Non-linear Optical Property and Sol-gel Preparation of CuCl-doped Sodium Borosilicate Glasses

Abstract

Abstract: The transparent stiff sodium borosilicate gels containing CuCl were synthesized by using tetraethyl
orthosilicate/ethanol, boric acid/ethanol, sodium ethoxide/ethanol, CuCl/HCl as precursors. The CuCl-doped glasses were prepared by
densification of the stiff gels at 500～600℃. The effects of the concentration of CuCl and the chlorhydric acid on the sol, gel
and glass were investigated, and the preparation mechanism of CuCl-doped sodium borosilicate glasses were discussed also. The photoluminescence
properties of the glasses were studied. The third order nonlinear refractive index of such glasses were characterized by Z-scan method at
1.33μm, and n₂ measured was 3.3×10^-20_m2/W.

Key words: CuCl, sol-gel, Na₂O-B₂O₃-SiO₂ glass, third order nonlinear refractive index

CLC Number:

TQ171

XIANG-Wei-Dong. Non-linear Optical Property and Sol-gel Preparation of CuCl-doped Sodium Borosilicate Glasses[J]. Journal of Inorganic Materials.

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Non-linear Optical Property and Sol-gel Preparation of CuCl-doped Sodium Borosilicate Glasses

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