Preparation and Characterization of Graphene Oxide/β-cyclodextrin Supramolecular Hybrid Material

doi:10.3724/SP.J.1077.2012.00596

Abstract

Abstract: A novel hybrid material based on graphene oxide was synthesized by utilizing organic synthesis and supramolecular self-assembly techniques. And the structures of graphene derivatives and product were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), transmission electron microscope (TEM) and scanning electron microscopy (SEM). Thermogravimetric analysis (TG) shows that introduction of organic groups would significantly enhance the thermal stability of derivatives based on graphene oxide in the range of 50-400℃. The nanomaterial obtained has great potential practical significance and theoretical value to develop organic-inorganic hybrid materials based on graphene with novel features.

Key words: graphene oxide, β-cyclodextrin, supramolecular self-assembly, organic inorganic hybrid material

CLC Number:

TB332

ZHANG Shu-Peng, SONG Hai-Ou. Preparation and Characterization of Graphene Oxide/β-cyclodextrin Supramolecular Hybrid Material[J]. Journal of Inorganic Materials, 2012, 27(6): 596-602.

References

[1] Liu J, Chen G, Jiang M. Supramolecular hybrid hydrogels from noncovalently functionalized fraphene with block copolymers. Macromolecules, 2011, 44(19): 7682-7691.

[2] Allen M J, Tung V C, Kaner R B. Honeycomb carbon: a review of graphene. Chem. Rev., 2010, 110(1): 132-145.

[3] Rümmeli M H, Rocha C G, Ortmann F, et al. Graphene: piecing it together. Adv. Mater., 2011, 23(39): 4471-4490.

[4] Huang Y, Chen Y S. Functionalization of graphene and their applications. Sci. China. Chem., 2009, 39(9): 887-896.

[5] Dreyer D R, Park S, Bielawski C W, et al. The chemistry of graphene oxide. Chem. Soc. Rev., 2010, 39(1): 228--40.

[6] Alzari V, Nuvoli D, Scognamillo S, et al. Graphene-containing thermoresponsive nanocomposite hydrogels of poly (N-isopropylacrylamide) prepared by frontal polymerization. J. Mater. Chem., 2011, 21 (24): 8727-8733.

[7] Hummers W S, Offeman R E. Preparation of graphitic oxide. J. Am. Chem. Soc., 1958, 80: 1339.

[8] He H. A new structural model for graphite oxide. Chem. Phys. Lett., 1998, 287(1/2): 53-56.

[9] Lerf A, He H, Forster M, et al. Structure of graphite oxide revisited. J. Phys. Chem. B., 1998, 102(23): 4477-4482.

[10] Ogoshi T, Ichihara Y, Yamagishi T, et al. Supramolecular polymer networks from hybrid between graphene oxide and per-6-amino-β-cyclodextrin. Chem. Commun., 2010, 46(33): 6087-6089.

[11] Li W, Tang X Z, Zhang H B, et al. Simultaneous surface functionalization and reduction of graphene oxide with octadecylamine for electrically conductive polystyrene composites. Carbon, 2011, 49(14): 4724-4730.

[12] Yuan X Y.Progress in preparation of graphene. J. Inorg. Mater, 2011, 26(6): 561-570.

[13] 金征宇, 徐学明, 陈寒青, 等. 环糊精化学-制备与应用. 北京: 化学工业出版, 2009, 1(1): 1-30.

[14] Chen Y, Li F, Liu B W, et al. Thermodynamic Origin of selective binding of β-cyclodextrin derivatives with chiral chromophoric substituents toward steroids. J. Phys. Chem. B, 2010, 114(49): 16147-16155.

[15] Shen Z, Ma J, Liu Y, et al. β-cyclodextrin-immobilized (4S)-phenoxy-(S)-proline as a catalyst for direct asymmetric aldol reactions. Chirality, 2005, 17(9): 556-558.

[16] Kim H, Abdala A A, Macosko C W. Graphene/polymer nanocomposites. Macromolecules, 2010, 43 (16): 6515-6530.

[17] Kovtyukhova N I, Ollivier P J, Martin B R, et al. Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations. Chem. Mater., 1999, 11: 771-778.

[18] Stankovich S, Dikin D A, Piner R D, et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon, 2007, 45(7): 1558-1565.

[19] Stankovich S, Piner R, Nguyen S, et al. Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets. Carbon, 2006, 44(15): 3342-3347.

[20] Ma W S, Zhou J W. Preparation of a dispersible graphene. Chem. J. Chin. Univ. 2010, 31(10): 1982-1986.

[21] Xu C, Wu X, Zhu J, et al. Synthesis of amphiphilic graphite oxide. Carbon, 2008, 46(2): 386-389.

[22] 谢晶曦, 常俊标, 王旭明. 红外光谱-在有机化学和药物化学中的应用, 修订版. 北京: 科学出版社, 2001, 1(1): 155-319.

[23] 宁永成. 有机化合物结构鉴定与有机波谱学, 2版. 北京: 科学出版社, 2003: 485-498.

[24] Zhang S P, Xiong P, Yang X J, et al. Novel PEG functionalized graphene nanosheets: enhancement of dispersibility and thermal stability. Nanoscale, 2011, 3(5): 2169-2174.

[25] Nethravathi C, Rajamathi M. Chemically modified graphene sheets produced by the solvothermal reduction of colloidal dispersions of graphite oxide. Carbon, 2008, 46(14): 1994-1998.

[26] Si Y, Samulski E T. Exfoliated graphene separated by platinum nanoparticles. Chem. Mater,. 2008, 20(21): 6792-6797.

[27] Ferrari A, Robertson J. Interpretation of Raman spectra of disordered and amorphous carbon. Phys. Rev. B, 2000, 61(20): 14095-14107.

[28] Worsley K A, Ramesh P, Mandal S K, et al. Soluble graphene derived from graphite fluoride. Chem. Phys. Lett., 2007, 445(1/2/3): 51-56.

[29] Wang G, Shen X, Wang B, et al. Synthesis and characterisation of hydrophilic and organophilic graphene nanosheets. Carbon, 2009, 47(5): 1359-1364.

[30] Becerril H A, Mao J, Liu Z, et al. Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano, 2008, 2(3): 463-470.