Journal of Inorganic Materials ›› 2018, Vol. 33 ›› Issue (6): 641-647.DOI: 10.15541/jim20170380
• Orginal Article • Previous Articles Next Articles
XU Shun-Jian, XIAO Zong-Hu, LUO Xiao-Rui, ZHONG Wei, LOU Yong-Ping, OU Hui
Received:
2017-08-07
Revised:
2017-11-24
Online:
2018-06-20
Published:
2018-05-24
Supported by:
CLC Number:
XU Shun-Jian, XIAO Zong-Hu, LUO Xiao-Rui, ZHONG Wei, LOU Yong-Ping, OU Hui. Cooperative Effect of Carbon Nanotubes and Dimethyl Sulfoxide on PEDOT:PSS Hole Transport Layer in Planar Perovskite Solar cells[J]. Journal of Inorganic Materials, 2018, 33(6): 641-647.
Fig. 5 AFM images and grain size distributions of CH3NH3PbI3 perovskite layers deposited on different PEDOT:PSS films(a) DMSO-PEDOT:PSS; (b) CNT-PEDOT:PSS; (c) CNT- DMSO-PEDOT:PSS
Fig.7 Statistic PCE of PSCs employing the hole transport layers of (a) pristine PEDOT:PSS, (b) DMSO-PEDOT:PSS, (c) CNT-PEDOT:PSS and (d) CNT-DMSO-PEDOT:PSS
HTL | Jsc/(mA∙cm-2) | Voc/V | FF | PCE/% |
---|---|---|---|---|
Pristine PEDOT:PSS | 6.67 | 0.60 | 0.32 | 1.30 |
DMSO-PEDOT:PSS | 13.49 | 0.51 | 0.30 | 2.03 |
CNT-PEDOT:PSS | 14.71 | 0.61 | 0.34 | 3.01 |
Co-modified film | 15.63 | 0.77 | 0.48 | 5.75 |
Table 1 Best photovoltaic performances of PSCs employing various PEDOT:PSS films as hole transport layers
HTL | Jsc/(mA∙cm-2) | Voc/V | FF | PCE/% |
---|---|---|---|---|
Pristine PEDOT:PSS | 6.67 | 0.60 | 0.32 | 1.30 |
DMSO-PEDOT:PSS | 13.49 | 0.51 | 0.30 | 2.03 |
CNT-PEDOT:PSS | 14.71 | 0.61 | 0.34 | 3.01 |
Co-modified film | 15.63 | 0.77 | 0.48 | 5.75 |
[1] | WANG WEI-QI, ZHENG HUI-FENG, LU GUAN-HONG,et al. Recent progress on applications of nano metal oxides in perovskite solar cells. Journal of Inorganic Materials, 2016, 31(9): 897-907. |
[2] | AITOLA KERTTU, SVEINBJORNSSON KAN, CORREA-BAENA JUAN-PABLO,et al. Carbon nanotube-based hybrid hole- transporting material and selective contact for high efficiency perovskite solar cells. Energy & Environmental Science, 2016, 9(2): 461-466. |
[3] | YANG WOON SEOK, NOH JUN HONG, JEON NAM JOONG,et al. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange. Science, 2015, 348(6240): 1234-1237. |
[4] | LEE MICHAEL M, TEUSCHER JOEL, MIYASAKA TSUTOMU,et al. Efficient hybrid solar cells based on meso-superstructured organometal halid eperovskites. Science, 2012, 338(6107): 643-647. |
[5] | LIU XIAODONG, YU HAO, YAN LI,et al. Triple cathode buffer layers composed of PCBM, C60, and LiF for high-performance planar perovskite solar cells. ACS Applied Materials & Interfaces, 2015, 7(11): 6230-6237. |
[6] | ZUO CHUANTIAN, DING LIMING.Modified PEDOT layer makes a 1.52 VVoc for perovskite/PCBM solar cells. Advanced Energy Materials, 2017, 7(2): 1601193. |
[7] | HUANG DI, GOH TENGOOI, KONG JAEMIN,et al. Perovskite solar cells with a DMSO-treated PEDOT:PSS hole transport layer exhibit higher photovoltaic performance and enhanced durability. Nanoscale, 2017, 9(12): 4236-4243. |
[8] | GIURI ANTONELLA, MASI SOFIA, COLELLA SILVIA,et al. Cooperative effect of GO and glucose on PEDOT:PSS for high VOC and hysteresis-free solution-processed perovskite solar cells. Advanced Functional Materials, 2016, 26(38): 6985-6994. |
[9] | HUANG XU, WANG KAI, YI CHAO,et al. Efficient perovskite hybrid solar cells by highly electrical conductive PEDOT:PSS hole transport layer. Advanced Energy Materials, 2016, 6(3): 1501773. |
[10] | SUN KUAN, LI PENGCHENG, XIA YIJIE,et al. Transparent conductive oxide-free perovskite solar cells with PEDOT:PSS as transparent electrode. ACS Applied Materials & Interfaces, 2015, 7(28): 15314-15320. |
[11] | WU ZHONGWEI, BAI SAI, XIANG JIAN,et al. Efficient planar heterojunction perovskite solar cells employing graphene oxide as hole conductor. Nanoscale, 2014, 6(18): 10505-10510. |
[12] | ANTIOHOS DENNIS, FOLKES GLENN, SHERELL PETER, et al. Compositional effects of PEDOT-PSS/single walled carbon nanotube films on supercapacitor device performance.Journal of Materials Chemistry, 2011, 21(40): 15987-15994. |
[13] | SHIN NA-RI, CHOI SUL-HWA, KIM JIN-YEOL.Highly conductive PEDOT:PSS electrode films hybridized with gold- nanoparticle-doped-carbon nanotubes.Synthetic Metals, 2014, 192(12): 23-28. |
[14] | ZHANG YONG, TAN LICHENG, FU QINGXIA,et al. Enhancing the grain size of organic halide perovskites by sulfonate-carbon nanotube incorporation in high performance perovskite solar cells. Chemical Communications, 2016, 52(33): 5674-5677. |
[15] | MA XIAOPIN, WANG XIUYU, LI MINGXIU,et al. A highly conductive poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film with the solvent bath treatment by dimethyl sulfoxide as cathode for polymer tantalum capacitor. Chemical Physics Letters, 2016, 654: 86-91. |
[16] | XIONG SHANXIN, ZHANG LIYING, LU XUEHONG.Conductivities enhancement of poly(3,4-ethylenedioxythiophene)/poly (styrene sulfonate) transparent electrodes with diol additives.Polymer Bulletin, 2013, 70(1): 237-247. |
[17] | YOO DOHYUK, KIM JEONGHUN, KIM JUNG HYUN.Direct synthesis of highly conductive poly(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) (PEDOT:PSS)/graphene composites and their applications in energy harvesting systems.Nano Reseach, 2014, 7(5): 717-730. |
[18] | JIANG QINGLIN, LIU CONGCONG, SONG HAIJUN,et al. Free-standing PEDOT:PSS film as electrode for the electrodeposition of bismuth telluride and its thermoelectric performance. International Journal of Electrochemical Science, 2014, 9(12): 7540-7551. |
[19] | PARK JONGWOON, LEE ARI, YIM YOUNCHAN,et al. Electrical and thermal properties of PEDOT:PSS films doped with carbon nanotubes. Synthetic Metals, 2011, 161(5/6): 523-527. |
[20] | RATTAN SUNITA, SINGHAL PRACHI, VERMA A L.Synthesis of PEDOT:PSS (poly(3,4-ethylenedioxythiophene)/poly(4- styrene sulfonate))/NGPs (nanographitic platelets) nanocomposites as chemiresistive sensors for detection of nitroaromatics.Polymer Engineering and Science, 2013, 53(10): 2045-2052. |
[21] | WANG QI, DONG QINGFENG, LI TAL,et al. Thin insulating tunneling contacts for efficient and water-resistant perovskite solar cells. Advanced Materials, 2016, 28(31): 6734-6739. |
[22] | YU YU, YANG SONGWANG, LEI LEI,et al. Nucleation mediated interfacial precipitation for architectural perovskite films with enhanced photovoltaic performance. Nanoscale, 2017, 9(7): 2569-2578. |
[23] | HUANG XU, GUO HENG, YANG JIAN,et al. Moderately reduced graphene oxide/PEDOT:PSS as hole transport layer to fabriccate efficient perovskite hybrid solar cells. Organic Electronics, 2016, 39: 288-295. |
[24] | LEE DA-YOUNG, NA SEOK-IN, KIM SEOK-SOON.Graphene oxide/PEDOT:PSS composite hole transport layer for efficient and stable planar heterojunction perovskite solar cells.Nanoscale, 2016, 8(3): 1513-1522. |
[25] | LEE JIYONG, MENAMPARAMBATH MINI MOL, HWANG JAE-YEOL,et al. Hierarchically structured hole transport layers of spiro-OMeTAD and multiwalled carbon nanotubes for perovskite solar cells. ChemSusChem, 2015, 8(14): 2358-2362. |
[26] | CHRISTIANS JEFFREY A, FUNG RAYMOND C M, KAMAT PRASHANT V. An inorganic hole conductor for organo-lead halide perovskite solar cells. improved hole conductivity with copper iodide.Journal of the American Chemical Society, 2014, 136(2): 758-764. |
[27] | KUANG CHAOYANG, TANG GANG, JIU TONGGANG,et al. Highly efficient electron transport obtained by doping PCBM with graphdiyne in planar-heterojunction perovskite solar cells. Nano Letters, 2015, 15(4): 2756-2762. |
[28] | ZHOU HUANPING, CHEN QI, LI GANG,et al. Interface engineering of highly efficient perovskite solar cells. Science, 2014, 345(6196): 542-564. |
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