无机材料学报

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稀土Dy和Ce共掺杂La2Zr2O7新型热障涂层用陶瓷材料

周宏明1,2, 易丹青1, 钟华1
  

  1. 中南大学 1. 材料科学与工程学院, 2. 粉末冶金国家重点实验室, 长沙 410083
  • 收稿日期:2007-07-13 修回日期:2007-09-07 出版日期:2008-05-20 网络出版日期:2008-05-20

Dy and Ce Co-doped La2Zr2O7 Ceramic Powder used for Thermal Barrier Coating

ZHOU Hong-Ming 1,2, YI Dan-Qing 1, ZHONG Hua 1   

  1. 1. School of Materials Science Engineering, Central South University, Changsha 410083, China;
    2. State Key Laboratory for Powder Metallurgy, Changsha 410083, China
  • Received:2007-07-13 Revised:2007-09-07 Published:2008-05-20 Online:2008-05-20

摘要: 用化学沉淀法制备了稀土Dy和Ce共掺杂La2Zr2O7新型热障涂层用陶瓷粉末La 1.7 Dy 0.3(Zr 0.8 CeZr 0.2 )2 O 7 (LDCZ). 通过X射线衍射、扫描电镜、高温膨胀仪、DSC和激光热导仪对粉末相结构、不同煅烧温度下的相组成、微观结构、高温相稳定性、热膨胀系数和导热系数进行了分析. 结果表明, 稀土共掺杂的La 1.7 Dy 0.3 (Zr 0.8 CeZr 0.2 ) 2 O 7 保持了烧绿石结构, 1200℃时粉末为无定形的混合氧化物, 900℃时转化为复合不仅可提高锆酸镧的热膨胀系数, 使其高于8YSZ的热膨胀系数, 并可使其导热系数较La 2 Zr 2 O 7 降低25%以上, 达到1.28~1.07W/m·K.

关键词: La2Zr2O 7, 热物性能, 热障涂层, 稀土共掺杂, 化学沉淀法

Abstract: Dy and Ce co-doped lanthanum zirconate composite (La 1.7 Dy 0.3(Zr 0.8 CeZr 0.2 )2 O 7, LDCZ) ceramic powders were prepared by the chemical precipitation method. XRD, SEM, differential Scanning Calorimetry (DSC) and TG, were used to analyze the crystallogrphic phase, microstructure and the phase stability of LDCZ. High-temperature dilatometer, DSC and laser thermal diffusivity methods were used to analyze its thermal expansion coefficient (TEC), specific heat and thermal diffusivity. The results show that the compositions of all prepared ceramic powders are in the range of the synthesis of La 2 Zr 2 O 7 with pyrochlore structure, the ceramic powders are amorphous mixed oxide at 120℃, the amorphous mixed oxide is converted to composite oxide when temperature is increased to 900, and the composite oxide is converted to single La 2 Zr 2 O 7  with pyrochlore structure at 1200℃. The LDCZ powders keep the pyrochlore structure and there is no phase transformations for LDCZ at high temperatures (~1300℃). The thermophysical results indicate that the thermal expansion coefficient of the LDCZ ceramic is slightly higher than that of conventional Y2O3-8wt%ZrO2 (8YSZ) and the thermal conductivity of the ceramic is 1.28--1.07W/m·K, it is 25% lower than preparing thermal barrier coatings.

Key words: La2Zr2O 7, thermophysical properties, thermal barrier coating, rare-earth co-doped, chemical precipitation method

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