Fabrication and Properties of the Potassium Sodium Niobate/Cobalt Copper Ferritemultiferroic Magnetoelectric Composites

doi:10.3724/SP.J.1077.2012.12014

Journal of Inorganic Materials ›› 2012, Vol. 27 ›› Issue (10): 1042-1046.DOI: 10.3724/SP.J.1077.2012.12014

• Research Paper • Previous Articles Next Articles

Fabrication and Properties of the Potassium Sodium Niobate/Cobalt Copper Ferritemultiferroic Magnetoelectric Composites

XUAN Min-Jie¹, LIU Xin-Yu^1,2, YUAN Chang-Lai^1,2, XU Ji-Wen³, MA Jia-Feng^1,2

(1. School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China; 2. School of Materials Science and Engineering, Central South University, Changsha 410083, China; 3. School of Materials Science and Engineering, Shaanxi Normal University, Xi’an 710100, China)

Received:2012-01-05 Revised:2012-03-03 Published:2012-10-20 Online:2012-09-17
About author:XUAN Min-Jie. E-mail: xmjdy@126.com
Supported by:
The Information Materials Key Laboratory foundation of Guangxi (0710908-15-Z); Natural Science Foundation of Guangxi (2010GXNSFD013007)

Abstract

Abstract: (1–x)(0.9462K_0.5Na_0.5NbO₃-0.0498LiSbO₃-0.004BiFeO₃)-xCo_0.85Cu_0.15Fe₂O₄((1–x)(KNN-LS-BFO)-xCCFO) (x=0.1, 0.2, 0.3, 0.4, 0.5) multiferroic magnetoelectric ceramics were prepared by solid phase method. The presence of perovskite and spinel in the sintered composites were proved by XRD patterns and no impurity phase existed. SEM images show that particle size of KNN-LS-BFO is big and complete, while the particle size of CCFO is small. When x increases from 0.1 to 0.5, the piezoelectric coefficient of the composites decreases from 120 pC/N to 33 pC/N, While saturation magnetization and remanent magnetization increase and saturation magnetostriction constant increases from 18×10^–6 to 52×10^–6 approximately. When the applied magnetic field increases, the magnetoelectric properties of the composites increase to the maximum and then decrease. When the alternating magnetic field frequency is 1 kHz and x=0.3, the magnetoelectric voltage coefficient attains maximum value 20.6 mV/A.

Key words: multiferroic materials, magnetoelectric effect, magnetoelectric voltage coefficient

CLC Number:

TQ174

XUAN Min-Jie, LIU Xin-Yu, YUAN Chang-Lai, XU Ji-Wen, MA Jia-Feng. Fabrication and Properties of the Potassium Sodium Niobate/Cobalt Copper Ferritemultiferroic Magnetoelectric Composites[J]. Journal of Inorganic Materials, 2012, 27(10): 1042-1046.

References

[1] Yu J, Chu J H. Progress and prospect for high temperature single- phased magnetic ferroelectrics. Chin. Sci. Bull., 2008, 53(14): 2097–2112.

[2] Fiebig M. Revival of the magnetoelectric effect. J. Phys. D: Appl. Phys., 2005, 38(8): 123–152.

[3] Cheong S W, Mostovoy M. Multiferroics: a magnetic twist for ferroelectricity. Nature Mater., 2007, 6: 13–20.

[4] Hill N A. Why are there so few magnetic ferroelectrics. J. Phys. Chem. B., 2000, 104(29): 6694–6709

[5] HE Hong-Cai, LIN Yuan-Hua, NAN Ce-Wen. Multiferroic magnetoelectric composite film, Chin. Sci. Bull., 2008, 53(10): 1136–1148.

[6] Duong G V, Groessinger R, Turtelli S. Effect of structure on magnetoelectric properties of CoFe2O4-BaTiO3 multiferroic composites. J. Magn. Magn. Mater., 2007, 310(2):361–363.

[7] Zhou Y, Zhang J C, Li L, et al. Multiferroic composites in nano-microscale with non-solid solution by Co-ferrite and (K0.5Na0.5)NbO3-based ferroelectric matrix. J. Alloys Compd., 2009, 484(1): 535–539.

[8] Jiang M H, Liu X Y, Chen G H. Phase structures and electrical properties of new lead-free Na0.5K0.5NbO3-LiSbO3-BiFeO3 ceramics. Scrip. Mater., 2009, 60(10): 909–912.

[9] Bhame S D, Joy P A. Enhanced magnetostrictive properties of CoFe2O4?synthesized by an autocombustion method. Sens. Actuators, 2007, 137(2): 256–261.

[10] Manoj Kumar, Yadav K L. Synthesis of nanocrystalline xCuFe2O4-(1–x)BiFeO3 magnetoelectric composite by chemical method. Mater. Lett., 2007, 61(8): 2089–2092.

[11] Lu J, Pan D A, Yang B, et al. Wideband magnetoelectric measurement system with the application of a virtual multi-channel lock-in amplifier. Mater. Sci. Tech., 2008, 19(4):1–4.

[12] Kanamadi C M , Kulkarni S R, Patankar K K, et al. Magnetoelectric and dielectric properties of Ni0.5Cu0.5Fe2O4-Ba0.5Pb0.5Ti0.5Zr0.5O3 ME composites. J. Mater. Sci., 2007, 42(13): 5080–5084.

[13] Yan X, Ren W, Wu X Q, et al. Lead-free (K, Na)NbO3 ferroelectric thin films: preparation, structure and electrical properties. J. Alloys Compd., 2010, 508(1):129–132.

[14] XIANG Yong, XIE Dao-Hua. The Development of spinel structure functional materials. J Magn. Mater. Devices, 2001, 32(3): 21–25.

[15] Diao Chun-Li, Lou Guang-Hui. The research status and prospect of ferrite magnetic materials. ShanDong Ceramics, 2006, 29(1): 18–21.

[16] HU Jun, YAN Mi, BAO Da-Xin, et al. High permeability NiZn ferrites sintered at a low temperature of 930℃. Journal of Functional Materials, 2005, 6(36): 853–855.

[17] YU Zhi-Song, TIAN Zhi-Dong, XIONG Rui. Size-controlling preparation of CoFe2O4 nano-particles and its magnetic properties. J. Wuhan Univ., 2009, 55(2): 177–181.

[18] Ren S Q, Weng L Q, Song S H, et al. BaTiO3/CoFe2O4 particulate composites with large high frequency magnetoelectric response. J. Mater. Sci., 2005, 40(16): 4375–4378.

[19] Duong G V, Groessinger R, Turtelli R S. Magnetoelectricproperties of CoFe2O4-BaTiO3 core-shellstructure composite. J. Magn. Magn. Mater., 2006, 42(10): 3611–3613.

[20] 近角聪信, 著. 葛世慧, 译. 铁磁性物理. 兰州: 兰州大学出版社, 2002: 297–317.

[21] Chen W, Shannigrahi S, Chen X F, et al. Multiferroic behavior and magnetoelectric effect in CoFe2O4/Pb(Zr0.53Ti0.47)O3 thick films. Solid. State. Commun., 2010, 150(5): 271–274.

[22] Patil D R, Lokare S A, Devan R S, et al. Dielectric properties and magnetoelectric effect of (x)NiFe2O4+(1-x)Ba0.8Sr0.2TiO3 composites. J. Phys. Chem Solids, 2007, 68(8): 1522–1526.

[23] Srinivasan G, Devreugd C P, Flattery C S. Magnetoelectric interactions in hot-pressed nickel zinc ferrite and lead zirconante titanate composites. Appl. Phys. Lett., 2004, 85(13): 2550–2552.

[24] Shi Z, Nan C W, Zhang J, et al. Magnetoelectric properties of multiferroic composites with pseudo-1-3-type structure. J. Appl. Phys., 2006, 99(12): 1241081–1241085.

[25] YANG Chang-Hai, WEN Yu-Mei, LI Ping, et al. Influence of bias magnetic field on magnetoelectric effect of magneto strictive/ elastic/piezoelectric laminated composite. Acta Physica Sinica, 2008, 57(11): 7292–7296.

Fabrication and Properties of the Potassium Sodium Niobate/Cobalt Copper Ferritemultiferroic Magnetoelectric Composites

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 5

Recommended Articles

Metrics

Comments

[1]	WANG Jing, WU Xia, DENG Chao-Yong, ZHU Kong-Jun, NAN Ce-Wen. Research Progress of Film/Bulk Oxide Magnetoelectric Composites [J]. Journal of Inorganic Materials, 2014, 29(9): 905-911.
[2]	ZHANG Hui, MA Yong-Jun, WANG Yi-Cheng, WEN Dan-Dan, YE Fei, BAI Fei-Ming. Preparation of 1-3 Dimensional PZT-NFO Nanocomposite Films by Off-axis Magnetron Sputtering [J]. Journal of Inorganic Materials, 2014, 29(4): 371-376.
[3]	LI Ting-Xian, ZHANG Ming, HU Zhou, LI Kuo-She, YU Dun-Bo, YAN Hui. Preparation and Strong Magnetoelectric Effect of Multiferroic BaTiO₃/La_2/3Sr_1/3MnO₃ Composite Film [J]. Journal of Inorganic Materials, 2012, 27(3): 291-295.
[4]	GAI Zhen-Tao, YU Li-Ming, ZHOU Yun, ZHAO Xin-Luo, ZHANG Jin-Cang. Magnetic Dielectric and Magnetoelectric Properties of Magnetoelectric Nano-composites xCoAl_0.2Fe_1.8O₄+(1-x)BaTiO₃ [J]. Journal of Inorganic Materials, 2010, 25(11): 1155-1158.
[5]	GAO Jian-Sen，ZHANG Ning. Magnetoelectric Effect in Laminate Composites Tb_1-xDy_xFe_2-y-BaTi_0.99Cr_0.01O_3-δ [J]. Journal of Inorganic Materials, 2009, 24(2): 367-370.