2.00 μm Emission Properties of Tm3+/Ho3+ Co-doped Chalcohalide Glasses

doi:10.3724/SP.J.1077.2012.11483

Journal of Inorganic Materials ›› 2012, Vol. 27 ›› Issue (7): 711-715.DOI: 10.3724/SP.J.1077.2012.11483

• Research Paper • Previous Articles Next Articles

2.00 μm Emission Properties of Tm³⁺/Ho³⁺ Co-doped Chalcohalide Glasses

WEI Shu-Lin^1,2, XU Yin-Sheng^1,3, ZHANG Pei-Qing^1,2, CHEN Fei-Fei^1,2, NIE Qiu-Hua^1,2, XU Tie-Feng^1,2, DAI Shi-Xun^1,2

(1. Laboratory of Infrared Material and Devices, Ningbo University, Ningbo 315211, China; 2. College of Information Science and Engineering, Ningbo University, Ningbo 315211,China; 3. The Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China)

Received:2011-08-08 Revised:2011-10-24 Published:2012-07-20 Online:2012-06-06
About author:WEI Shu-Lin. E-mail: yyyfffyyy@163.com
Supported by:
International Science & Technology Cooperation Program of China (2011DFA12040); National Program on Key Basic Research Project (973 Program) (2012CB722703); National Natural Science Foundation of China; New Century Excellent Talents Project from Ministry of Education; Zhejiang Outstanding youth project; Ningbo Emerging Photoelectric Functional Materials And Devices Innovation Team Project; K.C. Wong Magna Fund in Ningbo University

Abstract

Abstract: 2 μm laser has many potential applications on the medical surgery, laser radar, and pollution monitoring etc. Tm³⁺ and Ho³⁺ ions co-doped 70GeS₂-20In₂S₃-10CsI chalcohalide glasses were synthesized by vacuumed melting- quenching technique. The DSC curves and Raman spectra showed that these glasses had good thermal stability and low phonon energy, respectively. The absorption and emission characteristics were evaluated with an emphasis on the 2.00 μm fluorescence from Ho³⁺: ⁵I₇→⁵I₈ transition. Under 808 nm excitation, the infrared emission bands extending from 1.80 μm to 2.10 μm can be seen on the emission spectra of the Tm³⁺ and Ho³⁺ ions co-doped glasses. This broad emission was consisted of two emission bands centered at 1.86 and 2.00 μm, corresponding to the optical transitions Tm³⁺:³F₄→³F₅ and Ho³⁺:⁵I₇→⁵I₈, respectively. At fixed Tm³⁺ ions concentration, the intensity of 2.00 μm emission increased with Ho³⁺ ions concentration increasing from 0.05mol% to 0.125mol%. The enhanced emission of Ho³⁺ ions gives another route to obtain the 2.00 μm infrared laser.

Key words: Tm³⁺/Ho³⁺ co-doped, chalcogenide glass, energy transfer

CLC Number:

TQ171

WEI Shu-Lin, XU Yin-Sheng, ZHANG Pei-Qing, CHEN Fei-Fei, NIE Qiu-Hua, XU Tie-Feng, DAI Shi-Xun. 2.00 μm Emission Properties of Tm³⁺/Ho³⁺ Co-doped Chalcohalide Glasses[J]. Journal of Inorganic Materials, 2012, 27(7): 711-715.

References

[1] Orlovskii Y V, Basiev T T, Pukhov K K, et al. Low-phonon BaF2: Ho3+, Tm3+ doped crystals for 3.5–4 μm lasing. Opt. Mater. 2010, 32(5): 599-611.

[2] Lee T H, Heo J. 1.6 μm emission and gain properties of Ho3+ in selenide and chalcohalide glasses. J. Appl. Phys., 2005, 98(11): 113510-1-7.

[3] Chen S, Yeo T, Leighton J, et al. Tm:Ho co-doped single mode optical fibre laser pumped by a 1600 nm Er fibre laser. Opt. Commun., 2008, 281(9): 2567-2571.

[4] Brierley M, France P, Millar C. Lasing at 2.08 μm and 1.38 μm in a holmium doped fluoro-zirconate fibre laser. Electron. Lett., 1988, 24(9): 539-540.

[5] Tian Y, Zhang L, Feng S, et al. 2 μm Emission of Ho3+-doped fluorophosphate glass sensitized by Yb3+. Opt. Mater., 2010, 32(11): 1508-1513.

[6] Zhang W J, Zhang Q Y, Chen Q J, et al. Enhanced 2.0 -m emission and gain coefficient of transparent glass ceramic containing BaF2: Ho3+,Tm3+ nanocrystals. Opt. Express, 2009, 17(23): 20952-20958.

[7] Wang M, Yu C, He D, et al. Enhanced 2 μm emission of Yb–Ho doped fluorophosphates glass. J. Non-Cryst. Solids, 2011, 357(11/12/13): 2447-2449.

[8] Gao G, Hu L, Fan H, et al. Investigation of 2.0 μm emission in Tm3+ and Ho3+ co-doped TeO2-ZnO-Bi2O3 glasses. Opt. Mater., 2009, 32(2): 402-405.

[9] Schweizer T, Samson B N, Hector J R, et al. Infrared emission from holmium doped gallium lanthanum sulphide glass. Infrared Phys. Technol., 1999, 40(4): 329-335.

[10] Kim Y S, Cho W Y, Shin Y B, et al. Emission characteristics of Ge-Ga-S glasses doped with Tm3+/Ho3+. J. Non-Cryst. Solids, 1996, 203: 176-181.

[11] Tao H, Mao S, Tong W, et al. Formation and properties of the GeS2-In2S3-KCl new chalcohalide glassy system. Mater. Lett., 2006, 60(6): 741-745.

[12] Guignard M, Nazabal V, Moreac A, et al. Optical and structural properties of new chalcohalide glasses. J. Non-Cryst. Solids, 2008, 354(12/13): 1322-1326.

[13] Xu Y, Chen D, Zhang Q, et al. Bright red upconversion luminescence of thulium ion-doped GeS2-In2S3-CsI glasses. J. Phys. Chem. C, 2009, 113(22): 9911-9915.

[14] Abdel-Aziz M M. Effect of thallium on the crystallization kinetics of the chalcogenide glasses GeSe2 and GeSe4. J. Therm. Anal. Calorim., 2005, 79(3): 709-714.

[15] Tao H, Mao S, Dong G, et al. Raman scattering studies of the Ge-In sulfide glasses. Solid State Commun., 2006, 137(8): 408-412.

[16] Mao S, Tao H, Zhao X, et al. Microstructure and thermal properties of the GeS2-In2S3-CsI glassy system. J. Non-Cryst. Solids, 2008, 354(12/13): 1298-1302.

[17] Tao H, Zhao X, Tong W, et al. Micro-structural study of the GeS2-In2S3-KCl glassy system by Raman scattering. Spectrochim. Acta, Part A, 2006, 64(4): 1039-1045.

[18] Dong G, Tao H, Chu S, et al. Study on the structure dependent ultrafast third-order optical nonlinearity of GeS2-In2S3 chalcogenide glasses. Opt. Commun., 2007, 270(2): 373-378.

[19] Repkova M, Nemec P, Frumar M. Structure and thermal properties of Ge-In-S chalcogenide glasses. J. Optoelectronics Adv. Mater., 2006, 8(5): 1796-1800.

2.00 μm Emission Properties of Tm³⁺/Ho³⁺ Co-doped Chalcohalide Glasses

RichHTML

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles 0

Metrics

Comments

[1]	ZHOU Xiong, FANG Lizhi, HUANG Shuangwu, XIA Haiping, HU Jianxu, ZHANG Jianli, CHEN Baojiu. Ultraviolet and Near-infrared Luminescence of Ce ³⁺/Yb ³⁺ Co-doping LiLuF₄ Single Crystal [J]. Journal of Inorganic Materials, 2020, 35(5): 556-560.
[2]	LI Sheng-Song, ZHENG Yong-Chao, MENG Shu-Lin, WU Li-Zhu, ZHONG Jin- Yi, ZHAO Chong-Lin. Core/Shell Quantum Dots and Au Nanoparticles Assembly for Effective Detection of Nerve Agent Mimic [J]. Journal of Inorganic Materials, 2019, 34(8): 893-898.
[3]	CHEN Wei, ZHU Ning, ZHAO Zhe-Ming, ZHANG Pei-Qing, WANG Xun-Si, DAI Shi-Xun. Single-mode Chalcogenide Fiber: Fabrication and Supercontinuum Generation [J]. Journal of Inorganic Materials, 2018, 33(6): 678-682.
[4]	SHI Zhong-Xiang, WANG Jing, GUAN Xin. Multicolor Upconversion Emission Tuning of NaY(WO₄)₂: Dy³⁺ via Er³⁺ Doping [J]. Journal of Inorganic Materials, 2018, 33(5): 521-527.
[5]	GUO Wei, ZHANG Bin, ZHAI Cheng-Cheng, QI Si-Sheng, YU Yi, YANG An-Ping, LI Lei, YANG Zhi-Yong, WANG Rong-Ping, TANG Ding-Yuan, TAO Guang-Ming, LUTHER-DAVIES Barry. Fabrication and Application of Small Core Chalcogenide Glass Fibers in Nonlinear Optics [J]. Journal of Inorganic Materials, 2016, 31(2): 180-184.
[6]	YANG Guang-Wu, YANG Rui-Xia, ZHANG Shou-Chao, ZHU Fei. Ce Doping Concentration on Luminescence Property of YVO₄:Ce³⁺ Crystals [J]. Journal of Inorganic Materials, 2016, 31(10): 1073-1080.
[7]	PENG Xia, LI Shu-Xing, LIU Xue-Jian, HUANG Yi-Hua, HUANG Zheng-Ren, LI Hui-Li. Syntheses and Photoluminescence Properties of Eu²⁺/Tb³⁺ Doped Sr₂Si₅N₈ Phosphors [J]. Journal of Inorganic Materials, 2015, 30(4): 397-400.
[8]	QIAO Bei-Jing, CHEN Fei-Fei, NIE Qiu-Hua, DAI Shi-Xun, HUANG Yi-Cong. Structure and Third-order Optical Nonlinearity Performance of Ge-Sn-Se Doped TiO₂Glass-ceramics at 1550 nm [J]. Journal of Inorganic Materials, 2015, 30(11): 1189-1194.
[9]	XU Yan-Tao, GUO Hai-Tao, YAN Xing-Tao, LU Min, LIN Ao-Xiang, LI Fu, YANG Jian-Feng, ZHAN Huan. Preparation and Applications of Low-loss As-S Chalcogenide Glass Fibers [J]. Journal of Inorganic Materials, 2015, 30(1): 97-101.
[10]	XU Yin-Sheng, CHENG Jun-Wen, QI Jia-Ni, LU Shan-Shan, LU Ke-Lun, XU Jian-Wei, SHAO Qi-Fen, DAI Shi-Xun. Nonlinear Optical Properties of Silver Composited Ge-In-S-CsI Chalcogenide Glasses [J]. Journal of Inorganic Materials, 2014, 29(7): 735-740.
[11]	YIN Dong-Mei, TU De-Yang, CHE Bing-Chen, ZHANG Fang-Fang, LIN Chang-Gui, DAI Shi-Xun. Effect of Sn Addition on the Structure and Optical Properties of Ge-Se-Te Chalcogenide Glasses [J]. Journal of Inorganic Materials, 2014, 29(3): 279-283.
[12]	WEI Wen-Hou, FANG Liang, YANG Zhi-Yong, SHEN Xiang. Effect of Sb on Structure and Physical Properties of GeSb_xSe_7-_x Chalcogenide Glasses [J]. Journal of Inorganic Materials, 2014, 29(11): 1218-1222.
[13]	LUO Jia-Liang, WU Yun-Tao, REN Guo-Hao. Luminescence Property and Energy Transfer of Ce³⁺, Eu³⁺ Co-doped Lu₃Al₅O₁₂Polycrystals [J]. Journal of Inorganic Materials, 2014, 29(11): 1211-1217.
[14]	ZHANG Shou-Chao, RUAN Yong-Feng, JIA Guo-Zhi, FENG Zhi-Hui, LIU Zhi-Peng, PEI Li-Bin. Blue-emitting Properties of Ce³⁺Doped YVO₄ under Ultraviolet Excitation [J]. Journal of Inorganic Materials, 2014, 29(10): 1067-1072.
[15]	WANG Sen, ZHOU Ya-Xun, DAI Shi-Xun, WANG Xun-Si, SHEN Xiang, CHEN Fei-Fei. Influence of High Phonon Energy Oxide on Spectroscopic Properties of Er³⁺/Ce³⁺ Co-doped Tellurite Glasses [J]. Journal of Inorganic Materials, 2012, 27(8): 865-870.