Journal of Inorganic Materials ›› 2014, Vol. 29 ›› Issue (6): 639-644.DOI: 10.3724/SP.J.1077.2014.13416
• Orginal Article • Previous Articles Next Articles
WANG Yan, WANG Hong-Ning, CHEN Ruo-Yu
Received:
2013-08-13
Revised:
2013-10-29
Published:
2014-06-20
Online:
2014-05-27
About author:
WANG Yan. E-mail: wangyan1989816@126.com
CLC Number:
WANG Yan, WANG Hong-Ning, CHEN Ruo-Yu. Structure of Antireflective Films with Si-O-P Bonds and Impact Factors on Its Performance[J]. Journal of Inorganic Materials, 2014, 29(6): 639-644.
Add to citation manager EndNote|Ris|BibTeX
n(H3PO4/SiO2) | 0 | 0.16 | 0.33 | 0.49 | 0.65 | 0.82 | 0.98 |
---|---|---|---|---|---|---|---|
SBET /(m2•g-1) | 230.5 | 76.3 | 59.6 | 38.7 | 21.6 | 2.1 | / |
Si-OH content/(bonds•nm-2) | 10.2 | 7.8 | 5.6 | 4.3 | 3.1 | 2.3 | / |
Pencil hardness grade | 5B | F | 3H | 6H | 4H | 3H | H |
Table 1 SBET and the Si-OH content of the SiO2 gels with different n(H3PO4)﹕n(H2O2)﹕n(EtOH)﹕n(SiO2)= 0.52﹕30﹕1) and pencil hardness grades of the corresponding SiO2 films
n(H3PO4/SiO2) | 0 | 0.16 | 0.33 | 0.49 | 0.65 | 0.82 | 0.98 |
---|---|---|---|---|---|---|---|
SBET /(m2•g-1) | 230.5 | 76.3 | 59.6 | 38.7 | 21.6 | 2.1 | / |
Si-OH content/(bonds•nm-2) | 10.2 | 7.8 | 5.6 | 4.3 | 3.1 | 2.3 | / |
Pencil hardness grade | 5B | F | 3H | 6H | 4H | 3H | H |
n(H2O2/SiO2) | 0 | 0.26 | 0.39 | 0.52 | 0.64 | 0.77 | 0.90 | 1.03 |
---|---|---|---|---|---|---|---|---|
Pencil hardness grade | F | 3H | 3H | 6H | 6H | 5H | 5H | 5H |
Average transmittance/% | 98.0 | 97.7 | 98.0 | 98.0 | 97.6 | 97.9 | 97.8 | 98.0 |
Table 2 Pencil hardness grades and the average transmittance in the visible light of the SiO2 films with different n(H2O2/SiO2) (n(H3PO4/EtOH/SiO2)= 0.49: 30: 1)
n(H2O2/SiO2) | 0 | 0.26 | 0.39 | 0.52 | 0.64 | 0.77 | 0.90 | 1.03 |
---|---|---|---|---|---|---|---|---|
Pencil hardness grade | F | 3H | 3H | 6H | 6H | 5H | 5H | 5H |
Average transmittance/% | 98.0 | 97.7 | 98.0 | 98.0 | 97.6 | 97.9 | 97.8 | 98.0 |
[1] | FURBO S, SHAH L J. Thermal advantages for solar heating systems with a glass cover with antireflection surfaces. Sol. Energy, 2003, 74(6): 513-523. |
[2] | ZHANG QIAN, JI RUO-NAN, ZHANG LIANG, et al. Synthesis and properties research of antireflection film for solar cells. Chemical Industry and Engineering Progress, 2012, 31(Sppl.): 347-349. |
[3] | NOSTELL P, ROOS A, KARLSSON B. Optical and mechanical properties of Sol-Gel antireflective films for solar energy applications. Thin Solid Films, 1999, 351(1): 170-175. |
[4] | WANG QUAN-ZHI, JING XI-LI, MA YI-HENG, et al. Refractive indexes distribution of anti-reflection coatings for high efficiency silicon solar cells. Laser and Infrared, 2011, 41(6): 669-672. |
[5] | BAUTISTA M C, MORALES A. Silica antireflective films on glass produced by the Sol-Gel method.. Sol. Energy Mater. Sol.Cells, 2003, 80(2): 217-225. |
[6] | BELLEVILLE P F, PRENÉ P, MENNECHEZ F, et al. Sol-Gel antireflective spin-coating process for large-size shielding windows. International symposium on optical science and technology .International Society for Optics and Photonics, 2002, 4804: 69-72. |
[7] | RAUT H K, NAIR A S, DINACHALI S S, et al. Porous SiO2 anti-reflective coatings on large-area substrates by electrospinning and their application to solar modules. Sol. Energy Mater. Sol. Cells, 2013, 111: 9-15. |
[8] | SHEN JUN, LIU YUAN, LI XIAO-GUANG. Surface modification and contamination resistance of Sol-Gel SiO2 derived. Journal of the Chinese Ceramic Society, 2010, 38(11): 2054-2058. |
[9] | MAI X D, JUNE K L, WOO-SIK S, et al. Ultralow-n SiO2 Thin films synthesized using organic nanoparticles template.Bull. Korean Chem. Soc, 2010, 31(12): 3593-3599. |
[10] | ZHAO Q N, LIU Y, HOU S H, et al. Preparation and characterization of nano-porous SiO2/TiO2-SiO2 thin films on glass substrates by Sol-Gel method. Key Eng. Mater. , 2013, 531: 651-654. |
[11] | XU Y D, PENG CH, XIN CH F, et al. Preparation of silica antireflective films for solar energy application .Mater. Lett, 2013, 94(1): 89-91. |
[12] | CHI F T, YAN L H, LV H B, et al. Novel pathways for the preparation of silica antireflective films: improvement in mechanical property. Mater. Lett , 2011, 65: 1095-1097. |
[13] | WANG JIAN-WU, BAI YU-CHEN, YAO WEI, et al. Preparation and investigation of SiO2/TiO2 antireflective coatings with self- cle-an--ing and scratch-resistant Properties. Journal of Inorganic Materials, 2011, 26(7): 769-773. |
[14] | LI X G, SHEN J. A scratch-resistant and hydrophobic broadband antireflective coating by Sol-Gel method. Thin Solid Films, 2011, 519: 6236-6240. |
[15] | WU G M, WANG J, SHEN J, et al. Properties of Sol-Gel derived scratch-resistant nano-porous silica films by a mixed atmosphere treatment. J. Non-Cryst Solids, 2000, 275(3): 169-174. |
[16] | WANG J, WU G M, SHEN J, et al. Scratch-resistant improvement of Sol-Gel derived nano-porous silica films. J. Sol-Gel Sci. Technol, 2000, 18: 219-224. |
[17] | YE H P, ZHANG X X, ZHANG Y L, et al. Preparation of antireflective coatings with high transmittance and enhanced abrasion- resistance by a base/acid two-step catalyzed Sol-Gel process. Sol. Energy Mater. Sol. Cells, 2011, 95: 2347-2351. |
[18] | KOZUKA H, YAMANO A, FUJITA M, et al. Aqueous dip-coating route to dense and porous silica thin films using silica nanocolloids with an aid of polyvinylpyrrolidone. J. Sol-Gel Sci. Technol, 2012, 61: 381-389. |
[19] | ZHU JIAN-JUN, YAO JING, LV XIAO-MENG, et al. Synthesis and characterization of superhydrophobic mesoporous silica aerogels by ambient pressure drying .Journal of the Chinese Ceramic Society, 2009, 37(4): 512-515. |
[20] | NISHIYAMA N, KAIHARA J, NISHIYAMA Y, et al. Vapor-phase synthesis of mesoporous SiO2-P2O5 thin films. Langmuir, 2007, 23: 4746-4748. |
[21] | DAYANAND C, BHIKSHAMAIAH G, JAYA TYAGARAJU V, et al. Review structural investigations of phosphate glasses: a detailed infrared study of the x(PbO)-(1-x)P2O5 vitreous system .J. Mater. Sci, 1996, 31:1945-1967. |
[22] | CUI SH, LIU Y, FAN M H, et al. Temperature dependent microstructure of MTES modified hydrophobic .Mater. Lett , 2011, 65: 606-609. |
[23] | SALAME I I, BANDOSZ T J. Surface chemistry of activated carbons: combining the results of temperature-programmed desorption, boehm, and potentiometric titrations .J. Colloid Interf. Sci, 2001, 240: 252-258. |
[24] | BOEHM H P. Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon, 1994, 32(5): 759-769. |
[25] | BOEHM H P. Chemical identification of surface groups. Adv.in Catal., 1966, 16: 179-274. |
[26] | OUYANG ZHAO-HUI, WU LIN, LI KONG-BIAO, et al. Surface modification of nano-SiO2 in gas phase. Chemical Industry and Engineering Progress, 2005, 24(11): 1265-1268. |
[27] | ISO 15184: 1998, Paints and varnishes: determination of film hardness by pencil test.. ISO, 1998. |
[28] | CHEN ZH, WU L Y L, CHWA E, et al. Scratch resistance of brittle thin films on compliant substrates. Mater. Sci. Eng. A, 2008, 493: 292-298. |
[29] | DAPUZZO M, ARONNE A, ESPOSITO S, et al. Sol-Gel synthesis of humidity-sensitive P2O5-SiO2 amorphous films .J. Sol-Gel Sci. Technol, 2000, 17: 247-254. |
[30] | DUAN XIANG, WANG DE-PING, YAO AI-HUA, et al. Fabrication of hydroxyapatite with three-dimensional pore frame by colloidal template method. Journal of Inorganic Materials, 2009, 24(1): 161-165. |
[1] | MA Bao-Kai, LI Mian, CHEONG Ling-Zhi, WENG Xin-Chu, SHEN Cai, HUANG Qing. Enzyme-MXene Nanosheets: Fabrication and Application in Electrochemical Detection of H2O2 [J]. Journal of Inorganic Materials, 2020, 35(1): 131-138. |
[2] | ZHANG Xiao-Feng,ZHANG Guan-Hua,MENG Yue,XUE Ji-Long,XIA Sheng-Jie,NI Zhe-Ming. Photocatalytic Degradation of Methylene Blue by Schiff-base Cobalt Modified CoCr Layered Double Hydroxides [J]. Journal of Inorganic Materials, 2019, 34(9): 974-982. |
[3] | SUN Li-Mei, SHI Le-Le, ZHANG Shuai-Shuai, ZHANG Yi-Jia, LI Zeng-Hui, HE Wurigamula. Cathode Performance of Mg-H2O2 Semi-fuel Cell with Pdn-Fe Alloy as Cathode [J]. Journal of Inorganic Materials, 2018, 33(1): 81-86. |
[4] | TAN Man-Lin, ZHANG Li-Jie, WANG Xiao-Wei, MA Qing, FU Dong-Ju, ZHANG Wei-Li, LI Dong-Shuang, CHEN Jian-Jun, ZHANG Hua-Yu. Hydrophobic and Environment-resistant Properties of SiO2/TiO2/SiO2-TiO2 Multilayer Antireflective Films in Wide Solar Spectra Range [J]. Journal of Inorganic Materials, 2016, 31(4): 365-371. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||