Journal of Inorganic Materials

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Encapsulation Study of Persistent Luminescent Pigment of Alkaline Earth Aluminate

LU Xing-Dong; SHU Wan-Gen; TAN Ai-Dong; ZHOU Wen-Hua   

  1. Chemistry and Chemical College of Central-south University; Changsha 410083; China
  • Received:2003-10-08 Revised:2003-11-24 Published:2004-11-20 Online:2004-11-20

Abstract: Silica encapsulation was studied on the particle surface of aluminate-based luminescent pigment by using TEOS as
the raw materials. The encapsulated particles were analyzed by SEM, diameter testing, BET surface area measurement and XPS, a dense SiO2 film formed
on particle surface with the thickness of 14nm. The anti-water property and luminescent characteristics measurement show
that encapsulated particles have a better anti-water performance and similar luminescent properties to non-encapsulated particles. Moreover, the
encapsulation procedure was analyzed and the process parameters’ effect on coating film was also researched. The results show that the encapsulation
procedure is actually a kind of sol-gel procedure of SiO2·nH2O on the surface of particles and its process is optimized as following: pH
of encapsulation solvent is about 10, encapsulation temperature is at 80℃ and reaction time is about 3.0.

Key words: luminescent pigment, encapsulation, sol-gel, aluminate

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