Research Paper

Research of Cf/TaC Composites Prepared by Low Temperature Chemical Vapor Infiltration (CVI) Process

  • CHEN Zhao-Ke ,
  • XIONG Xiang ,
  • XIAO Peng ,
  • LI Guo-Dong ,
  • HUANG Bo-Yun
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  • State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Received date: 2006-04-24

  Revised date: 2006-06-26

  Online published: 2007-03-20

Abstract

TaC was deposited by a chemical vapor infiltration(CVI) method with TaCl5-Ar-C3H6 system in the carbon fiber felt. The influences of temperature on CVI deposition rate, deposition uniformity, phase composition, crystallization size and surface growth morphology of TaC coating in carbon fiber felt were studied. The experimental results show that, the deposition rate increases firstly with the rising of temperature, reaches its maximum value at 950℃ and then decreases; at 900℃, the deposition uniformity is the best; the highly crystalline TaC can be deposited between 800℃ and 1000℃ and the crystalline size increases at elevated temperature; it is island-like growth model of TaC on the carbon fiber between 800℃ and 1000℃; with the rising of deposition temperature, the sizes of the deposition islands increase firstly and then decrease; the diffusion ability of the deposition islands increases, and the deposition islands link and melt each other at elevated temperature.

Cite this article

CHEN Zhao-Ke , XIONG Xiang , XIAO Peng , LI Guo-Dong , HUANG Bo-Yun . Research of Cf/TaC Composites Prepared by Low Temperature Chemical Vapor Infiltration (CVI) Process[J]. Journal of Inorganic Materials, 2007 , 22(2) : 287 -292 . DOI: 10.3724/SP.J.1077.2007.00287

References

[1] 马福康, 邱向东, 贾厚生,等译. 铌与钽, 第1版. 长沙: 中南工业大学出版社, 1997. 19.
[2] 闫志巧, 熊翔, 肖鹏, 等(YAN Zhi-Qiao, et al). 无机材料学报(Journal of Inorganic Materials), 2005, 20 (5): 1195--1200.
[3] 崔红, 苏君明, 李瑞珍, 等. 西北工业大学学报, 2000, 18 (4): 669--673.
[4] 李国栋, 熊翔, 黄伯云. 中国有色金属学报, 2005, 15 (4): 565--571.
[5] 何捍卫, 周科朝, 熊翔. 稀有金属材料与工程, 2004, 33 (5): 490--493.
[6] Sinani I L, Chuzhko R K, Chernikov Yu P. Inorganic Materials, 1998, 34 (4): 342--344.
[7] Sinani I L, Chuzhko R K, Chernikov Yu P. Neorg. Mater., 1995, 31 (5): 663--667.
[8] Chuzhko R K, Repnikov N N, Sinani I L. Zh. Fiz. Khim., 1993, 67 (5): 1024--1027.
[9] David W. Graham, Stinton David P. Journal of the American Ceramic Society, 1994, 77 (9): 2298.
[10] SAYIR A. Journal of Materials Science., 2004, 39: 5995--6003.
[11] Kim C, Grummon D S, Gottstein G. Scripta Metallurgica et Materialia. 1991, 25 (10): 2351--2356.
[12] Courtright E L, Prater J T, Holcomb G R, et al. Oxidation of Metals (Historical Archive), 1991, 36 (5-6): 423--437.
[13] Patterson M C L a, He S. Materials and Manufacturing Processes, 1996, 11 (3): 367--379.
[14] Kim C, Grummon D S. Scripta Metallurgica et Materialia, 1991, 25 (10): 2351--2356.
[15] 孟广耀. 化学气相淀积与无机新材料. 北京: 科学出版社, 1984.
[16] 肖鹏, 徐永东, 黄伯云(XIAO Peng, et al). 无机材料学报(Journal of Inorganic Materials), 2002, 17 (4): 877--881.
[17] 王恩哥. 物理学进展, 2003, 23 (1): 1--60.

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