p3 | Sr3d |
|---|---|---|---|---|---|---|---|---|---|---|
| S1 | 750.20 | 535.80 | 443.21 | 355.40 | 352.20 | 289.00 | - | 195.06 | 138.00 | - |
| S2 | 750.20 | 536.60 | 444.00 | 356.00 | 352.60 | 289.80 | 284.54 | 195.27 | 140.59 | 140.59 |
| S3 | 750.20 | 535.60 | 443.82 | 355.00 | 351.80 | 288.00 | 283.00 | 194.20 | 139.00 | 137.23 |
Table 3 XPS peak energies of samples S1, S2 and S3
| Sample | OKLL-Mg | O1s | Ca2s | Ca2p1/2 | Ca2p3/2 | C1s | C1s(Ⅲ) | P2s | P2p3 | Sr3d |
|---|---|---|---|---|---|---|---|---|---|---|
| S1 | 750.20 | 535.80 | 443.21 | 355.40 | 352.20 | 289.00 | - | 195.06 | 138.00 | - |
| S2 | 750.20 | 536.60 | 444.00 | 356.00 | 352.60 | 289.80 | 284.54 | 195.27 | 140.59 | 140.59 |
| S3 | 750.20 | 535.60 | 443.82 | 355.00 | 351.80 | 288.00 | 283.00 | 194.20 | 139.00 | 137.23 |
Fig. 7 XPS deconvulation for C1s of samples S1, S2 and S3
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