Formation and Thermal Stabilities Research of Ionic Liquids/α-ZrP Antibacterial Materials

doi:10.3724/SP.J.1077.2011.01193

Abstract

Abstract: Three different ionic liquids/α-zirconium phosphonates (IL-ZrP) composites antibacterial materials were prepared by introducing quarternary ammonium type ionic liquids (1-hexadecyl-3-methylimidazolium bromide, C₁₆MIMBr; hexadecyl dimethyl benzyl ammonium chloride, C₁₆HDBACCl; hexadecyl trimethyl ammonium chloride, C₁₆CTACCl) into the interlayer of α-zirconium phosphonates (α-ZrP). The structure, components and thermal stability of composites was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscope (FTIR), Thermogravimetric-Fourier transform infrared spectroscope analysis (TG-FTIR). XRD patterns show that the interlayer spacing of IL-ZrP are larger than the original α-ZrP. It represents that the ionic liquids are intercalated into the layer of α-ZrP. TG-FTIR shows that the mass fraction of C₁₆MIMBr, C₁₆HDBACCl and C₁₆CTACCl in three IL-ZrP are 53.11wt%, 50.65wt% and 51.25wt%, respectively. The onset temperatures of the decomposition for C₁₆MIMBr, C₁₆HDBACCl and C₁₆CTACCl are 174℃, 198℃ and 219℃, while the onset temperatures of the decomposition for C16MIMBr-ZrP, C₁₆HDBACCl-ZrP and C₁₆CTACCl-ZrP are 219℃, 225℃ and 263℃. The existing of α-ZrP improves the thermal stability of ionic liquids. Among the three IL-ZrP, the C₁₆MIMBr-ZrP has excellent antibacterial activity, (i.e. within 24 h, the minimal inhibitory concentration of C₁₆MIMBr pillared α-zirconium phosphonates against S. aureus and E. coli is less than 19 mg/L).

Key words: ionic liquids, α-ZrP, organic-inorganic composites, antibacterial activity

CLC Number:

TB332

LI Dan, CHEN Yun-Fa. Formation and Thermal Stabilities Research of Ionic Liquids/α-ZrP Antibacterial Materials[J]. Journal of Inorganic Materials, 2011, 26(11): 1193-1198.

References

[1] Wang H, Han D, Li N, et al. Molecular modeling of the intercalation of porphyrins into α-zirconium phosphate. Journal of Molecular Modeling, 2005, 12(1): 9-15.

[2] Haiyan W, Daxiong H, Na L, et al. Study on the intercalation and interlayer state of porphyrins into α-zirconium phosphate. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2005, 52(3): 247-252.

[3] Zhang R, Hu Y, Li B, et al. Studies on the preparation and structure of polyacrylamide/α-zirconium phosphate nanocomposites. Journal of Materials Science, 2007, 42(14): 5641-5646.

[4] Vivani R, Alberti G, Costantino F, et al. New advances in zirconium phosphate and phosphonate chemistry: structural archetypes. Microporous and Mesoporous Materials, 2008, 7(1/2): 58-70.

[5] Hayashi Nakayama A H, Tsuhako M. Intercalation of melamine into layered zirconium phosphates and their adsorption properties of formaldehyde in gas and solution phase. Solid State Sciences, 2009, 11(5): 1007-1015.

[6] Tan S, Ouyang Y, Zhang L, et al. Study on the structure and antibacterial activity of silver-carried zirconium phosphate. Materials Letters, 2008, 62(14): 2122-2124.

[7] 谭绍早, 郑佳, 陈茵, 等(TAN Shao-Zao, et al). 含季鏻阳离子的抗菌改性蒙脱土的制备及表征. 无机材料学报(Journal of Inorganic Materials), 2009, 24(3): 507-511.

[8] 王云斌, 杨晋涛, 费正东, 等(WANG Yun-Bin, et al). 吡啶硫酮锌/蒙脱土的制备及其抗菌性能研究. 无机材料学报(Journal of Inorganic Materials), 2010, 25(5): 512-516.

[9] 韩晓建, 黄争鸣, 何创龙, 等(HAN Xiao-Jian, et al). 聚碳酸酯/ TiO2超细纤维的制备与表征. 无机材料学报(Journal of Inorganic Materials), 2007, 22(3): 407-412.

[10] 丁浩, 童忠良, 杜高翔. 工业杀菌剂. 北京: 化学工业出版社, 2007: 149-150.

[11] Antonietti M, Kuang D, Smarsly B, et al. Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures. Angewandte Chemie International Edition, 2004, 43(38): 4988-4992.

[12] Mehnert C P. Supported ionic liquid catalysis. Chemistry-a European Journal, 2004, 11(1): 50-56.

[13] Taubert A, Li Z. Inorganic materials from ionic liquids. Dalton Transactions, 2007(7): 723-727.

[14] Li Z, Jia Z, Luan Y, et al. Ionic liquids for synthesis of inorganic nanomaterials. Current Opinion in Solid State & Materials Science, 2009, 12(1): 1-8.

[15] Trewyn B G, Whitman C M, Victor S. Morphological control of room-temperature ionic liquid templated mesoporous silica nanoparticles for controlled release of antibacterial agents. Nano Letters, 2004, 4(11): 2139-2143.

[16] Clearfield A, Stynes J A. The preparation of crystalline zirconium phosphate and some observations on its ion exchange behaviour. Journal of Inorganic and Nuclear Chemistry, 1964, 26(1): 117-129.

[17] 徐金锁, 唐颐(XU Jin-Suo, et al). 烷基胺和醇胺在层状磷酸锆中的嵌入研究. 高等学校化学学报(Chem. J. Chinese U.), 1997, 18(1): 88-92.

[18] 杜以波, 李峰. 胺和醇对α-ZrP的插层性能研究. 石油学报:石油加工, 1998, 14(1): 62-65.

[19] 陈仪本, 欧阳友生, 黄小茉, 等. 工业杀菌剂. 北京: 化学工业出版社, 2001: 21-25.