Preparation and Magnetic Properties of Sr1-xLaxFe12-xCoxO19 Nanofibers by Electrospinning

doi:10.3724/SP.J.1077.2011.00797

Abstract

Abstract: PVP/Sr_1-xLa_xFe_12-xCo_xO₁₉(x=0-0.5) composite nanofiers were fabricated by Sol-Gel process and electrospinning technique. After high temperature calcination, Sr_1-xLa_xFe_12-xCo_xO₁₉(x=0-0.5) ferrite nanofibers were successfully obtained. The morphology, phases, structure and magnetic properties of the nanofibers were characterized by Scanning electron microscope(SEM), Transmission electron microscope(TEM), X-ray diffraction(XRD) and Vibrating sample magnetometer(VSM). The results show that the samples have an uniform diameter of 80-150 nm after calcined at 800℃. The Sr_1-xLa_xFe_12-xCo_xO₁₉(x=0-0.5) ferrite nanofiers all exhibit a hard magnetic performance, and chemical composition have considerable influence on magnetic properties of these ferrite nanofibers. The Sr_1-xLa_xFe_12-xCo_xO₁₉(x=0-0.5) ferrite nanofiers exhibit M-type strontium ferrites, CoFe₂O₄ phase and LaFeO₃ phase at x≥0.3. The substitutions of La³⁺ and Co²⁺ obviously increase the magnetic properties of the as-prepared samples at x≤0.1, the coercivity(Hc), saturation magnetization(Ms) and remanent magnetization(Mr) of Sr_0.9La_0.1Fe_11.9Co_0.1O₁₉ nanofibers are 432.02 kA/m, 54.7 A·m²/kg, 28.9 A·m2/kg, respectively. The magnetic properties of the fibers increase significantly, compared with that of the Sr_0.9La_0.1Fe_11.9Co_0.1O₁₉ powder samples.

Key words: electrospinning, M-type strontium ferrites, La-Co substitution, magnetic properties

CLC Number:

TQ174

LI Cong-Ju, ZHANG Lian-Lian, WANG Jiao-Na. Preparation and Magnetic Properties of Sr_1-xLa_xFe_12-xCo_xO₁₉Nanofibers by Electrospinning[J]. Journal of Inorganic Materials, 2011, 26(8): 797-801.

References

[1] Li C J, Wang J N. Electrospun SrRe0.6Fe11.4O19 magnetic nanofibers: fabrication and characterization. Materials Letters, 2010, 64(5): 586-588.

[2] Tenaud P, Morel A, Kools F, et al. Recent improvement of hard ferrite permanent magnets based on La-Co substitution. Journal of Alloys and Compounds, 2004, 370(1/2): 331-334.

[3] Janasi S R, Emura M, Landgraf F J G, et al. The effects of synthesis variables on the magnetic properties of coprecipitated barium ferrite powders. Journal of Magnetism and Magnetic Materials, 2002, 238(1): 168-172.

[4] 李锐, 洪炜宁, 孙学峰．Sr1-xLaxFe12-xCoxO19铁氧体纳米颗粒的结构与磁性．磁性材料及器件, 2009, 40(3): 32-34, 45．

[5] Kishan Reddy N, Mulay V N. Magnetic properties of W-type ferrites. Materials Chemistry and Physics, 2002, 76(1): 75-76.

[6] Liu X S, Hernandez-Gomez P, Huang K, et al. Research on La3+-Co2+-substituted strontium ferrite magnets for high intrinsic coercive force. Journal of Magnetism and Magnetic Materials, 2006, 305(2): 524-528.

[7] Wiesinger G, Muller M, Grossinger R. et al. Substituted ferrites studied by nuclear methods. Physica Status Solidi A, 2002, 189(2): 499-508.

[8] 黄凯, 刘先松．Sr1-xLaxFe12-xCoxO19铁氧体的结构与磁性．磁性材料及器件, 2008, 39(4): 22-25．

[9] Wu H, Zhang R, Liu X, et al. Electrospinning of Fe, Co, and Ni nanofibers: synthesis, assembly, and magnetic properties. Chemistry of Materials, 2007, 19(14): 3506-3511.

[10] 李从举, 翟国钧, 付中玉, 等(LI Cong-Ju, et al)．TiO2纳米纤维无纺布的制备及光催化性能研究．无机化学学报(Chinese J. Inorg. Chem.), 2006, 11(22): 2061-2064．

[11] Ju Y W, Park J H, Jung H R, et al. Electrospun MnFe2O4 nanofibers: preparation and morphology. Conlposites Science and Technology, 2008, 68(7/8): 1704-1709.

[12] 郭远征, 李从举, 王娇娜(GUO Yuan-Zheng, et al)．纳米BaFe12O19纤维的电纺制备及磁性研究. 无机化学学报(Chinese J. Inorg. Chem.), 2009, 25(6): 1018-1021．

[13] 刘明权, 沈湘黔, 孟献丰, 等(LIU Ming-Quan, et al)．M型锶铁氧体纳米纤维静电纺丝和磁性能．无机材料学报(Journal of Inorganic Materials), 2010, 25(1): 68-72．

[14] Morel A, Le Breton J M, Kreisel J, et al. Sublattice occupation in Sr1-xLaxFe12-xCoxO19 hexagonal ferrite analyzed by Mossbauer spectrometry and Raman spectroscopy. Journal of Magnetism and Magnetic Materials, 2002, 242-245(Part 2): 1405-1407.

[15] Pieper M W, Morel A, Kools F. NMR analysis of La+Co doped M-type ferrites. Journal of Magnetism and Magnetic Materials, 2002, 242-245(Part 2): 1408-1410.

[16] NGA TTV, Hien T D, Duong N P, et al. Structural and magnetic properties of SrLaxFe12-xO19(x=0-0.15) prepared by using a Sol-Gel method. Journal of the Korean Physical Society, 2008, 52(5): 1474-1477.

Preparation and Magnetic Properties of Sr_1-xLa_xFe_12-xCo_xO₁₉Nanofibers by Electrospinning

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