Effect of Ultrasonic Field on Preparation of Sb2O3

doi:10.3724/SP.J.1077.2006.01333

Abstract

Abstract: The preparation of ultrafine cubic Sb₂O₃ was studied by using oxychloride (Sb4O5Cl2) neutralized with ammonia under ultrasonic field. The results show that Sb₂O₃ obtained in the process is cubic crystalline and well-dispersed, which has an average particle size of 0.777μm when the ultrasonic power is 100W, the ultrasonic time is 30min, and the temperature is 20℃. The effects of ultrasonic power, time, ratios of distilled water to oxychloride, and temperature on the crystal structure and particle size of the Sb₂O₃ formed were investigated by means of XRD, SEM and laser sizer.

Key words: ultrasonic field, ultrafine, cubic crystal, Sb2O3

CLC Number:

TB333

QIU Ke-Qiang,ZHANG Rong-Liang,TANG Shu-Zhen,SHE Yuan-Yuan,HU Han-Xiang. Effect of Ultrasonic Field on Preparation of Sb₂O₃[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2006.01333.

References

[1] 李文杰, 徐本富(LI Wen-Jie, et al). 广东工学院学报(Journal of Guangdong Institute of Technology), 1993, 10 (2): 51--58.
[2] 段学臣, 赵天从(DUAN Xue-Chen, et al). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 1996, 6 (1): 36--39.
[3] 甘庆民, 杨秉文(GAN Qing-Min, et al). 材料工程(Material Engineering), 1997, (8): 27,46.
[4] 张多默, 肖松文, 刘志宏,等(ZHANG Duo-Mo, et al). 中南大学学报(Journal of Central South University), 2000, 31 (2): 121--123.
[5]肖松文, 刘志宏, 李启厚,等(XIAO Song-Wen, et al). 矿冶工程(Mining and Metallurgical Engineering), 1999, 19 (3): 39--41.
[6] Suslick K S, Hyeon T, Fang M, Materials Science and Engineering: A, 1995, 204(1-2): 186--192.
[7] Kristl M, Drofenik M. Inorganic Chemistry Communications, 2003, 6 (12): 1419--1422.
[8] Cui H M, Liu H, Wang J Y, et al. Journal of Crystal Growth, 2004, 271 (3-4): 456--461.
[9] 张昭, 吴潘, 王乐飞, 等(ZHANG Zhao, et al). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 2005, 15 (2): 321--326.
[10] 吴争平, 尹周谰, 陈启元, 等(WU Zhen-Ping, et al). 过程工程学报(The Chinese Journal of Process Engineering), 2002, 2 (1): 26--31.
[11] Borkovska L V, Baran M P. Korsunska N O, et al. Physica, 2003, B340-342: 258--262.
[12] Kumar R Vijaya, Elgamioel R, Koltypin Yu, et al. Journal of Crystal Growth, 2003, 250 (3-4): 409--417.
[13] 徐华蕊, 李凤生, 陈舒林,等(XU Hua-Rui, et al). 化工进展(Chemical Industry and Engineering Process ), 1996, (5): 20--31,57.
[14] 陈雪梅, 陈彩凤, 陈志刚(CHEN Xue-Mei, et al). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 2003, 13 (10): 122--126.
[15] 梁新义, 秦永宁, 齐晓周,等(LIANG Xin-Yi, et al). 化学物理学报(Chinese Journal of Chemical Physics), 1998, 11 (4): 375--378.

Effect of Ultrasonic Field on Preparation of Sb₂O₃

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WANG Xue-Zheng, WANG Hai-Bin, LIU Xue-Mei, YANG Tao, SONG Xiao-Yan. Grain Growth Inhibitor on the WC-Co Cemented Carbide Coating [J]. Journal of Inorganic Materials, 2017, 32(8): 813-818.
[2]	DOU Zhi-He, ZHANG Ting-An, WEN Ming, SHI Guan-Yong, HE Ji-Cheng. Preparation of Ultra-fine NdB₆ Powders by Combustion Synthesis and Its Reaction Mechanism [J]. Journal of Inorganic Materials, 2014, 29(7): 711-716.
[3]	ZHANG Zhi-Xiao, DU Xian-Wu, WANG Wei-Min, FU Zheng-Yi, WANG Hao. Preparation and Sintering of High Active and Ultrafine B₄C-SiC Composite Powders [J]. Journal of Inorganic Materials, 2014, 29(2): 185-190.
[4]	WANG Xiao-Dong, YAN Jing, HUANG Wei. Preparation and Characterization of Ultrafine Crystal TS-1 Films [J]. Journal of Inorganic Materials, 2011, 26(1): 85-90.
[5]	TIAN Chang-An,LIU Jun-Liang,CAI Jun,ZENG Yan-Wei. Synthesis of La_9.33Si₆O₂₆ Single-phase Ultrafine Powder by Sol-Gel Self-combustion Method [J]. Journal of Inorganic Materials, 2008, 23(1): 77-81.
[6]	HAN Xiao-Jian,HUANG Zheng-Ming,HE Chuang-Long,LIU Ling,DONG Guo-Hua,WU Qing-Sheng. Preparation and Characterization of Polycarbonate/TiO₂ Ultrafine Fibers [J]. Journal of Inorganic Materials, 2007, 22(3): 407-412.
[7]	WU Guo-Hua,ZHOU Hong-Zhao,ZHU Shen-Lin. Preparation of Ultrafine Barium Sulfate in Impinging Streams Microreactor [J]. Journal of Inorganic Materials, 2006, 21(5): 1079-1084.
[8]	FENG Li,LIU Jiong-Tian,WANG Jian-Huai,WANG Bin-Guo,SONG Shuo-Jiang. Effects of Surfactants on Dispersion Properties of Nano-Sb₂O₃ and Nano-Sb₂O₃/Mica [J]. Journal of Inorganic Materials, 2006, 21(4): 972-978.
[9]	LIN Kai-Li,QIN Chao,NI Si-Yu,CHEN Li-Dong,LU Jian-Xi,CHANG Jiang. Fabrication of Transparent β-Ca₃(PO₄)₂ Bioceramics by Spark Plasma Sintering Technique using Ultrafine Powders [J]. Journal of Inorganic Materials, 2006, 21(3): 645-650.
[10]	JING Jie-Hui,SUN Du-Cheng,XU Xiu-Mei. Preparation and Characterization of Nano-scale Anatase Titania by Electrolytic Precipitate Method [J]. Journal of Inorganic Materials, 2006, 21(1): 53-57.
[11]	CHEN Min,ZHENG Pei-Zhuang,HANG Zhi-Bin,ZHENG Xiao-Ming. Preparation of Ultrafine Ce-Zr-Ba Mixed Oxide Powder with High Surface Area [J]. Journal of Inorganic Materials, 2004, 19(3): 661-665.
[12]	YIN Bang-Yue,WANG Ling-Sen,FANG Yan-Chu. Preparation and Sintering of Ultrafine B₄C Powders [J]. Journal of Inorganic Materials, 2002, 17(2): 343-347.
[13]	KAN Yan-Mei,JIN Xi-Hai,WANG Pei-Ling,LI Yong-Xiang,CHENG Yi-Bing. Preparation of Ultrafine Bi₄Ti₃O₁₂ Powder by Coprecipitation Methods [J]. Journal of Inorganic Materials, 2002, 17(1): 51-55.
[14]	ZHANG Chao-Ping,DENG Wei,HU Lin,LUO Yu-Ping,HU Zong-Chao,GAO Xiang,SHEN De-Jun. Preparation of Ultrafine Ni-Fe Composite Particles by Microemulsion [J]. Journal of Inorganic Materials, 2001, 16(3): 481-485.
[15]	LIN Rong-Yi,ZHANG Jia-Yun,ZHANG Pei-Xin. Growth Control of Ultrafine CaCO₃ [J]. Journal of Inorganic Materials, 2001, 16(2): 353-357.