介孔Au/ZrO2复合薄膜的制备及其三阶非线性光学性能

doi:10.3724/SP.J.1077.2011.11526

无机材料学报 ›› 2012, Vol. 27 ›› Issue (3): 327-331.DOI: 10.3724/SP.J.1077.2011.11526 CSTR: 32189.14.SP.J.1077.2011.11526

介孔Au/ZrO₂复合薄膜的制备及其三阶非线性光学性能

陆强¹, 崔方明², 魏晨阳³, 华子乐³, 董长青¹

(1. 华北电力大学, 北京102206; 2. 中国空间技术研究院, 北京100081; 3. 中国科学院上海硅酸盐研究所, 上海200050)

收稿日期:2011-08-23 修回日期:2011-11-15 出版日期:2012-03-20 网络出版日期:2012-02-16
作者简介:LU Qiang (1982-) male, PhD. E-mail: qianglu@mail.ustc.edu.cn
基金资助:
National Natural Science Foundation of China (51106052); Program for New Century Excellent Talents in University (NCET-10-0374); Fundamental Research Funds for the Central Universities (11QG25)

Synthesis and Third-order Optical Nonlinearity of Mesoporous Au/ZrO₂ Thin Films

LU Qiang¹, CUI Fang-Ming², WEI Chen-Yang³, HUA Zi-Le³, DONG Chang-Qing¹

(1. North China Electric Power University, Beijing 102206, China; 2. Chinese Academy of Space Technology, Beijing 100081, China; 3. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China)

Received:2011-08-23 Revised:2011-11-15 Published:2012-03-20 Online:2012-02-16
About author:LU Qiang (1982-) male, PhD. E-mail: qianglu@mail.ustc.edu.cn
Supported by:
National Natural Science Foundation of China (51106052); Program for New Century Excellent Talents in University (NCET-10-0374); Fundamental Research Funds for the Central Universities (11QG25)

摘要/Abstract

摘要： 以尿素为沉淀剂, 通过沉积-淀的方法, 制备了高分散的金纳米颗粒负载的介孔氧化锆薄膜; 以1064 nm激光为入射光束, 通过Z扫描实验测试了复合薄膜的非线性光学折射和吸收, 并计算了复合薄膜的非共振三阶非线性光学极化率(~10^-10 esu), 金纳米颗粒的高分散性和氧化锆薄膜衬底的高线性折射率使复合薄膜显示了增强的三阶非线性极化率.

关键词: 金纳米颗粒, 介孔, 氧化锆薄膜, 三阶非线性光学性能

Abstract: Highly dispersed gold nanoparticles incorporated mesoporous zirconia thin films were synthesized through an easy deposition-precipitation method using urea as precipitator. The resultant composite thin films presented an enhanced off-resonant third-order optical nonlinear susceptibility of 10^-10 esu measured by Z-scan technique at 1064 nm. The enhanced optical nonlinearity of the composite thin films was attributed to the high dispersion of the gold nanoparticles and the high linear refractive index of the zirconia matrix.

Key words: Au nanoparticles, mesoporous, ZrO₂ thin films, third-order optical nonlinearity

中图分类号:

TQ174

陆强, 崔方明, 魏晨阳, 华子乐, 董长青. 介孔Au/ZrO₂复合薄膜的制备及其三阶非线性光学性能[J]. 无机材料学报, 2012, 27(3): 327-331.

LU Qiang, CUI Fang-Ming, WEI Chen-Yang, HUA Zi-Le, DONG Chang-Qing. Synthesis and Third-order Optical Nonlinearity of Mesoporous Au/ZrO₂ Thin Films[J]. Journal of Inorganic Materials, 2012, 27(3): 327-331.

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介孔Au/ZrO₂复合薄膜的制备及其三阶非线性光学性能

Synthesis and Third-order Optical Nonlinearity of Mesoporous Au/ZrO₂ Thin Films

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