Preparation of Nanocrystalline Ba3(Ca1.18Nb1.82)O9-δ Powder by UsingCitrate Sol-Gel Method

Abstract

Abstract: Ba₃(Ca_1.18Nb_1.82)O_9-δ(BCN18) powders were synthesized by using a wet chemical method from a mixture of all
water-soluble compounds including Ba, Ca and Nb-citrate. Heating a mixed aqueous solution with the molar ratio of Ba:Ca:Nb:citric acid=3:1.18:1.82:12
produced a light green gelatinous viscous matter without any precipitation, then evaporating, drying and calcinating were conducted. The obtained gels
were characterized by TG-DTA, XRD and TEM. The experimental results show that the heating temperature is 750℃ for getting the powder and
the average particle size is about 50nm. Furthermore a pure BCN18 phase with a complex perovskite structure forms at 1000℃,it is lower about
600℃ than that reported by using the traditional solid-reaction method. The citrate sol-gel method is more practical and ascendant than the wet-chemical method used to the alcohol salt system reported in present literature.

Key words: Ba₃（Ca_1.18Nb_1.82）O_9-δ（BCN18）, sol-gel method, high temperature proton conductors, complex perovskite

CLC Number:

TB383

SU Xin-Tai,LIU Rui-Quan,HU Yun-Xia,XIE Ya-Hong,WANG Ji-De. Preparation of Nanocrystalline Ba₃(Ca_1.18Nb_1.82)O_9-_δ Powder by UsingCitrate Sol-Gel Method[J]. Journal of Inorganic Materials.

[1]	DAI Le, LIU Yang, GAO Xuan, WANG Shuhao, SONG Yating, TANG Mingmeng, DMITRY V Karpinsky, LIU Lisha, WANG Yaojin. Self-polarization Achieved by Compositionally Gradient Doping in BiFeO₃ Thin Films [J]. Journal of Inorganic Materials, 2024, 39(1): 99-106.
[2]	MAN Xin, WU Nan, ZHANG Mu, HE Hongliang, SUN Xudong, LI Xiaodong. Lu₂O₃-MgO Nano-powder: Synthesis and Fabrication of Composite Infrared Transparent Ceramics [J]. Journal of Inorganic Materials, 2021, 36(12): 1263-1269.
[3]	YANG Conggang, MI Le, FENG Aihu, YU Yang, SUN Dazhi, YU Yun. Synthesis and Performance of KH-560 Modified SiO₂ Insulation Coating [J]. Journal of Inorganic Materials, 2021, 36(12): 1343-1348.
[4]	ZHU Ben-Bi,ZHANG Wang,ZHANG Zhi-Jian,ZHANG Jian-Zhong,IMRAN Zada,ZHANG Di. Photothermal Enhanced Photocatalytic Properties of Titanium Dioxide (B)/Glass Fiber Cloth [J]. Journal of Inorganic Materials, 2019, 34(9): 961-966.
[5]	HE Fei, LI Ya, LUO Jin, FANG Min-Han, HE Xiao-Dong. Development of SiO₂/C and SiC/C Composites Featuring Aerogel Structures [J]. Journal of Inorganic Materials, 2017, 32(5): 449-458.
[6]	CHEN Ting, ZHA Jian-Rui, ZHANG Xiao-Jun, JIANG Wei-Hui, JIANG Wan, LIU Jian-Min, WU Qian. Silane Coupling Agent on Synthesis and Antioxidation Property of Zircon Film [J]. Journal of Inorganic Materials, 2017, 32(11): 1154-1158.
[7]	YIN Yue-Feng, LIANG Gui-Jie, ZHANG Qiang, PAN Zheng, LI Wang-Nan, LI Zai-Fang. Optimization of Dye-sensitized Solar Cells Prepared by Pechini Sol-Gel Method [J]. Journal of Inorganic Materials, 2016, 31(7): 739-744.
[8]	WU Shuang, LIU Bo, QIU Zhi-Che, CHEN Shi-Wei, ZHANG Juan-Nan, LIU Xiao-Lin, GU Mu, HUANG Shi-Ming, NI Chen. Improved Preparation Method and Luminescence Properties of LuTaO₄:Ln³⁺(Ln=Eu,Tb) Thin Film [J]. Journal of Inorganic Materials, 2016, 31(4): 372-376.
[9]	ZHANG Yuan-Yuan, TANG Xiao-Dong, CHEN Ying, WANG Gen-Shui, DONG Xian-Lin. Electrical Transport Properties in La_0.7Ca_0.3-_xSr_xMnO₃ Thin Films [J]. Journal of Inorganic Materials, 2016, 31(3): 274-278.
[10]	XU Jia-Yue, WANG Jie, CHEN Wei, XIAO Xue-Feng, YANG Bo-Bo, WANG Zhan-Yong, LI Fei, XIE Hui-Dong. Synthesis, Growth and Scintillation Properties of Large Size Bi₄Si₃O₁₂ Crystals [J]. Journal of Inorganic Materials, 2016, 31(10): 1147-1150.
[11]	LI Yan-Chun, ZHANG Xiu-Ling, ZHAN Zhi-Bin, DI Lan-Bo. Influence of Ionic Liquids on Structure and Properties of Magnetically Separable TiO₂ Photocatalytic Materials [J]. Journal of Inorganic Materials, 2015, 30(7): 706-712.
[12]	WU Ying-Jie, WANG Hai-Ling, NING Xing-Kun, WANG Zhan-Jie, WANG Qiang. Dielectric Properties of Au-BaTiO₃ Nanocomposite Films Prepared by Sol-Gel Method [J]. Journal of Inorganic Materials, 2015, 30(2): 207-213.
[13]	HE Fei, YU Wan-Jun, FANG Min-Han, HE Xiao-Dong, LI Ming-Wei. An Overview on Silica Aerogels Synthesized by Siloxane Co-precursors [J]. Journal of Inorganic Materials, 2015, 30(12): 1243-1253.
[14]	WANG San-Hai, JIANG Wei-Hui, FENG Guo, LIU Jian-Min, MIAO Li-Feng, WANG Hong-Da. Preparation of Zircon Whisker Using Carbon Black as Reducing Agent [J]. Journal of Inorganic Materials, 2014, 29(8): 835-838.
[15]	LOU Feng-Guang, WANG Shi-Kai, WANG-Meng, Feng Su-Ya, YU Chun-Lei, HU Li-Li. Sol-Gel Derived Al³⁺,Yb³⁺ Co-doped Silica Fiber Core [J]. Journal of Inorganic Materials, 2014, 29(4): 393-398.

Preparation of Nanocrystalline Ba₃(Ca_1.18Nb_1.82)O_9-_δ Powder by UsingCitrate Sol-Gel Method

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments