甘氨酸辅助合成BiOI及其模拟太阳光光催化性能研究

doi:10.15541/jim20160244

无机材料学报 ›› 2017, Vol. 32 ›› Issue (2): 148-154.DOI: 10.15541/jim20160244 CSTR: 32189.14.10.15541/jim20160244

甘氨酸辅助合成BiOI及其模拟太阳光光催化性能研究

张磊, 马国强, 朱遂一, 杨霞, 耿直, 霍明昕

(东北师范大学环境学院, 长春130117)

收稿日期:2016-04-12 修回日期:2016-06-15 出版日期:2017-02-20 网络出版日期:2017-01-13
作者简介:张磊(1984–), 男, 硕士研究生. E-mail: zhanglei.1616@163.com
基金资助:
国家自然科学基金(51478095.51238001.51508078.51578118);教育部新世纪优秀人才支持计划(NCET-13-0723);吉林省科技发展计划项目(20160520023JH);吉林省教育厅“十二五”科学技术研究项目(2014B043)

Glycine Assisted Synthesis of BiOI and Enhanced Simulated Sunlight Activity

ZHANG Lei, MA Guo-Qiang, ZHU Sui-Yi, YANG Xia, GENG Zhi, HUO Ming-Xin

(Northeast Normal University, School of Environment, Changchun 130117, China)

Received:2016-04-12 Revised:2016-06-15 Published:2017-02-20 Online:2017-01-13
About author:ZHANG Lei. E-mail: zhanglei.1616@163.com
Supported by:
National Natural Science Foundation of China (51478095 51238001.51508078.51578118);Program for New Century Excellent Talents in University of the Ministry of Education of China (NCET-13-0723);Jilin Provincial Science and Technology Development Project of China (20160520023JH);Jilin Province Education Department Science and Technology Research Project of China (2014B043)

摘要/Abstract

摘要：

以甘氨酸分子作为模板, 硝酸铋作为铋源, 采用水热合成的方法一步制备了尺寸均一的具有片层花状微球形貌的四方晶相BiOI光催化材料。通过X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、紫外-可见漫反射光谱(UV-Vis/DRS)、N₂吸附-脱附等手段考察了五水硝酸铋与甘氨酸的摩尔比、水热反应时间对BiOI材料形貌、晶相结构及光学吸收等物理化学性质的影响。进一步以罗丹明B和水杨酸为目标污染物对其模拟太阳光光催化性能进行了评价。实验结果显示, 当五水硝酸铋与甘氨酸的摩尔比为1: 2, 水热时间为12 h所合成的BiOI光催化降解活性最高。经40 min模拟太阳光照射后, 罗丹明B和水杨酸的反应速率常数分别达到0.0232和0.0223 min^-1, 与未添加甘氨酸同等条件下合成的BiOI的反应速率常数(0.0111和0.0143 min^-1)相比, 有显著提升。光催化活性提高的主要原因是甘氨酸辅助合成的BiOI材料具有更为规则的形貌和更大的比表面积。

关键词: 甘氨酸, BiOI, 模拟太阳光, 罗丹明B, 水杨酸

Abstract:

Tetragonal BiOI with uniform size petal composed microspheres morphology was synthesized by one-step hydrothermal method using glycine molecules as templates and Bismuth nitrate as the source of Bi³⁺. The physicochemical properties of the fabricated BiOI was characterized by X-ray powder diffraction (XRD), scanning electron microscope (SEM), UV-Vis diffuse reflection spectroscope (UV-Vis/DRS), N₂ adsorption-desorption isothermal. The molar ratios of Bi(NO₃)₃·5H₂O and glycine (Bi: G), and hydrothermal time played important roles in the preparation process, which affected the morphology, structure, and light absorption properties of BiOI. Rhodamine-B and salicylic acid were used as the goal pollutants to evaluate the simulated sunlight catalytic properties of BiOI prepared with or without glycine. The BiOI prepared with Bi: G=1: 2 and hydrothermal time of 12 h exhibited the excellent degradation activity. After 40 min irradiation, Rhodamine-B and salicylic acid degradation rate constant by the glycine assisted synthesis of BiOI reached 0.0232 and 0.0223 min^-1, respectively. However, the photocataytic degradation rate constant of BiOI prepared without glycine was only 0.0111 and 0.0143 min^-1. Compared with BiOI prepared without glycine, the degradation activity improved sharply. The enhanced photocatalytic activity was mainly ascribed to regular morphology and big BET surface area of the BiOI prepared with the addition of glycine.

Key words: Glycine, BiOI, simulated sunlight, Rhodamine-B, salicylic acid

中图分类号:

O643

张磊, 马国强, 朱遂一, 杨霞, 耿直, 霍明昕. 甘氨酸辅助合成BiOI及其模拟太阳光光催化性能研究[J]. 无机材料学报, 2017, 32(2): 148-154.

ZHANG Lei, MA Guo-Qiang, ZHU Sui-Yi, YANG Xia, GENG Zhi, HUO Ming-Xin. Glycine Assisted Synthesis of BiOI and Enhanced Simulated Sunlight Activity[J]. Journal of Inorganic Materials, 2017, 32(2): 148-154.

图/表 8

图1 不同五水硝酸铋与甘氨酸摩尔比合成的BiOI催化剂的SEM照片

Fig. 1 SEM images of the BiOI sample with different molar ratios of Bi(NO3)3·5H2O to glycine(a, b) 1: 0; (c, d) 1: 0.5; (e, f) 1: 2; (g, h) 1: 4

图2 不同水热合成时间的BiOI催化剂的SEM照片

Fig. 2 SEM images of the BiOI samples prepared with different synthesis time(a, b) 0 h; (c, d) 4 h; (e, f) 8 h; (g, h) 12 h

图3 不同条件下制备的BiOI样品的XRD图谱

Fig. 3 XRD patterns of BiOI prepared under different conditions(a) Different Bi: G; (b) Different synthesis time

图4 不同条件下所制备的BiOI的UV-Vis/DRS图谱

Fig. 4 UV-Vis/DRS patterns of BiOI prepared under different conditions(a) different Bi: G, and (b) different synthesis time, inset is the plots of (αhν)1/2 versus hν

表1 催化剂表面性质

Table 1 Textural parameters of as-prepared samples

Sample	S_BET^a/(m²·g^-1)	PV^b /(cm³·g^-1)	D_p^c/nm
Bi: G=1: 0	52.88	0.065	27.3
Bi: G=1: 2	58.95	0.075	28.1

图5 不同比例甘氨酸投加量下所制备的BiOI光催化降解(a)RhB和(b)SA准一级动力学曲线

Fig. 5 Pseudo-first-order kinetics curves of BiOI obtained with different glycine additions in the degradation of (a) RhB and (b) SA

图6 不同时间水热合成的BiOI光催化降解(a)RhB和(b)SA准一级动力学曲线

Fig. 6 Pseudo-first-order kinetics curves of BiOI obtained with different synthesis time in the degradation of (a) RhB and (b) SA

图7 BiOI光催化剂降解SA循环实验

Fig. 7 Reuse of BiOI for degradation of SA

参考文献 24

[1]	SERGIO C, LAURA G, ADRIANA L,et al. Wet oxidation of salicylic acid solutions.Environ. Sci. Technol., 2010, 44(22): 8629-8635.
[2]	TIAN M, ADAMAS B, WEN J,et al. Photoelectro chemical oxidation of salicylic acid and salicylaldehyde on titanium dioxide nanotube arrays. Electrochimi.. Acta, 2009, 54(14): 3799-3805.
[3]	LI X, KiKUGAWA N, YE J.Nitrogen-doped lamellar niobic acid with visible light-responsive photocatalytic activity.Adv. Mater., 2008, 20(20): 3816-3819.
[4]	MEROIN D, PIFFERI V, SIRONI B, et al.Block copolymers for the synthesis of pure. Block copolymers for the synthesis of pure and Bi-promoted nano-TiO2 as active photocatalysts.J. Nanopart. Res., 2012, 14: 1086(8): 544.
[5]	WANG WEN-ZHONG, SHANG MENG, YIN WEN-ZONG,et al. Recent progress on the bismuth containing complex oxide photocatalysts.Journal of Inorganic Materials, 2012, 27(1): 11-18.
[6]	SANG HUAN-XIN, TIAN YE, WANG XI-TAO,et al. Photocatalytic H2 evolution from glycerol solution over Bi3+-doped TiO2 nanoparticles.Journal of Inorganic Materials, 2012, 27(12): 1283-1288.
[7]	TAO Y, CAO N, PAN J,et al. Controllable synthesis of TiO2 nanomaterials by assisting with lcysteine and ethylenediamine.J. Membr. Sci., 2014, 49(2): 897-904.
[8]	SHI S, WANG X H, GUO G,et al. Preparation and characterization of microporous poly(D, L-lactic acid) film for tissue engineering scaffold.Int. J. Nano, 2010, 5(1): 1049-1055.
[9]	CHEN X, LI H L, WANG S M,et al. Biomolecule-assisted hydrothermal synthesis of molybdenum disulfide microspheres with nanorods.Materials Letters, 2012, 66: 22-24.
[10]	YU S H, HE Z, ZHU J.Amino acids controlled growth of shuttle-like scrolled tellurium nanotubes and nanowires with sharp tips.Chem. Mater. , 2005, 17(11): 152-160.
[11]	ZUO F, YAN S, ZHANG B,et al. L-Cysteine assisted synthesis of PbS Nanocube- based pagoda-like hierarchical architectures.J.Phys.Chem.C, 2008, 112(8): 2831-2835.
[12]	WANG S G, SHEN C B, LONG K,et al. The electrochemical corrosion of bulk nanocrystalline ingotiron in acidic sulfate solution.J. Phys. Chem. B, 2006, 110(1): 377-382.
[13]	ZHAO Z Y, DAI W W.Structural, electronic, and optical properties of Eu-doped BiOX (X = F, Cl, Br, I): A DFT plus U study. Inorg. Chem., 2014, 53(24): 13001-13011.
[14]	ZHANG X, AI Z, FALONG J A,et al. Generalized one-pot synthesis, characterization, and photocatalytic activity of hierarchical BiOX (X = Cl, Br, I) nanoplate microspheres.J. Phys. Chem.C, 2008, 112(3): 747-753.
[15]	WANG J, YU Y, ZHANG L. Highly efficient photocatalytic removal of sodium pentachlorophenate with Bi3O4Br under visible light.Appl. Phys. B. Environ., 2013, 136-137(21): 112-121.
[16]	WANG W, HUANG F, LIN X,et al. Visible-light-responsive photocatalysts xBiOBr-(1-x) BiOI.Catal. Commun., 2008, 9(1): 8-12.
[17]	WANG T M, AN H Z, DU Y,et al. Photocatalytic properties of BiOX (X = Cl, Br, and I).Rare Metals, 2008, 27(3): 243-250.
[18]	ZHANG X, AI Z, JIA F A,et al. Generalized one-pot synthesis, characterization, and photocatalytic activity of hierarchical BiOX (X = Cl, Br, I) nanoplate microspheres.J. Phys. Chem.C, 2008, 112(3): 747-753.
[19]	WANG X F, DUAN F, CHEN M Q.Highly exposed surface area of {001} facets dominated BiOBr nanosheets with enhanced visible light photocatalytic activity.Appl. Chem. Ind. 2016, 14: 1671-1680.
[20]	TAO Y G, XU Y Q, PAN J, et al. Glycine assisted synthesis of flower-like TiO2 hierarchical spheres and its application in photocatalysis.Mater. Sci. Eng.B, 2012, 177(18): 1664-1671.
[21]	KIJIMA N, MATANO K, SAITO M,et al. Oxidative catalytic cracking of n-butane to lower alkenes over layered BiOCl catalyst.Appl. Catal., A, 2001, 206(2): 237-244.
[22]	DAI G, YU J, LIU G.Synthesis and enhanced visible-light photoelectrocatalytic activity of p-n junction BiOI/TiO2 nanotube arrays. J. Phys. Chem.C, 2011, 115(15): 7339-7346.
[23]	ZHANG W, ZHANG Q, DONG F.Visible-light photocatalytic removal of NO in air over BiOX (X = Cl, Br, I) single-crystal nanoplates prepared at room temperature.Ind. Eng. Chem. Res., 2013, 52(20): 6740-6746.
[24]	LONG B, HUANG Y C, LI H B.Carbon dots sensitized BiOI with dominant {001} facets for superior photocatalytic performance.Ind. Eng. Chem. Res., 2015, 54(51): 12788-12795.

甘氨酸辅助合成BiOI及其模拟太阳光光催化性能研究

Glycine Assisted Synthesis of BiOI and Enhanced Simulated Sunlight Activity

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