碳纳米管和二甲基亚砜对钙钛矿太阳电池中PEDOT:PSS空穴传输层的协同影响

doi:10.15541/jim20170380

Journal of Inorganic Materials ›› 2018, Vol. 33 ›› Issue (6): 641-647.doi: 10.15541/jim20170380

• Orginal Article • Previous Articles Next Articles

Cooperative Effect of Carbon Nanotubes and Dimethyl Sulfoxide on PEDOT:PSS Hole Transport Layer in Planar Perovskite Solar cells

Shun-Jian XU(), Zong-Hu XIAO, Xiao-Rui LUO, Wei ZHONG, Yong-Ping LOU, Hui OU

Xinyu Institute of New Energy, Xinyu University, Xinyu 338004, China

Received:2017-08-07 Revised:2017-11-24 Online:2018-06-20 Published:2018-05-24
Supported by:
National Natural Science Foundation of China (51462035);Training Programme Foundation for Young Scientist of Jiangxi, China (20133BCB23035);Natural Science Foundation of Jiangxi (20161BAB206106);Educational Commission of Jiangxi, China (KJLD13100);Educational Commission of Jiangxi, China (GJJ171060)

Abstract

Abstract:

Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) film is commonly used as hole transport layer in planar perovskite solar cells (PSCs). To further strengthen the charge transport within PEDOT:PSS film and boost the growth of the perovskite crystal on PEDOT:PSS film, carbon nanotubes (CNTs) and dimethyl sulfoxide (DMSO) were simultaneously used as additives to prepare the co-modified film of CNT-DMSO-PEDOT:PSS. Results demonstrate an advantageous cooperative effect of CNTs and DMSO on the co-modified film. The dispersed CNTs with a grid-like structure throughout PEDOT:PSS matrix plays dual roles: to promote the perovskite crystal growth on co-modified surface and to reduce the sheet resistance of the co-modified film, while DMSO improves the conductivity of the co-modified film and controls the loss of CNTs from the co-modified film. Due to the cooperative effect, co-modified film is significantly more capable to collect, transport charges and enhance the perovskite layer growth with larger grains on its surface than that with pristine PEDOT:PSS film or PEDOT:PSS films modified by a single additive of CNT or DMSO, CNT-PEDOT:PSS or DMSO-PEDOT:PSS. Meanwhile, the co-modified film maintains high transparency with a transmittance of 88.8% at 550 nm. As a result, the PSCs of co-modified film has a hig power conversion efficiency of 5.75% in contrast to the devices based on the CNT-PEDOT:PSS (3.01%), DMSO-PEDOT:PSS (2.03%) and pristine PEDOT:PSS (1.30%) films.

Key words: carbon nanotubes, dimethyl sulfoxide, PEDOT:PSS, hole transport layer, perovskite solar cells

CLC Number:

TM914

Shun-Jian XU, Zong-Hu XIAO, Xiao-Rui LUO, Wei ZHONG, Yong-Ping LOU, Hui OU. Cooperative Effect of Carbon Nanotubes and Dimethyl Sulfoxide on PEDOT:PSS Hole Transport Layer in Planar Perovskite Solar cells[J].Journal of Inorganic Materials, 2018, 33(6): 641-647.

Figures/Tables 9

Fig. 1

Fig. 2

Fig. 3

Fig. 4

Fig. 5

Fig. 6

Fig.7

Table 1

Fig. 8

References 28

[1]	WANG WEI-QI, ZHENG HUI-FENG, LU GUAN-HONG,et al. Recent progress on applications of nano metal oxides in perovskite solar cells. Journal of Inorganic Materials, 2016, 31(9): 897-907.
[2]	AITOLA KERTTU, SVEINBJORNSSON KAN, CORREA-BAENA JUAN-PABLO,et al. Carbon nanotube-based hybrid hole- transporting material and selective contact for high efficiency perovskite solar cells. Energy & Environmental Science, 2016, 9(2): 461-466.
[3]	YANG WOON SEOK, NOH JUN HONG, JEON NAM JOONG,et al. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange. Science, 2015, 348(6240): 1234-1237.
[4]	LEE MICHAEL M, TEUSCHER JOEL, MIYASAKA TSUTOMU,et al. Efficient hybrid solar cells based on meso-superstructured organometal halid eperovskites. Science, 2012, 338(6107): 643-647.
[5]	LIU XIAODONG, YU HAO, YAN LI,et al. Triple cathode buffer layers composed of PCBM, C60, and LiF for high-performance planar perovskite solar cells. ACS Applied Materials & Interfaces, 2015, 7(11): 6230-6237.
[6]	ZUO CHUANTIAN, DING LIMING.Modified PEDOT layer makes a 1.52 VVoc for perovskite/PCBM solar cells. Advanced Energy Materials, 2017, 7(2): 1601193.
[7]	HUANG DI, GOH TENGOOI, KONG JAEMIN,et al. Perovskite solar cells with a DMSO-treated PEDOT:PSS hole transport layer exhibit higher photovoltaic performance and enhanced durability. Nanoscale, 2017, 9(12): 4236-4243.
[8]	GIURI ANTONELLA, MASI SOFIA, COLELLA SILVIA,et al. Cooperative effect of GO and glucose on PEDOT:PSS for high VOC and hysteresis-free solution-processed perovskite solar cells. Advanced Functional Materials, 2016, 26(38): 6985-6994.
[9]	HUANG XU, WANG KAI, YI CHAO,et al. Efficient perovskite hybrid solar cells by highly electrical conductive PEDOT:PSS hole transport layer. Advanced Energy Materials, 2016, 6(3): 1501773.
[10]	SUN KUAN, LI PENGCHENG, XIA YIJIE,et al. Transparent conductive oxide-free perovskite solar cells with PEDOT:PSS as transparent electrode. ACS Applied Materials & Interfaces, 2015, 7(28): 15314-15320.
[11]	WU ZHONGWEI, BAI SAI, XIANG JIAN,et al. Efficient planar heterojunction perovskite solar cells employing graphene oxide as hole conductor. Nanoscale, 2014, 6(18): 10505-10510.
[12]	ANTIOHOS DENNIS, FOLKES GLENN, SHERELL PETER, et al. Compositional effects of PEDOT-PSS/single walled carbon nanotube films on supercapacitor device performance.Journal of Materials Chemistry, 2011, 21(40): 15987-15994.
[13]	SHIN NA-RI, CHOI SUL-HWA, KIM JIN-YEOL.Highly conductive PEDOT:PSS electrode films hybridized with gold- nanoparticle-doped-carbon nanotubes.Synthetic Metals, 2014, 192(12): 23-28.
[14]	ZHANG YONG, TAN LICHENG, FU QINGXIA,et al. Enhancing the grain size of organic halide perovskites by sulfonate-carbon nanotube incorporation in high performance perovskite solar cells. Chemical Communications, 2016, 52(33): 5674-5677.
[15]	MA XIAOPIN, WANG XIUYU, LI MINGXIU,et al. A highly conductive poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film with the solvent bath treatment by dimethyl sulfoxide as cathode for polymer tantalum capacitor. Chemical Physics Letters, 2016, 654: 86-91.
[16]	XIONG SHANXIN, ZHANG LIYING, LU XUEHONG.Conductivities enhancement of poly(3,4-ethylenedioxythiophene)/poly (styrene sulfonate) transparent electrodes with diol additives.Polymer Bulletin, 2013, 70(1): 237-247.
[17]	YOO DOHYUK, KIM JEONGHUN, KIM JUNG HYUN.Direct synthesis of highly conductive poly(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) (PEDOT:PSS)/graphene composites and their applications in energy harvesting systems.Nano Reseach, 2014, 7(5): 717-730.
[18]	JIANG QINGLIN, LIU CONGCONG, SONG HAIJUN,et al. Free-standing PEDOT:PSS film as electrode for the electrodeposition of bismuth telluride and its thermoelectric performance. International Journal of Electrochemical Science, 2014, 9(12): 7540-7551.
[19]	PARK JONGWOON, LEE ARI, YIM YOUNCHAN,et al. Electrical and thermal properties of PEDOT:PSS films doped with carbon nanotubes. Synthetic Metals, 2011, 161(5/6): 523-527.
[20]	RATTAN SUNITA, SINGHAL PRACHI, VERMA A L.Synthesis of PEDOT:PSS (poly(3,4-ethylenedioxythiophene)/poly(4- styrene sulfonate))/NGPs (nanographitic platelets) nanocomposites as chemiresistive sensors for detection of nitroaromatics.Polymer Engineering and Science, 2013, 53(10): 2045-2052.
[21]	WANG QI, DONG QINGFENG, LI TAL,et al. Thin insulating tunneling contacts for efficient and water-resistant perovskite solar cells. Advanced Materials, 2016, 28(31): 6734-6739.
[22]	YU YU, YANG SONGWANG, LEI LEI,et al. Nucleation mediated interfacial precipitation for architectural perovskite films with enhanced photovoltaic performance. Nanoscale, 2017, 9(7): 2569-2578.
[23]	HUANG XU, GUO HENG, YANG JIAN,et al. Moderately reduced graphene oxide/PEDOT:PSS as hole transport layer to fabriccate efficient perovskite hybrid solar cells. Organic Electronics, 2016, 39: 288-295.
[24]	LEE DA-YOUNG, NA SEOK-IN, KIM SEOK-SOON.Graphene oxide/PEDOT:PSS composite hole transport layer for efficient and stable planar heterojunction perovskite solar cells.Nanoscale, 2016, 8(3): 1513-1522.
[25]	LEE JIYONG, MENAMPARAMBATH MINI MOL, HWANG JAE-YEOL,et al. Hierarchically structured hole transport layers of spiro-OMeTAD and multiwalled carbon nanotubes for perovskite solar cells. ChemSusChem, 2015, 8(14): 2358-2362.
[26]	CHRISTIANS JEFFREY A, FUNG RAYMOND C M, KAMAT PRASHANT V. An inorganic hole conductor for organo-lead halide perovskite solar cells. improved hole conductivity with copper iodide.Journal of the American Chemical Society, 2014, 136(2): 758-764.
[27]	KUANG CHAOYANG, TANG GANG, JIU TONGGANG,et al. Highly efficient electron transport obtained by doping PCBM with graphdiyne in planar-heterojunction perovskite solar cells. Nano Letters, 2015, 15(4): 2756-2762.
[28]	ZHOU HUANPING, CHEN QI, LI GANG,et al. Interface engineering of highly efficient perovskite solar cells. Science, 2014, 345(6196): 542-564.

HTL	J_sc/(mA∙cm^-2)	V_oc/V	FF	PCE/%
Pristine PEDOT:PSS	6.67	0.60	0.32	1.30
DMSO-PEDOT:PSS	13.49	0.51	0.30	2.03
CNT-PEDOT:PSS	14.71	0.61	0.34	3.01
Co-modified film	15.63	0.77	0.48	5.75

Cooperative Effect of Carbon Nanotubes and Dimethyl Sulfoxide on PEDOT:PSS Hole Transport Layer in Planar Perovskite Solar cells

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 28

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Tian-Tian LIU, Qing-Hua WANG, Xi-Li LIU, Feng GAO, Qing-Xiang WANG. Synthesis and Pseudocapacitive Behavior of Nickel Molybdate/Mutiwalled Carbon Nanotubes Composite [J]. Journal of Inorganic Materials, 2018, 33(7): 735-740.
[2]	Min DENG, Qi JIANG, Yuan FANG, Huan LI, Jia-Xin QIU, Xiao-Ying LU. Carbon Nanotubes/Polyaniline Chemically Modified Electrode: Preparation and Ascorbic Acid Detection [J]. Journal of Inorganic Materials, 2018, 33(1): 53-59.
[3]	Xuan ZHENG, Chun-Li GONG, Hai LIU, Guang-Jin WANG, Fan CHENG, Gen-Wen ZHENG, Sheng WEN, Chuan-Xi XIONG. Preparation of Phosphomolybdic Acid Coated Carbon Nanotubes and Its Supercapacitive Properties [J]. Journal of Inorganic Materials, 2017, 32(2): 127-134.
[4]	Wei-Qi WANG, Hui-Feng ZHENG, Guan-Hong LU, Yang-Qiao LIU, Jing SUN, Lian GAO. Recent Progress on Applications of Nano Metal Oxides in Perovskite Solar Cells [J]. Journal of Inorganic Materials, 2016, 31(9): 897-907.
[5]	Chao YANG, Ying LI, Lu YAN, Yun-Zhen CAO. Influence of Catalyst Film Thickness Deposited by Atomic Layer Deposition on Growth of Aligned Carbon Nanotubes [J]. Journal of Inorganic Materials, 2016, 31(7): 681-686.
[6]	Run XU, Xin-Da LI, Zhi-Qiang LI, Ren-Yu ZHAO, Gen-Lian FAN, Ding-Bang XIONG, Jie TANG, Yong XU, Di ZHANG. Preparation and Reaction Kinetics of Carbon Nanotubes/Aluminum Composite Powders Using Polymer Pyrolysis Method [J]. Journal of Inorganic Materials, 2014, 29(7): 687-694.
[7]	Tian QIU, Jing-Jing HUANG, Miao ZHANG, Xian-Fu WANG, Chen LI, Xiao-Ying LU, Jie WENG. Effects of Adding Carbon Nanotubes/Hydroxyapatite Composites on the Properties and Structure of Calcium Phosphate Cement [J]. Journal of Inorganic Materials, 2013, 28(1): 91-96.
[8]	SONG Cheng-Wen, JIANG Da-Wei, LI Lin, SUN Mei-Yue, WANG Tong-Hua. Preparation and Gas Separation Properties of Carbon/Carbon Nanotubes Hybrid Membranes Derived from PMDA-ODA Polyimide [J]. Journal of Inorganic Materials, 2012, 27(9): 923-927.
[9]	GUO De-Chao, ZENG Xie-Rong, DENG Fei, ZOU Ji-Zhao, SHENG Hong-Chao. Preparation and Electrochemical Performance of Carbon nanotubes/Micro-expanded?Graphite Composite Anodes for Lithium-ion Batteries [J]. Journal of Inorganic Materials, 2012, 27(10): 1035-1041.
[10]	WANG Zhi-Min, TANG Xin-Cun, XIAO Yuan-Hua, YU Xiao-Jing, ZHANG Liang, JIA Dian-Zeng, CHEN Gu-Chun. Polypyrrole Coated Carbon Nanotubes: Preparation, Characterization, and Gas-sensing Properties [J]. Journal of Inorganic Materials, 2011, 26(9): 961-968.
[11]	WU Zhen-Yi, YANG Sheng-Yan. Synthesis, Characterization and Photoelectric Properties of the Copper Phthalocyanine-modied Multi-walled Carbon Nanotubes [J]. Journal of Inorganic Materials, 2011, 26(8): 785-791.
[12]	WANG Can, ZHAN Liang, HUANG Zhen-Hong, QIAO Wen-Ming, LIANG Xiao-Yi, YANG Jun-He, Ling Li-Cheng. Metal-catalyst-free Growth and Characterization of Nitrogen-doped Carbon Nanotubes [J]. Journal of Inorganic Materials, 2011, 26(8): 881-884.
[13]	SHAO Jin, REN Yu-Rong, LI Guo-Qiang, HUANG Xiao-Bing, ZHOU Gu-Min, QU Mei-zhen. Carbon Coated Helical Carbon Nanotubes used as Anode Materials of Li-ion Battery [J]. Journal of Inorganic Materials, 2011, 26(6): 631-637.
[14]	ZHU Zhi-PING, HUANG Ke-Long, ZHOUYi. Study on Kinetics, Thermodynamics and Mechanism for Carbon Nanotubes Adsorbing Humic Acid [J]. Journal of Inorganic Materials, 2011, 26(2): 170-174.
[15]	ZHAO Meng-Li, YUE Yu-Chen, YUAN Li,LI De-Jun, LÜ Xiao-Ying, HUANG Yan. Study of Fibroblast and Platelet Adhesion on Multi-wallCarbon Nanotubes [J]. Journal of Inorganic Materials, 2011, 26(1): 73-77.