无机材料学报

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CVD宏观量半连续制备纳米碳管的研究

孙沿林; 张孝彬; 宁月生; 孔凡志; 刘芙   

  1. 浙江大学材料化工学院电镜实验室、硅材料国家重点实验室, 杭州 310027
  • 收稿日期:2001-02-26 修回日期:2001-04-10 出版日期:2002-03-20 网络出版日期:2002-03-20

CVD Method to Synthesize Carbon Nanotubes on a Large Scale

SUN Yan-Lin; ZHANG Xiao-Bin; NING Yue-Sheng; KONG Fan-Zhi; LIU Fu   

  1. Electron Microscope Laboratory of Academy of Material and Chemical Engineering; National Key Lab of Silicon; Zhejiang University; Hangzhou 310027; China
  • Received:2001-02-26 Revised:2001-04-10 Published:2002-03-20 Online:2002-03-20

摘要: 研究了以乙炔为基本原料,用N做载流气体;以纳米钻颗粒为催化剂在700~800℃常压下纳米碳管的宏观量制备.粗产品中纳米碳管的含量接近50%,而且纳米碳管缺陷很少,直而长,石墨化好.纳米碳管的形核过程是因为碳在催化剂表面分布不均匀造成的.纳米碳管的生长极限在15min左右,然后生长变得缓慢,纳米碳管的一般长度在5~30μm.

关键词: 纳米碳管, 化学气相沉积, 常压, 溶胶-凝胶

Abstract: Acetylene cracked under normal pressure at 700-800℃ with active nanoscale cobalt particles as catalyst and carbon nanotubes were prepared on a large scale. The final product rate was above 50wt% after 10min growth, and also defects were almost nonexistent. The lengthes of the carbon nanotubes ranged from 5 to 30μm. Non-well distributed carbon on catalyst surface accelerated the nucleating process. The growing time limitation was about 15min and then growing process became slow.

Key words: carbon nanotubes, CVD, normal pressure, sol-gel

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