Journal of Inorganic Materials ›› 2020, Vol. 35 ›› Issue (11): 1247-1254.DOI: 10.15541/jim20190629

Special Issue: 环境材料论文精选(2020)

• RESEARCH PAPER • Previous Articles     Next Articles

Preparation and Visible Light Photocatalytic Performance of BiOBr/Ti3C2 Composite Photocatalyst with Highly Exposed (001) Facets

LI Zhifeng1, TAN Jie1, YANG Xiaofei1, LIN Zuhong1, HUAN Zhenglai1, ZHANG Tingting1, 2   

  1. 1. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
    2. Beijing Centre for Resource and Environmental Research, Beijing 100029, China
  • Received:2019-12-11 Revised:2020-02-10 Published:2020-11-20 Online:2020-04-05
  • About author:LI Zhifeng(1996-), male, Master candidate. E-mail: lzf260cas@163.com

Abstract: BiOBr/Ti3C2 composite photocatalyst with highly exposed (001) facets was synthesized by hydrolysis method. Different instruments were employed to characterize the samples. The visible light photocatalytic performance of different samples were evaluated by using Rhodamine B as the target pollutant. The results show that the degradation efficiency of Rhodamine B reaches 97.1% within 60 min over BiOBr/Ti3C2 (20.0wt% Ti3C2 addidion) composite photocatalyst, which is 34.7% higher than that of BiOBr. With the introduction of layered Ti3C2, the interface between BiOBr and Ti3C2 forms the Schottky junction energy barrier, which produces effective electron traps to inhibit the combination of photogenic electron-hole pairs, and greatly improves the visible light photocatalytic activity of BiOBr. After 5 cycles, the degradation efficiency of BiOBr/Ti3C2 composite photocatalyst remains 91.0%, showing reliable stability. The active species capture experiment shows that superoxide radical (•O2-) is the main active species in the photocatalytic degradation of Rhodamine B, and a possible photocatalytic mechanism is proposed accordingly.

Key words: BiOBr, Ti3C2, visible light photocatalysis, Schottky junction

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