Preparation and Structural Characterization of B2O3/MCM-41 Material

Abstract

Abstract: The B₂O₃/MCM-41 material was prepared by the solution-grafting method, using tri-butyl borate as boron source. DTA, XRD, FTIR, XPS and N₂ adsorption-desorption isotherms were employed to characterize the synthesized materials. The results show that boron specie separates out and exists as cubic B₂O₃ after calcining at 400℃. The trigonal BO₃ is as the basic coordinated unit in B₂O₃/MCM-41. The solution-grafting and following calcination have little effect on the structure of MCM-41 host.

Key words: B₂O₃, MCM-41, solution-grafting

CLC Number:

TB383

LI Zheng-Ping,GAO Lian. Preparation and Structural Characterization of B₂O₃/MCM-41 Material[J]. Journal of Inorganic Materials.

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Preparation and Structural Characterization of B₂O₃/MCM-41 Material

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