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Gene Activating Glasses
Bench L L,Xynos I D,Edgar A J,Buttery L D K,Polak J M,ZHONG Ji-Pin,LIU Xuan-Yong,CHANG Jiang
2002 Vol. 17 (5): 897909
Abstract(
2308 )
PDF(847KB)(
1134
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Thirty years ago it was discovered that bioactive glasses bond to bone. This unique material has been used clinically for more than 15 years with many thousands of successful cases. Recent research has shown that bioactive response appears to be under genetic control. Class A bioactive glasses that are osteoproductive enhance osteogenesis through a direct control over genes that regulate cell cycle induction and progression. Cells that are not capable of forming new bone are eliminated from the cell population, a characteristic that is missing when osteoblasts are exposed to bioinert or Class B bioactive materials. The biological consequence of genetic control of the cell cycle of osteoblast progenitor cells is the rapid proliferation and differentiation of osteoblasts. The result is rapid regeneration of bone. Understanding the genetic basis for bioactive glasses provides an important opportunity for glass research. It should now be feasible to design a new generation of gene-activating glasses tailored for specific patients and disease states. The new generation of gene activating glasses can also be fabricated into bioactive resorbable scaffolds for tissue engineering of bone constructs for patients with large bone defects. If we can activate genes by use of glasses it is certainly possible that we may one day be able to use glasses to control genes.
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Low-Temperature Firing in Microwave Dielectric Ceramics
WANG Ning,ZHAO Mei-Yu,YIN Zhi-Wen
2002 Vol. 17 (5): 915924
Abstract(
2168 )
PDF(528KB)(
1253
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This paper reviewed the recent progress on the studies of low-temperature firing in microwave dielectric ceramics.Oxides or low melting glass additions,chemical processing,and small particle sizes of the starting materials are three methods normally used to reduce the sintering temperature of dielectric ceramics. In addition, it is an effective method to develop new microwave dielectric materials with low-firing temperature.
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Flier-plate Material with Graded Wave Impedance and Application in Dynamic High-pressure Physics
WANG Chuan-Bin,ZHANG Lian-Meng
2002 Vol. 17 (5): 925930
Abstract(
1857 )
PDF(313KB)(
1156
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Flier-plate Material with Graded Wave Impedance is a new kind of Functionally Graded Material (FGM), which may be applied to dynamic high-pressure physics. By using such flier-plate material, quasi-isentropic compression to target material or projectile can be realized, and based on it hypervelocity launching of projectile is further accomplished. As a result, extremely high pressure equivalent to nuclear explosion can be obtained in the laboratory, which offers a practical and feasible method for the design of nuclear weapons and the researches on weapon physics.
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Influence of Si4+ Ion on Scintillation Properties and Radiation Hardness of Y3+ Doping PbWO4 Crystals
ZHANG Xin,LIAO Jing-Ying,XIE Jian-Jun,SHEN Bing-Fu,SHAO Pei-Fa,LI Chang-Quan,YUAN Hui,YIN Zhi-Wen
2002 Vol. 17 (5): 931937
Abstract(
2052 )
PDF(442KB)(
873
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Based on the fact that the exceptional irradiation behaviors are prominent at the top part of Y3+ doping PWO crystals while exposed to low dose rate γa-ray, previous studies concluded that this phenomenon was caused by enrichment of impurities such as Na+, K+ and Si4+ whose segregation coefficient are smaller than 1. In this paper, the relationships among annealing, optical transmission and radiation hardness of Si4+ ion contained Y3+: PWO crystals were investigated. The experimental results show that the Si4+ ions do not influence optical transmission and radiation hardness of Y3+: PWO crystals at the concentration involved in the study. It can be concluded that the exceptional irradiation behaviors of Y3+: PWO crystals do not relate to the contamination of Si4+ ion.
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Preparation and Characterization of Spherical, Solid Barium Titanate Ultrafine Powders with Uniform Composition by Spray Hydrolysis Reaction
XU Hua-Rui,GU Hong-Chen,GAO Lian,GUO Jing-Kun
2002 Vol. 17 (5): 938944
Abstract(
2034 )
PDF(1342KB)(
1236
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The spherical, solid BaTiO3 powders with 0.5~2μm and uniform composition were prepared by the spray hydrolysis reaction method. The main factors on the preparation of solid and uniform composition powders are reaction temperature and time, and the concentration of dimethyl oxalate (DMO), which is the inter-precipitator. The optimum conditions for the preparation of ideal powders are that the reaction temperature is more than 85℃, and the time is more than 3s, and the concentration of DMO is more than 0.75 mol/L.
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Preparation and Characterization of La3+-doped Barium Titanate Nanosize Polycrystalline Powders
WANG Zhi-Min,HAN Ji-Xin,LIU Jing-Bo
2002 Vol. 17 (5): 945952
Abstract(
1918 )
PDF(2083KB)(
901
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Nanosize polycrystalline powders of lanthanum doped barium titanate were prepared by the cosolubilized- hydrous gel process using titanium butoxide and lanthanum acetate as well as barium acetate with 0.7mol/L total concentration of precursor. The sol was obtained by cosolubilized hydrosis of starting materials using HOAc as medium and catalyst with pH=3.8. The wet-gel was acquired by concentrating and aging sol at room temperature. The wet-gel to dry-gel conversion was performed at 50℃/24h in an electrical oven. The TG-DTG measurement of dry-gel was carried out to determine the appropriate temperature range of calcination. Then a series of polycrystal powders were prepared by calcining dry-gel at different points of above temperature range. Powder samples were characterized detailedly to confirm the phase formation, crystalline size, grain morphology, elemental composition and the fine structure by FT-IR, XRD, SEM, EDS, TEM and LRS. So that opitimizing 800℃/2h as the suitable condition for calcination of dry-gel to prepare nanosize polycrystal powders LaxBa1-xTiO 3(x=0.00, 005, 0.10, 0.20, 0.30).
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Chemical Surface Coating of α-Fe Magnetic Particles with Silane Coupling Agent
WANG Qi-Xiang,SONG Bao-Zhen,LI Hong-Zhong
2002 Vol. 17 (5): 953958
Abstract(
2238 )
PDF(1130KB)(
1076
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The magnetic and chemical stability of α-Fe metal magnetic recording particles can be modified by chemical surface coating with silane coupling agents. The results of measurements by TEM, FT-IR, TG-DSC, Mossbauer, EXAFS and VSM etc show that a close, uniform, firm and ultrathin layer, which is benefit for the magnetic and chemical stability, can be formed by the cross-linked chemical bond Si--O--Si. And the organic molecule has chemically bonded to the particle surface oxide layer with Si--O--Fe, which has greatly affected the surface electronic structure and the second shell of Fe atom. However, the organic layer really does not affect the first shell of the matrix Fe atom.
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Substitution Structure, Phase Tranversion and Absorbing F- Action of the CHAP in Nanoscale
HUANG Zhi-liang,WANG Da-Wei,LIU Yu,ZHANG Yu,WEI Jun,HE Ya-Lin
2002 Vol. 17 (5): 959966
Abstract(
1859 )
PDF(1226KB)(
968
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The nano carbonate-containing hydroxyapatite(CHAP) with different CO32- contents (WCO32-) was prepared by a sol-gel process. DTA, TG, XRD, FTIR, TEM,dynamic absorption test and crystalline density measurement were used to study substitution structure, phase tranversion and absorbing F- action of the CHAP. Test results indicate that the CHAP is with AB mixed-type substitution structure. When WCO32-<3.34%, RI increases and capacities absorbing F- decrease with the increasing of CO32- contents, and the CHAP has preferentially a tendency of absorbing CO32- to enter its lattice in absorbing F- process, and a phase tranversion from the CHAP to Ca-deficient HAP takes place at 150~776℃, then the HAP occurs dehydroxy phase tranversion at 776℃. When WCO32-=3.34%, RI has maximum value, a phase tranversion from the CHAP to Ca-stoichiometric HAP takes place at 150~776℃, so the dehydroxy phase tranversion of HAP can not occur at 776℃. When 3.34%<WCO32-≤7.52%, RI decreases and capacities absorbing F- increase with the increasing of CO32- content, and the CHAP has preferentially a tendency of absorbing F- to enter its lattice and exchanging out CO32- in absorbing F- process, and a phase tranversion from the CHAP to Ca-surplus HAP takes place at 150~776℃, so the dehydroxy phase tranversion of HAP can not occur at 776℃. The nano CHAP crystals have a behavior of dissolving along crystal length, and 2~3 times capacities absorbing F- of the pure HAP, and show an effect of dissolving-precipitating adsorption in nanoscale.
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Preparation of Iron Oxide Nanoparticles in Non-aqueous Solution
DONG Rui,JIANG Ji-Sen,YANG Xie-Long
2002 Vol. 17 (5): 967972
Abstract(
2021 )
PDF(1052KB)(
1419
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Iron oxide nanoparticles were prepared in non-aqueous solution. The nanoparticles were characterized by FTIR, XRD, TEM, TG-DTA and Mossbauer techniques. Amphous ultrafine FeOOH particles can be obtained at room temperature. Different kinds of iron oxide nanoparticles can be systhesized by controlling the calcining temperature. When calcined at 300℃ for 1h, FeOOH transformed to Fe3-xO4, and the Fe3-xO4 particles size was about 30 nm. α-Fe2O3 can be obtained at the temperature of 450℃ for Ih and its primary particles size increased to98nm.
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Surface Chemistry Analysis of Si3N4 Powders and Selection of the Dosage of Coupling Agents
YAN Lu-Ting,SI Wen-Jie,MIAO He-Zhuo,QI Long-Hao
2002 Vol. 17 (5): 973978
Abstract(
1932 )
PDF(232KB)(
1012
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Oxidation and hydrolization are disadvantageous factors in producing and storing Si3N4 powders. But it provides a convenience in the aspect improving the compatibility between inorganic ceramic powders and organic medium. In this article, the surface characters of as-received and modified powders were compared and their effect on the selection of coupling agents was also discussed.
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Hydrothermal Synthesis of Bi2O3 Whiskers
YANG Qun-Bao,LI Yong-Xiang,YIN Qing-Rui,WANG Pei-Ling,CHENG Yi-Bing
2002 Vol. 17 (5): 979984
Abstract(
1925 )
PDF(2035KB)(
959
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The non-agglomerated Bi2O3 whiskers with a monoclinic structure were hydrother-mally prepared by using Bi(OH)3 and KOH. The hydrothermal reaction takes place in the ranges of 120~220℃ from 0.5 to 10h. The influences of the starting materials, reaction temperature and time on the morphologies of Bi2O3 whiskers were examined. The length and aspect ratio (length to diameter) of hydrothermally prepared Bi2O3 whiskers are in the ranges of 4~70μm and 5~16, respectively.
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Preparation and Physicochemical Process of Nanosized Hydroxyapatite Powders with High Purity
SONG Yun-Jing,WEN Shu-Lin,LI Mu-Sen,SU Qing-Cai,JIANG Qing-Hui
2002 Vol. 17 (5): 985991
Abstract(
2055 )
PDF(965KB)(
1250
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In this paper, nano-sized hydroxyapatite powders were prepared by a sol-gel method with Ca(NO3)2·4H2O and P2O5 ethanol solution as precursors. This process was simple without refluxing and the reactants were cheap compared with other sol-gel methods. The morphology and the phase structure were studied by TEM, XRD, IR, and TG-DTA. The nano-sized HA powders with high quality were prepared after the as-prepared powders were sintered at 500℃ for 2h. The results show that the mixture is composed of Ca (NO3)2, amorphous HA and ester phosphate at 200, 300 and 400℃. The amount of HA increases while the amount of Ca(NO3)2 and ester phosphate decreases with the increase of temperature. A small amount of β-Ca2P2O7 and CaO is present at 300 and 400℃. This process is simple and appropriate to produce nano-sized HA powders in large quantities.
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Microstructure and Dielectric Property of Strontium-Lead Titanate Functionally Graded Ceramics
ZHU Jing-Chuan,CHENG Hua-Rong,YIN Zhong-Da,Jeon Jaeho
2002 Vol. 17 (5): 992998
Abstract(
2014 )
PDF(2641KB)(
919
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A series of (Sr, Pb)TiO3 system dielectric ceramics with homogeneous and functionally graded compositions were fabricated by sintering process using chemically-coprecipitated (Sr1-xPbx)TiO3 nano-particles, and their compositional distribution, microstructure and dielectric property were investigated as well. The results indicate that, the ceramics are nearly densified and their grains coarse somewhat (mean size is about 6.3μm) after sintering. There are a small number of sealed pores in the ceramics. In homogeneous ceramics, Sr and Pb distribute evenly, while in graded ceramics Sr and Pb vary gradually. The major phase constituent obviously transforms from cubic paraelectric phase to tetragonal ferroelectric phase after sintering, in which the ferroelectric domains exist. The graded constitution effectively optimizes the dielectric property of (Sr, Pb)TiO3 ceramics; the work temperature zone is broadened and the dielectric-temperature stability is improved obviously.
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Structural Characteristics and Electrochemical Properties of Co-doped Spinel Li1+xCoyMn2-x-yO4 for Lithium-ion Batteries
ZHENG Zi-Shan,TANG Zi-Long,ZHANG Zhong-Tai,SHEN Wan-Ci
2002 Vol. 17 (5): 9991003
Abstract(
2146 )
PDF(1136KB)(
1033
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Cobalt was doped into the host spinel to produce cobalt-doped spinel material by a solution technique. The end Co-doped materials have many advantages of narrowly distributed and well crystallized particles and small surface area. The determination of XRD patterns shows that the peaks shift towards high angle and become sharp as the introduction of cobalt. The analysis of infrared (IR) spectroscopy illustrates that cobalt doping can enhance the strength of Mn--O bonds and improve the structural stability of the materials. The presence of cobalt reduces the dissolution of Mn into the electrolyte according to the investigation of ICP analysis results since Co-doped materials have more stable structure and smaller surface area. Cobalt doping can enhance the bond Mn--O and weaken the bond Li--O in the spinel. As the result, the Li+ ion has easier diffusion in the spinel and the Co-doped material has smaller charge-transfer resistant (Rct). The measurement of electorchemical properties shows that the Co-doped material Li1.03Co0.05Mn1.92O4 prepared in this technique has good cycling performance and high initial capacity.
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Heterogeneous Phases for Pulse Electric Current Sintering AlOOH
ZHANG Dong-Ming,FU Zheng-Yi,QUO Jing-Kun
2002 Vol. 17 (5): 10041008
Abstract(
2241 )
PDF(288KB)(
737
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The phases in different depth of a sample for pulse electric current sintering AlOOH was investigated by means of XRD analysis. The results show that: (1) the phases in top surface are different with that in down surface which indicates that the temperature decrease from top to down in the sample; (2) the peak of XRD in the top surface is lower than that in the next layer(0.3mm to top surface). Comparing the results of microwave plasma bombardment and HP with pulse electric current sintering, it is found that the top surface of SPS sample has similar XRD patterns with that of microwave plasma bombardment sample. So it is deduced that the top surface is bombarded by plasma, thus making the crystal structure distorted. The reason for forming the heterogeneous phase in the sample was analyzed in this paper.
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Two Critical Sizes of Barium Titanate and Lead Titanate
ZHONG Wei-Lie,AI Shu-Tao,JIANG Bin
2002 Vol. 17 (5): 10091012
Abstract(
2033 )
PDF(260KB)(
950
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With the size decreasing, a ferroelectric will change from multi-domain to single-domain and then from ferroelectric to paraelectric. The size at which a ferroelectric changes from muti-domain to single-domain is called the single-domain critical size, and the size below which ferroelectricity disappears is called the ferroelectric critical size. In this work, we calculated the two critical sizes for barium titanate and lead titanate respectively. The calculated results accord with experimental.
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Microstructure and Properties of Polycarbosilane Transferred Nano SiC Reinforced B4C Matrix Composites
DING Shuo,WEN Guang-Wu,LEI Ting-Quan,ZHOU Yu
2002 Vol. 17 (5): 10131018
Abstract(
2300 )
PDF(2086KB)(
1116
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Nano-sized SiC reinforced B4C matrix composites were fabricated through a pyrolysis route from polycarbosilane(PCS) precursor. The microstructure and properties of the materials, compared with the materials sintered by direct mixed powders, were investigated. It shows that, the composites fabricated via precursor form a kind of complicated intra-intergranular structure: nano SiC within the grains of B4C and Al2O3, sharp angle-layered SiC precipitating in the grain boundaries, and SiC substructures within the grains of B4C. The crack deflection within the crystal grains is caused by intragranular fracture, increasing the fracture toughness significantly. The homogenization, relative density and mechanical properties of the composites fabricated by polycarbosilane precursor are higher than those of the composites made by directly mixed powders.
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Application in FCC Catalyst Carrier of Xinjiang Kaolin
XIAO Jin-Kai,RONG Tian-Jun,HUANG Shi-Ming
2002 Vol. 17 (5): 10191024
Abstract(
2073 )
PDF(365KB)(
1111
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The chemical composition, mineral component, the condition of occurrence of iron, IR spectroscopy, physic properties and catalytic properties of kaolin clays in Xinjiang are presented in this paper. The study of application of Xinjiang dickite in catalyst carrier should be lucubrated. The catalytic properties of kaolin are affected by their genesis, chemical composition, mineral component, structure of mineral and physical properties. The study of correlation between mineralogical characteristics and catalytic properties of catalyst carrier should be strengthened.
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Structure and Photocatalytic Activities of Ag/TiO2 Thin Films
HE Chao,YU Yun,ZHOU Cai-Hua,HU Xing-Fang
2002 Vol. 17 (5): 10251033
Abstract(
2066 )
PDF(1479KB)(
1436
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Nanometric TiO2 thin films doped with Ag were prepared by the sol-gel method. The effects of Ag on the structure of TiO2 films were systematically studied by means of X-ray diffraction, BET nitrogen adsorption, UV-VIS-NIR transmission spectroscopy and X-ray photoelectron spectroscopy. The photocatalytic activity of Ag/TiO2 thin films was characterized and studied in photocatalytic degradation of methylene blue under UV irradiation in comparison with pure TiO2 thin films. The results showed that suitable amount of Ag effectively improved photocatalytic activity of TiO2 thin films. The mechanism could be ascribed to that: (1) The electron-hole pair separation efficiency of TiO2 films was improved by the introduction of Ag. The concentration of photoholes at the surface of TiO2 films increased; (2) TiO2 particle sizes decreased while Ag was introduced, which further widened the band-gap of TiO2 and improved its photocatalytic redox capability; (3) The absorption of -OH and H2O on TiO2 films was increased, which improved the photoholes transfer efficiency and the concentration of reactive --OH group on TiO2 thin films after UV irradiation.
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High Temperature Strength of Mo/PSZ Composites as Evaluated by MSP Test (Ⅱ)
JIANG Wan,BAI Guang-Zhao,WANG Gang,LI Jing-Feng
2002 Vol. 17 (5): 10341040
Abstract(
2080 )
PDF(2303KB)(
911
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In present work, the mechanical properties of Mo/PSZ (partially stabilized zirconia) composites were investigated at a temperature range from room temperature to 1573K by means of the modified small punch test (MSP) and the dependence of MSP strength for Mo/PSZ composites on composition and microstructure was discussed in detail. It was found that the change of MSP strength with the composition at various test temperatures was different: it took the shape of “W” at room temperature; at temperatures up to 873K and 1273K, the MSP strength approached its peak, respectively at the compositions where the Mo phase was dispersed or both compositional phases were continuous. The results show that MSP strength depends not only on the composition but also on the composite microstructure.
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Comparative Study on Several Mixed Conducting Oxygen Permeable Membrane Reactors
LI Guang-Tao,SHAO Zong-Ping,XIONG Guo-Xing,DONG Hui,CONG You,YANG Wei-Shen
2002 Vol. 17 (5): 10411047
Abstract(
2072 )
PDF(506KB)(
980
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Three mixed conducting oxygen permeable membranes, i.e. SrCo0.5FeO3.25 (SC5FO), La0.15Sr0.85Ga0.3Fe0.7O3-δ (LSGFO) and Ba0.5Sr0.5 Co0.8Fe0.2O3-δ (BSCFO) were synthesized by wet chemical methods. A comparative study about their phase structures, phase and thermo-chemical stabilities, oxygen permeability and membrane reactor performance for partial oxidation of methane to syngas, was made. After annealing in an Ar atmosphere at elevated temperatures, the pure cubic perovskite structure was survived for LSGFO and BSCFO, but not for SC5FO. After H2-TPR experiment, the original phase structures of BSCidiiFO and SC5FO were totally destroyed, but the basic perovskite structure of LSGFO was survived. Multi H2-TPR and re-oxidation results of BSCFO oxide demonstrated that it had excellent phase reversibilities. The oxygen permeabilities of SC5FO and LSCFO were very low, while a permeation flux as high as 1.1 mL/cm2·min was obtained for a BSCFO membrane at 850℃, which demonstrates its promising application for oxygen separation. Leaking problem was encountered for a SC5FO membrane reactor during POM reaction, while LSGFO and BSCFO membrane reactors were stably operated in the POM reaction. At 950℃, under POM reaction conditions, the oxygen permeation flux of LSGFO slowly increased with time, at last (about 300h was needed), a flux about 4 [STP]mL/cm^2·min was obtained, which was 10 to 40 times higher than that under an air/He oxygen partial pressure gradient. The oxygen permeation flux of the BSCFO membrane can reach its steady state (850℃C, 10.45 [STP]mL/cm2·min) much quicker (about 21h). The BSCFO and LSGFO reactors were stably operated for a long time without failure. The high POM operation stability of LSGFO is due to its high thermo-chemical stability. However, for BSCFO membrane reactor, it is due to its high oxygen permeability and excellent phase reversibility.
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Growth of α-BaB2O4 Single Crystal by the Bridgman Method
YI Shou-Tao,WANG Sheng,LE Xiu-Hong
2002 Vol. 17 (5): 10481050
Abstract(
1932 )
PDF(809KB)(
885
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The high temperature phase barium metaborate α-BaB2O4 single crystal with 25mm in diameter, 100mm in height was grown by the Bridgman method. The data of crystal growth was briefly introduced. The results show that there is not any scattering particle examined under He-Ne laser in the crystal. And the birefractive index of this crystal in visible spectra is about △n≈0.13. The transmittance of the crystal obtained in 200~900nm is more than 80%.
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Influence of Low-frequency Vibrations to the Fluid Surface
CHEN Gang-Yi,JIN Wei-Qing,PAN Zhi-Lei,LIU Zhao-Hua,LIANG Xin-An
2002 Vol. 17 (5): 10511053
Abstract(
1920 )
PDF(874KB)(
982
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A continuously adjustable vibration amplitude was induced in glycerite water solution. Monitored by CCD, with Al tracer particles for flow visualization and velocity measurements, various resonance phenomena on the fluid surface were firstly observed. The surface streaming velocities at different resonance points were measured. The behavior of the fluid surface under a gradually increasing amplitude can be showed clearly by the experiment.
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Synthesis of Ultrafine Aluminium Nitride Powder by a Low-temperature Carbothermal Reduction Process
QIN Ming-Li,QU Xuan-Hui,LIN Jian-Liang,XIAO Ping-An,ZHU Bao-Jun
2002 Vol. 17 (5): 10541058
Abstract(
2209 )
PDF(1114KB)(
1343
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A new precursor containing a homogenous mixture of noncrystalline Al2O3 and carbon was prepared with aluminium nitrate, glucose and urea as raw materials, by a low-temperature combustion process. The nitridation of this precursor shows that it has a high reactivity and nitridation reaction proceeds rapidly. AlN powders with ultrafine particle sizes (~100nm) can beobtained at 1550℃ within 90min.
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Analysis on the Phase Distribution of Nano SiC Particles Coated with Cu
ZHANG Rui,GAO Lian,YU Ling,GUO Jing-Kun
2002 Vol. 17 (5): 10591062
Abstract(
1840 )
PDF(1416KB)(
908
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Nano SiC particles in diameter of about 100nm were commercially available, Cu particles were precipitated during the disproportionation reaction process. The morphology of the mixed powders containing the nano SiC and Cu particles were observed by SEM or Auger microprobe, in which the spherical particles dominated. EDS and AES were carried out to determine the element distribution in the local area and spot across a single particle. The coating process of Cu on the surface of the nano SiC particles ensures the homogeneous phase-distribution between the two different phases.
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Influences of Processing Parameters on Bi4Ti3O12 Powder Prepared by Molten Salt Methods
KAN Yan-Mei,WANG Pei-Ling,LI Yong-Xiang,CHENG Yi-Bing
2002 Vol. 17 (5): 10631067
Abstract(
1937 )
PDF(2368KB)(
913
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The influences of processing parameters on Bi4Ti3O12 powder prepared by a molten salt method were studied. The results obtained indicate that the powder characteristics are greatly influenced by the synthesizing temperature, type and quantity of the salts used. In chloride salt, Bi4Ti3O12 particles grow by the Ostwald ripening mechanism, their dimension increases with increasing temperatures, showing a circular platelike morphology. The powder prepared in sulfate salt has larger particle size and more irregular platelike morphology than that in the chloride salt. As the Bi4Ti3O12 precursor to salt ratio is less than 1, the grain size decreases with increasing sulfate salt quantity, at the same time the particle morphology becomes more irregular. Bi4Ti3O12 powder with specific particle size and morphology can be obtained by adjusting the processing parameters.
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Influence of CrO3 Additive on the Thermite Reaction Procedure in Fe2O3+Al System
WANG Shuang-Xi,LIANG Kai-Ming,ZHANG Xian-Hui,XU Wei
2002 Vol. 17 (5): 10681072
Abstract(
2177 )
PDF(1002KB)(
888
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A hercynite-free ceramic lined steel pipe was fabricated by the self-propagating high-temperature synthesis gravitational-thermite process(SHS G-T Process). The sequence of some reactions which are possible to take place in the aluminothermic system was determined by thermodynamic analysis, i.e. CrO3>Fe2O3>Fe3O4>FeO>FeAl2O4>Cr2O3. The results show that in Fe2O3+Al system CrO3 reacts with Al in two steps. This gives the possibility of elimination of FeAl2O4 phase, which is more reactive than Cr2O3.
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Effect of Thermal Treatment Time on the Dispersion of MoO3 onto the Surface of MCM-41
LI Zheng-Ping,GAO Lian,ZHENG Shan
2002 Vol. 17 (5): 10731077
Abstract(
2146 )
PDF(235KB)(
819
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The dispersion of MoO3 onto the surface of MCM-41 was carried out by thermally treating the mixtures of MoO3 and MCM-41. The effect of thermal treatment time on the spreading of MoO_3 onto the surface of MCM-41 support was studied by XRD and LRS. The results showed that bulk MoO3 transformed into dispersed surface polymolybdates species gradually as prolonging the treating time. The complete dispersion of MoO3 was attained after heating for 8h at 500℃ when m(MoO3)/m(MCM-41) was 0.2. The structure of MCM-41 was still maintained in the process of thermal treatment. BET surface areas, pore volumes and BJH pore sizes of the samples were not changed markedly as the increment of thermal treatment time, which indicated that MoO3 dispersed monolayeredly on the surface of MCM-41.
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2-D Phase-field Simulation of Pore Evolution in Sintering Ceramics
JING Xiao-Ning,NI Yong,HE Ling-Hui,ZHAO Jian-Hua
2002 Vol. 17 (5): 10781082
Abstract(
2146 )
PDF(1424KB)(
1235
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This paper was devoted to the modeling of pore evolution in sintering ceramics by a two-dimensional phase-field model. A pore among four grains was considered, and the microstructure was described by a continuous density field and a long-range orientation field(LRO). The evolution of the density was governed by Cahn-Hilliard equation, while the orientation field by the time-dependent Ginzburg-Landau equation(TDGL). The nonlinear evolution equations were solved by a semi-implicit Fourier-spectral scheme. The simulation results reflect the microscopic process such as grain contact, sintering neck growth and pore spheroidization. The predicted growth rate of sintering neck and sintering rate for different ratios of grain boundary to surface mobility are consistent with the existing theoretical analysis.
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Poisoning Phenomenon on the Surface of ITO Target During DC-Magnetron Sputtering Process
KONG Wei-Hua
2002 Vol. 17 (5): 10831088
Abstract(
2910 )
PDF(2309KB)(
14005
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The poisoning phenomenon on the surface of ITO target during DC-Magnetron sputtering process was investigated. XRD, EPMA and LECO oxygen analyzer were used to study the poisoning mechanism and the factors leading to poisoning were analyzed. The result shows that In2O3 is decomposed into In2O and O2. This reaction on the surface of ITO target is the reason causing the poisoning phenomenon.
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