The preparation of ultrafine cubic Sb2O3 was studied by using oxychloride (Sb4O5Cl2) neutralized with ammonia under ultrasonic field. The results show that Sb2O3 obtained in the process is cubic crystalline and well-dispersed, which has an average particle size of 0.777μm when the ultrasonic power is 100W, the ultrasonic time is 30min, and the temperature is 20℃. The effects of ultrasonic power, time, ratios of distilled water to oxychloride, and temperature on the crystal structure and particle size of the Sb2O3 formed were investigated by means of XRD, SEM and laser sizer.
QIU Ke-Qiang
,
ZHANG Rong-Liang
,
TANG Shu-Zhen
,
SHE Yuan-Yuan
,
HU Han-Xiang
. Effect of Ultrasonic Field on Preparation of Sb2O3[J]. Journal of Inorganic Materials, 2006
, 21(6)
: 1333
-1338
.
DOI: 10.3724/SP.J.1077.2006.01333
[1] 李文杰, 徐本富(LI Wen-Jie, et al). 广东工学院学报(Journal of Guangdong Institute of Technology), 1993, 10 (2): 51--58.
[2] 段学臣, 赵天从(DUAN Xue-Chen, et al). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 1996, 6 (1): 36--39.
[3] 甘庆民, 杨秉文(GAN Qing-Min, et al). 材料工程(Material Engineering), 1997, (8): 27,46.
[4] 张多默, 肖松文, 刘志宏,等(ZHANG Duo-Mo, et al). 中南大学学报(Journal of Central South University), 2000, 31 (2): 121--123.
[5]肖松文, 刘志宏, 李启厚,等(XIAO Song-Wen, et al). 矿冶工程(Mining and Metallurgical Engineering), 1999, 19 (3): 39--41.
[6] Suslick K S, Hyeon T, Fang M, Materials Science and Engineering: A, 1995, 204(1-2): 186--192.
[7] Kristl M, Drofenik M. Inorganic Chemistry Communications, 2003, 6 (12): 1419--1422.
[8] Cui H M, Liu H, Wang J Y, et al. Journal of Crystal Growth, 2004, 271 (3-4): 456--461.
[9] 张昭, 吴潘, 王乐飞, 等(ZHANG Zhao, et al). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 2005, 15 (2): 321--326.
[10] 吴争平, 尹周谰, 陈启元, 等(WU Zhen-Ping, et al). 过程工程学报(The Chinese Journal of Process Engineering), 2002, 2 (1): 26--31.
[11] Borkovska L V, Baran M P. Korsunska N O, et al. Physica, 2003, B340-342: 258--262.
[12] Kumar R Vijaya, Elgamioel R, Koltypin Yu, et al. Journal of Crystal Growth, 2003, 250 (3-4): 409--417.
[13] 徐华蕊, 李凤生, 陈舒林,等(XU Hua-Rui, et al). 化工进展(Chemical Industry and Engineering Process ), 1996, (5): 20--31,57.
[14] 陈雪梅, 陈彩凤, 陈志刚(CHEN Xue-Mei, et al). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 2003, 13 (10): 122--126.
[15] 梁新义, 秦永宁, 齐晓周,等(LIANG Xin-Yi, et al). 化学物理学报(Chinese Journal of Chemical Physics), 1998, 11 (4): 375--378.