Preparation and Electrochemical Behavior of LiNiO2 as Cathode Materials in Secondary Lithium Ion Battery

Abstract

Abstract: Layered and highly crystalline LiNiO₂ was prepared by heating a mixture of lithium hydroxide and nickel hydroxide at high temperature. The influence of preparation conditions on the electrochemical behavior of the product was discussed. It was found that tempwrature and duration of reaction as well as Li/Ni mole ratio exert important effects on the electrochemical behavior of the product. LiNiO₂ prepared in this work has a reversible capacity of about 140mA.·h/g.

Key words: lithium ion batteries, cathodic material, synthetic LiNiO₂, electrochemical behavior

CLC Number:

TM911

TIAN Yan-Wen,ZHAI Xiu-Jing,GAO Hong,ZHAI Yu-Chun. Preparation and Electrochemical Behavior of LiNiO₂ as Cathode Materials in Secondary Lithium Ion Battery[J]. Journal of Inorganic Materials.

[1]	CAI Ya-Ling, LI Ya-Fei, WANG Zeng-Mei, ZHANG Yao, CHEN Jian, GUO Xin-Li. CTAB-assisted Synthesis of MoS₂/C Nano-flowers with Improved Electrochemical Performances for Lithium Ion Batteries [J]. Journal of Inorganic Materials, 2016, 31(12): 1289-1294.
[2]	ZHANG Xu, WANG Yu, LI Yue, YANG Meng, ZHAO Xiang-Yu, MA Li-Qun. Effect of Nickle Substitution on the Performance of Lithium Ion Battery Material LiMnTiO₄ [J]. Journal of Inorganic Materials, 2015, 30(7): 739-744.
[3]	FENG Ming-Yan, TIAN Jian-Huan, LIU Yuan-Yuan, SHAN Zhong-Qiang. Effect of Silicon Anode Additives on Lithium Ion Batteries [J]. Journal of Inorganic Materials, 2015, 30(6): 647-652.
[4]	TIAN Li-Yuan, YAO Zhi-Heng, LI Feng, WANG Yong-Long, YE Shi-Hai. Synthesis and Electrochemical Performance of Red Phosphorus/Carbon Composites [J]. Journal of Inorganic Materials, 2015, 30(6): 653-661.
[5]	LI Yun-Jiao, XU Hu, KONG Long, LI Hua-Cheng, LI Chun-Xia, ZHANG Xian-Zhen, HAN Qiang. Synthesis and Electrochemical Characterizations of Co-doped Lithium Manganese Oxide Spinel Li_1.035Mn_1.965O₄ [J]. Journal of Inorganic Materials, 2014, 29(6): 661-666.
[6]	WANG Yan-Ming, WANG Fei, WANG Guang-Jian. Sol-Gel Synthesis and Electrochemical Performance of LiMnPO₄/C Cathode Material [J]. Journal of Inorganic Materials, 2013, 28(4): 415-419.
[7]	ZHENG Yue-Lei, CHEN Ren-Jie, WU Feng, LI Li. Progress of Research on the Conductive Mechanism of the Glassy Electrolytes in Lithium Ion Batteries [J]. Journal of Inorganic Materials, 2013, 28(11): 1172-1180.
[8]	PENG Peng, LIU Yu, WEN Zhao-Yin. Electrochemical Performance of Silicon/Carbon/Graphite Composite Anode for Lithium Ion Batteries [J]. Journal of Inorganic Materials, 2013, 28(11): 1195-1199.
[9]	MOU Fei, YANG Xue-Lin, DAI Zhong-Xu, ZHANG Lu-Lu, WEN Zhao-Yin. Effect of Sintering-method on Electrochemical Performance of LiFePO₄/C Cathode Material [J]. Journal of Inorganic Materials, 2012, 27(8): 838-842.
[10]	JIAN Zhi-Min, LIU Hong-Bo, SHI Lei, HE Yue-De, XIAO Hai-He, KUANG Jia-Cai. Influences of Mild Oxidation Treatment on the Structure and Electrochemical Behavior of Spherical Graphite [J]. Journal of Inorganic Materials, 2012, 27(2): 151-156.
[11]	LIU Guo-Cong, LIU You-Nian, LIU Su-Qing, DONG Hui. Sol-Gel Synthesis and Electrochemical Performance of Li₃V_2-2x/3Mnx(PO₄)₃ Cathode Material for Lithium-ion Batteries [J]. Journal of Inorganic Materials, 2012, 27(10): 1017-1022.
[12]	DENG Fei, ZENG Xie-Rong, ZOU Ji-Zhao, LI Xiao-Hua. Effects of Preparation Temperature on Pyrolytic Carbon Coated LiFePO₄/Vapor-grown Carbon Fiber (PCLFP/VGCF) Composite Cathode Material [J]. Journal of Inorganic Materials, 2011, 26(11): 1141-1146.
[13]	JIA Wei, XU Mao-Wen, BAO Shu-Juan, JIA Dian-Zeng. Synthesis and Electrochemical Performance of Porous TiO₂ [J]. Journal of Inorganic Materials, 2010, 25(12): 1335-1339.
[14]	SUN Ke,LU Hai-Wei,LI Da,ZENG Wei,LI Yue-Sheng,FU Zheng-Wen. Electrospun Manganese Oxides Nanofibers Electrode for Lithium Ion Batteries [J]. Journal of Inorganic Materials, 2009, 24(2): 357-360.
[15]	ZHOU Xin,ZHAO Xin-Bing,YU Hong-Ming,HU Jie-Zi. Electrochemical Properties of F-doped LiFePO₄/C Prepared by Solid-state Synthesis [J]. Journal of Inorganic Materials, 2008, 23(3): 587-591.

Preparation and Electrochemical Behavior of LiNiO₂ as Cathode Materials in Secondary Lithium Ion Battery

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments