升温速率对二氧化钛纳米晶形貌的影响

doi:10.3724/SP.J.1077.2010.00906

无机材料学报 ›› 2010, Vol. 25 ›› Issue (9): 906-910.DOI: 10.3724/SP.J.1077.2010.00906 CSTR: 32189.14.SP.J.1077.2010.00906

升温速率对二氧化钛纳米晶形貌的影响

刘博¹, 孔伟¹, 叶波¹, 俞中平¹, 王华², 钱国栋¹, 王智宇¹

(1. 浙江大学材料科学与工程系, 硅材料国家重点实验室, 杭州 310027; 2. 浙江大学分析测试中心, 杭州 310029)

收稿日期:2009-12-21 修回日期:2010-03-05 出版日期:2010-09-20 网络出版日期:2010-08-25
基金资助:
浙江省自然科学基金(Z4080021); 国家自然科学基金(50532030, 50625206)

Effect of Heating Rate on the Morphology of Nano Titanium Dioxide

LIU Bo¹, KONG Wei¹, YE Bo¹, YU Zhong-Ping¹, WANG Hua², QIAN Guo-Dong¹, WANG Zhi-Yu¹

(1. State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China; 2. Center of Analysis and Measurement Zhejiang University, Hangzhou 310029, China)

Received:2009-12-21 Revised:2010-03-05 Published:2010-09-20 Online:2010-08-25
Supported by:
Nature Science Foundation of Zhejiang Province(Z4080021); National Nature Science Foundation of China(50532030,50625206)

摘要/Abstract

摘要：

以钛酸四丁酯为钛源, 采用十二胺辅助油酸溶剂热技术, 在240℃/10min、90℃/10min、40℃/10min和20℃/10min四组不同升温速率下合成了球状、棒状和不规则点状多面体氧化钛纳米晶. 分别采用TEM、HRTEM、XRD对样品的形貌特点和物相结构进行表征. 结合TEM、HRTEM、XRD的表征结果, 分析了不同升温速率下二氧化钛纳米晶的形貌变化和微观生长机制. 结果表明, 通过严格控制升温速率, 能够合成球状、棒状和不规则点状多面体氧化钛纳米晶, 随着升温速率的下降, 纳米晶沿一维(001)方向生长速率呈现先升高后降低的趋势.

关键词: 氧化钛纳米晶, 形貌变化, 升温速率, 溶剂热

Abstract:

Different shapes of nano titanium dioxide including sphere, rod and irregular-shaped polyhedron were prepared by solvothermal process at heating rates of 240℃/10min, 90℃/10min, 40℃/10min and 20℃/10min using tetrabutyl titanate as Ti source, oleic acid as solvent, dodecylamine as auxiliary agent. TEM, HRTEM and XRD were adopted to characterize the phase composition morphology and phase structure of the final products. The micro-morphology and growth mechanisms of the titanium dioxide nanocrystals prepared at different heating rates were studied based on the TEM, HRTEM and XRD analyses．The results show that spherical, rod-like, and irregular polyhedral points of titanium dioxide nanocrystals could be synthesized by strictly controlling the heating rate. The growth rate of along the (001) direction of nanocrystal shows a first upward and then downward trend with the decline of the heating rate.

Key words: nano titanium dioxide, morphology change, heating rate, solvothermal synthesis

中图分类号:

O643

刘博, 孔伟, 叶波, 俞中平, 王华, 钱国栋, 王智宇. 升温速率对二氧化钛纳米晶形貌的影响[J]. 无机材料学报, 2010, 25(9): 906-910.

LIU Bo, KONG Wei, YE Bo, YU Zhong-Ping, WANG Hua, QIAN Guo-Dong, WANG Zhi-Yu. Effect of Heating Rate on the Morphology of Nano Titanium Dioxide[J]. Journal of Inorganic Materials, 2010, 25(9): 906-910.

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升温速率对二氧化钛纳米晶形貌的影响

Effect of Heating Rate on the Morphology of Nano Titanium Dioxide

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