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无机材料学报

无机材料学报

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纳米Al粉掺杂对MgB2 超导块材超导电性和显微结构影响

郭方方1, 徐政1, 许红亮1, 冯勇2   

  1. 1. 同济大学 材料科学与工程学院, 上海 200092; 2. 西北有色金属研究院, 西安 710016
  • 收稿日期:2006-02-02 修回日期:2006-04-12 出版日期:2007-01-20 网络出版日期:2007-01-20

Effects of Nano-Al Doping on Superconductivity and Microstructure of MgB2 Bulk Superconductors

GUO Fang-Fang1, XU Zheng1, XU Hong-Liang1, FENG Yong2   

  1. 1. School of Material Science and Engineering, Tongji University, Shanghai 200092, China; 2. Northwest Institute for Nonferrous Metal Research, Xi’an 710016, China
  • Received:2006-02-02 Revised:2006-04-12 Published:2007-01-20 Online:2007-01-20

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摘要： 以纳米Al粉为掺杂物质,借助超声 分散,较好地解决了纳米Al粉的团聚及其与B粉的均匀混合问题, 制备出了1mol％、2mol％、5mol％、8mol％纳米Al粉掺杂的MgB2 超导块材, 并对掺杂效果和机理进行了研究. 物相和显微结构分析表明, Al能够替代Mg进入MgB2 晶格内, 并导致MgB2 的晶胞参数 a 、 c 逐渐降低, 其中 c 的降低幅度较大. 随着Al掺量的增加, MgB2 的临界温度 Tc 逐渐降低, 由未掺杂时的38.5K降低至掺杂8mol％ Al时的35.5K. 超导电性研究结果表明, 纳米Al粉掺杂, 在低温、高场、低掺杂量的条件下可以改善MgB2 的超导性能, 掺杂量过大反而
抑制MgB2 的超导性能, 2mol％的纳米Al粉掺杂效果最好.

关键词: 纳米Al粉掺杂, MgB2 超导块材, 超导电性, 显微结构

Abstract: Nano-size Al powders were dispersed by ultrasonic vibrations to avoid reuniting and doped to the MgB2 bulk material uniformly. The effects and mechanism of doping were studied. The phase analysis and microstructure analysis show that Al atoms can dope into the lattice of MgB2 and substitute the site of Mg atoms. With the increase of addition, the crystal parameters a and c of MgB2 decrease gradually and the value of c depresses more, and the critical temperature Tc of MgB2 depresses too. The value of Tc is 35.5K for the superconductor with 8mol％ addition, while 38.5K for the pure MgB2 bulk superconductor. The results of our research demonstrate that the superconductivity of MgB2 with nano-Al doping is improved at the conditions of low temperature, high magnetic field and low level addition, the high level addition can restrain the superconductivity of MgB2 ; the effects are the best when the value of nano-Al dopant is 2mol%.

Key words: nano-Al powder doping, MgB2 bulk superconductor, superconductivity, microstructure

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