Oxidation Behavior and Meso-macro Model of Tubular C/SiC Composites in High-temperature Environment

doi:10.15541/jim20240002

Abstract

Abstract:

Oxidation damage is one of the main factors affecting the life of C/SiC composite nozzle used in rocket engines. To accurately predict the oxidation damage of C/SiC composite nozzle, we explored the oxidation behavior of the tubular C/SiC composites which had a similar shape to nozzle. Evolution of their composition, structure, and mechanical properties was investigated at different temperatures ranging from 900 to 1300 ℃. The results showed that the tubular C/SiC composites exhibited diffusion-controlled oxidation characteristics under the high-temperature environment. Their mass and residual strength decreased as a power function with time, and decline rate was positively correlated with temperature. Moreover, based on the theory of oxidation kinetics and mass transfer, a macro-meso oxidation model was established to simulate the oxidation process of tubular C/SiC composites in high-temperature environment to timely predict the evolution of their mass and residual strength. Consequentely, all the predicted results of the model fitted well with the experimental data. Our investigation consolidate that this macro-meso oxidation model is powerfull to predict the oxidation behavior and the life-span of C/SiC composite nozzle.

Key words: C/SiC composite, high-temperature oxidation, oxidation model, life prediction

CLC Number:

TB332

QUAN Wenxin, YU Yiping, FANG Bing, LI Wei, WANG Song. Oxidation Behavior and Meso-macro Model of Tubular C/SiC Composites in High-temperature Environment[J]. Journal of Inorganic Materials, 2024, 39(8): 920-928.

Figures/Tables 16

Fig. 1 Tubular specimen of C/SiC composite

Fig. 2 Ring tensile experiment of C/SiC composite

Fig. 3 Crack healed through thermal expansion and oxidation of SiC matrix

Fig. 4 Diffusion of oxygen in SiC cracks (a) and oxidation channel of carbon fibers (b)

Fig. 5 Equivalent oxidation depth of tubular C/SiC composite

Fig. 6 Mass retention rate (a), function fitting of

{(1 - η_{m})}^{2}

with t (b), strength retention rate (c), and function fitting of

{(1 - η_{R})}^{2}

with t (d) for tubular C/SiC composites after high-temperature air oxidation

Fig. 6 Mass retention rate (a), function fitting of ${(1 - η_{m})}^{2}$ with t (b), strength retention rate (c), and function fitting of ${(1 - η_{R})}^{2}$ with t (d) for tubular C/SiC composites after high-temperature air oxidation

Fig. 7 Morphology and distributions of elements on the surface of tubular C/SiC composite

Fig. 8 Microstructures at fractures of tubular C/SiC composites after high-temperature air oxidation

Fig. 9 Microstructures at fractures of carbon fibers in tubular C/SiC composites after high-temperature air oxidation

Fig. 10 Microstructures of cross-sections of tubular C/SiC composites after high-temperature air oxidation

Fig. 11 EDS distributions of oxygen contents at cross sections of tubular C/SiC composites after 1100 ℃-1 h (a), 1300 ℃-0.5 h (b) and 1300 ℃-1 h (c) high-temperature air oxidation

Table 1 Parabolic rate constant of SiC in air oxidation

Parameter	900 ℃	1000 ℃	1100 ℃	1200 ℃	1300 ℃
B/(nm²∙min^-1)	1.05	10.29	39.48	84.84	163.17

Table 2 Parameters of oxidation for 10 h

Parameter	900 ℃	1100 ℃	1300 ℃
$D_{O_{2}}^{z}$ /(m²∙s^–1)	3.18×10^-5	3.53×10^-5	3.86×10^-5
B/(nm²∙s^-1)	0.0175	0.658	2.720
Z/μm	0.0251	0.1539	0.3129
e/μm	1.980	1.835	1.658
$R_{O_{2}}^{z}$ /(mol∙m^–3∙s^–1)	1.937×10^-2	1.128×10^-2	2.880×10^-1

Table 2 Parameters of oxidation for 10 h

Parameter	900 ℃	1100 ℃	1300 ℃
$D_{O_{2}}^{z}$ /(m²∙s^–1)	3.18×10^-5	3.53×10^-5	3.86×10^-5
B/(nm²∙s^-1)	0.0175	0.658	2.720
Z/μm	0.0251	0.1539	0.3129
e/μm	1.980	1.835	1.658
$R_{O_{2}}^{z}$ /(mol∙m^–3∙s^–1)	1.937×10^-2	1.128×10^-2	2.880×10^-1

Fig. 12 Distributions of mole fraction of oxygen (a), gradient of mole fraction (b) and mole fraction with diffusion progress (c) in microcracks of SiC matrix

Table 3 Modifying factor of equivalent oxidation depth

Modifying factor	900 ℃	1100 ℃	1300 ℃
$β$	1.2×10^-5	3.1×10^-5	6.0×10^-5

Table 3 Modifying factor of equivalent oxidation depth

Modifying factor	900 ℃	1100 ℃	1300 ℃
$β$	1.2×10^-5	3.1×10^-5	6.0×10^-5

Fig. 13 Predicted results of strength retention rate (a) and mass retention rate (b)

References 29

[1]	栾新刚. 3D C/SiC在复杂耦合环境中的损伤机理与寿命预测. 西安: 西北工业大学博士学位论文, 2007.
[2]	张紫煜. 陶瓷基复合材料应用. 中国科技投资, 2016, 18: 308.
[3]	XU Y, ZHANG W. Numerical modelling of oxidized microstructure and degraded properties of 2D C/SiC composites in air oxidizing environments below 800 ℃. Materials Science and Engineering, 2011, 528(27): 7974.
[4]	LACOMBE A, PICHON T, LACOSTE M. High temperature composite nozzle extensions: a mature and efficient technology to improve upper stage liquid rocket engine performance. 43rd AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit, Cincinnati, 2007: 5471.
[5]	张立同, 成来飞, 梅辉, 等. 陶瓷基复合材料. 北京: 中国铁道出版社, 2020: 12- 42.
[6]	张立同, 成来飞. 连续纤维增韧陶瓷基复合材料可持续发展战略探讨. 复合材料学报, 2007, 2: 1.
[7]	HALBIG M C, MCGUFFIN-CAWLEY J D, ECKEL A J, et al. Oxidation kinetics and stress effects for the oxidation of continuous carbon fibers within a microcracked C/SiC ceramic matrix composite. Journal of the American Ceramic Society, 2008, 2: 519.
[8]	成来飞, 栾新刚, 张立同, 等. 超高温结构复合材料服役行为模拟:理论与方法. 北京: 化学工业出版社, 2020: 174-237.
[9]	CHEN X, SUN Z, CHEN P, et al. Modeling thermal expansion behavior of 2.5D C/SiC composites in air oxidizing environments between 400 ℃ and 800 ℃. Applied Composite Materials, 2020, 6: 861.
[10]	MEI H, TAN Y, CHANG P, et al. Simplified approach to study oxidative damage of C/SiC composites induced from notch defects. Ceramics International, 2019, 45(17): 22464.
[11]	LAMOUROUX F, CAMUS G, THEBAULT J. Kinetics and mechanisms of oxidation of 2D woven C/SiC composites: I. experimental approach. Journal of the American Ceramic Society, 1994, 8: 2049.
[12]	LAMOUROUX F, NASLAIN R, JOUIN J. Kinetics and mechanisms of oxidation of 2D woven C/SiC composites: II, theoretical approach. Journal of the American Ceramic Society, 1994, 8: 2058.
[13]	SULLIVAN R M. A model for the oxidation of carbon silicon carbide composite structures. Carbon, 2005, 43(2): 275.
[14]	ZHAO C, TU Z, MAO J. The dynamic thermophysical properties evolution and multi-scale heat transport mechanisms of 2.5D C/SiC composite under high-temperature air oxidation environment. Composites Part B, 2023, 263: 110831.
[15]	DING J, SUN Z, CHEN X, et al. A progressive oxidative damage model of C/SiC composites under stressed oxidation environments. Applied Composite Materials, 2021, 28(5): 1609.
[16]	颜淮. C/SiC复合材料微细观氧化损伤分析. 哈尔滨: 哈尔滨工业大学硕士学位论文, 2021.
[17]	CHEN P, NIU X, CHEN X, et al. Modeling the failure time and residual strength of C/SiC composites under stress-oxidation environment. Transactions of the Indian Ceramic Society, 2020, 4: 212.
[18]	ZHAO C, TU Z, MAO J. Thermal-oxidation coupled analysis method for unidirectional fiber-reinforced C/SiC composites in air oxidizing environments below 1000 ℃. International Communications in Heat and Mass Transfer, 2023, 143: 106678.
[19]	ECKEL A J, CAWLEY J D, PARTHASARATHY T A. Oxidation kinetics of a continuous carbon phase in a nonreactive matrix. Journal of the American Ceramic Society, 1995, 4: 972.
[20]	OPILA E J, SERRA J L. Oxidation of carbon fiber-reinforced silicon carbide matrix composites at reduced oxygen partial pressures. Journal of the American Ceramic Society, 2011, 7: 2185.
[21]	XIANG Y, CAO F, PENG Z, et al. Evolution of microstructure and mechanical properties of PIP-C/SiC composites after high- temperature oxidation. Journal of Asian Ceramic Societies, 2017, 3: 370.
[22]	SU F, HUANG P, WU J, et al. Creep behavior of C/SiC composite in hot oxidizing atmosphere and its mechanism. Ceramics International, 2017, 12: 9355.
[23]	DRAWIN S, BACOS M, DORVAUX J, et al. Oxidation model for carbon-carbon composites. 4th Symposium on Multidisciplinary Analysis and Optimization, Cleveland, 1992: 5016.
[24]	国义军, 石卫波, 曾磊, 等. 高超声速飞行器烧蚀防热理论与应用. 北京: 科学出版社, 2019: 112.
[25]	DEAL B E, GROVE A S. General relationship for the thermal oxidation of silicon. Journal of Applied Physics, 1965, 12: 3770.
[26]	FILIPUZZI L, NASLAIN R, JAUSSAUD C. Oxidation kinetics of SiC deposited from CH₃SiCl₃/H₂ under CVI conditions. Journal of Materials Science, 1992, 12: 3331.
[27]	SONG Y, DHAR S, FELDMAN L C. Modified deal grove model for the thermal oxidation of silicon carbide. Journal of Applied Physics, 2004, 9: 4953.
[28]	FULLER E N, SCHETTLER P D, GIDDINGS J C. New method for prediction of binary gas-phase diffusion coefficients. Industrial & Engineering Chemistry, 1966, 5: 18.
[29]	KNUDSEN M. The laws of molecular flow and of inner friction flow of gases through tubes. Journal of Membrane Science, 1995, 1: 23.